Kinetic and Mechanism of Oxidation of Oxalic Acid by Cerium (IV)

Kinetic and mechanism studies of the oxidation of oxalic acid by Cerium sulphate have been carried out in acid medium sulphuric acid. The uv- vis. Spectrophotometric technique was used to follow up the reaction and the selected wavelength to be followed was 320 nm. The kinetic study showed that the...

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Autor principal:	Dr. Ammar J. Mohammed
Formato:	article
Lenguaje:	EN
Publicado:	Al-Khwarizmi College of Engineering – University of Baghdad 2017
Materias:	Keyword: Cerium(IV), Kinetics, Oxidation, Oxalic Acid. Chemical engineering TP155-156 Engineering (General). Civil engineering (General) TA1-2040
Acceso en línea:	https://doaj.org/article/349813457de44bb292737b797d80dccb
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spelling	oai:doaj.org-article:349813457de44bb292737b797d80dccb2021-12-02T05:27:15ZKinetic and Mechanism of Oxidation of Oxalic Acid by Cerium (IV)1818-11712312-0789https://doaj.org/article/349813457de44bb292737b797d80dccb2017-12-01T00:00:00Zhttp://alkej.uobaghdad.edu.iq/index.php/alkej/article/view/27https://doaj.org/toc/1818-1171https://doaj.org/toc/2312-0789 Kinetic and mechanism studies of the oxidation of oxalic acid by Cerium sulphate have been carried out in acid medium sulphuric acid. The uv- vis. Spectrophotometric technique was used to follow up the reaction and the selected wavelength to be followed was 320 nm. The kinetic study showed that the order of reaction is first order in Ce(IV) and fractional in oxalic acid. The effect of using different concentration of sulphuric acid on the rate of the reaction has been studied a and it was found that the rate decreased with increasing the acid concentration. Classical organic tests was used to identify the product of the oxidation reaction, the product was just bubbles of CO2. Dr. Ammar J. MohammedAl-Khwarizmi College of Engineering – University of BaghdadarticleKeyword: Cerium(IV), Kinetics, Oxidation, Oxalic Acid.Chemical engineeringTP155-156Engineering (General). Civil engineering (General)TA1-2040ENAl-Khawarizmi Engineering Journal, Vol 1, Iss 1 (2017)
institution	DOAJ
collection	DOAJ
language	EN
topic	Keyword: Cerium(IV), Kinetics, Oxidation, Oxalic Acid. Chemical engineering TP155-156 Engineering (General). Civil engineering (General) TA1-2040
spellingShingle	Keyword: Cerium(IV), Kinetics, Oxidation, Oxalic Acid. Chemical engineering TP155-156 Engineering (General). Civil engineering (General) TA1-2040 Dr. Ammar J. Mohammed Kinetic and Mechanism of Oxidation of Oxalic Acid by Cerium (IV)
description	Kinetic and mechanism studies of the oxidation of oxalic acid by Cerium sulphate have been carried out in acid medium sulphuric acid. The uv- vis. Spectrophotometric technique was used to follow up the reaction and the selected wavelength to be followed was 320 nm. The kinetic study showed that the order of reaction is first order in Ce(IV) and fractional in oxalic acid. The effect of using different concentration of sulphuric acid on the rate of the reaction has been studied a and it was found that the rate decreased with increasing the acid concentration. Classical organic tests was used to identify the product of the oxidation reaction, the product was just bubbles of CO2.
format	article
author	Dr. Ammar J. Mohammed
author_facet	Dr. Ammar J. Mohammed
author_sort	Dr. Ammar J. Mohammed
title	Kinetic and Mechanism of Oxidation of Oxalic Acid by Cerium (IV)
title_short	Kinetic and Mechanism of Oxidation of Oxalic Acid by Cerium (IV)
title_full	Kinetic and Mechanism of Oxidation of Oxalic Acid by Cerium (IV)
title_fullStr	Kinetic and Mechanism of Oxidation of Oxalic Acid by Cerium (IV)
title_full_unstemmed	Kinetic and Mechanism of Oxidation of Oxalic Acid by Cerium (IV)
title_sort	kinetic and mechanism of oxidation of oxalic acid by cerium (iv)
publisher	Al-Khwarizmi College of Engineering – University of Baghdad
publishDate	2017
url	https://doaj.org/article/349813457de44bb292737b797d80dccb
work_keys_str_mv	AT drammarjmohammed kineticandmechanismofoxidationofoxalicacidbyceriumiv
_version_	1718400402531024896

Kinetic and Mechanism of Oxidation of Oxalic Acid by Cerium (IV)

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