Selective reduction and homologation of carbon monoxide by organometallic iron complexes

Metal-mediated activation of CO for C-C coupling reactions is a valuable approach to carbon monoxide valorization. Here, the authors use low-coordinate iron(II) complexes for the selective scission and homologation of CO affording unusual squaraines and iron carboxylates under mild conditions.

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Auteurs principaux: Helen R. Sharpe, Ana M. Geer, Laurence J. Taylor, Benjamin M. Gridley, Toby J. Blundell, Alexander J. Blake, E. Stephen Davies, William Lewis, Jonathan McMaster, David Robinson, Deborah L. Kays
Format: article
Langue:EN
Publié: Nature Portfolio 2018
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Accès en ligne:https://doaj.org/article/345eb1f0dbd64225b086da22de3b273c
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