Enhanced organic solar cell performance: Multiple surface plasmon resonance and incorporation of silver nanodisks into a grating‐structure electrode

In this study, plasmonic nanostructures were examined to enhance the light harvesting of organic thin-film solar cells (OSCs) by multiple surface plasmon resonance (SPR) phenomena originating from the grating-coupled configuration with a Blu-ray Disc recordable (BD-R)-imprinted aluminum (Al) grating...

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Autores principales: Putnin Thitirat, Lertvachirapaiboon Chutiparn, Ishikawa Ryousuke, Shinbo Kazunari, Kato Keizo, Ekgasit Sanong, Ounnunkad Kontad, Baba Akira
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Publicado: Institue of Optics and Electronics, Chinese Academy of Sciences 2019
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spelling oai:doaj.org-article:34a21339d26947798d0e0d3823fcd80b2021-11-11T09:53:20ZEnhanced organic solar cell performance: Multiple surface plasmon resonance and incorporation of silver nanodisks into a grating‐structure electrode2096-457910.29026/oea.2019.190010https://doaj.org/article/34a21339d26947798d0e0d3823fcd80b2019-07-01T00:00:00Zhttp://www.oejournal.org/article/doi/10.29026/oea.2019.190010https://doaj.org/toc/2096-4579In this study, plasmonic nanostructures were examined to enhance the light harvesting of organic thin-film solar cells (OSCs) by multiple surface plasmon resonance (SPR) phenomena originating from the grating-coupled configuration with a Blu-ray Disc recordable (BD-R)-imprinted aluminum (Al) grating structure and the incorporation of a series of silver nanodisks (Ag NDs). The devices with such a configuration maximize the light utilization inside OSCs via light absorption, light scattering, and trapping via multiple surface plasmon resonances. Different types and sizes of metallic nanoparticles (NPs), i.e., gold nanoparticles (Au NPs), Ag nanospheres (Ag NSs), and Ag NDs, were used, which were blended separately in a PEDOT:PSS hole transport layer (HTL). The device structure comprised of grating-imprinted-Al/P3HT:PCBM/Ag ND:PEDOT:PSS/ITO. Results obtained from the J–V curves revealed that the power conversion efficiency (PCE) of grating-structured Al/P3HT:PCBM/PEDOT:PSS/ITO is 3.16%; this value is ~6% higher than that of a flat substrate. On the other hand, devices with flat Al and incorporated Au NPs, Ag NSs, or Ag NDs in the HTL exhibited PCEs ranging from 3.15% to 3.37%. Furthermore, OSCs with an Al grating substrate were developed by the incorporation of the Ag ND series into the PEDOT:PSS layer. Compared with that of a reference device, the PCEs of the devices increased to 3.32%–3.59% (11%–20% improvement), indicating that the light absorption enhancement at the active layer corresponds to the grating-coupled surface plasmon resonance and localized surface plasmon resonance excitations with strong near-field distributions penetrating into the active layer leading to higher efficiencies and subsequent better current generation.Putnin ThitiratLertvachirapaiboon ChutiparnIshikawa RyousukeShinbo KazunariKato KeizoEkgasit SanongOunnunkad KontadBaba AkiraInstitue of Optics and Electronics, Chinese Academy of Sciencesarticlegrating-coupled surface plasmon resonancelocalized surface plasmon resonanceag nanodisksorganic solar cellsimprinted gratingOptics. LightQC350-467ENOpto-Electronic Advances, Vol 2, Iss 7, Pp 1-11 (2019)
institution DOAJ
collection DOAJ
language EN
topic grating-coupled surface plasmon resonance
localized surface plasmon resonance
ag nanodisks
organic solar cells
imprinted grating
Optics. Light
QC350-467
spellingShingle grating-coupled surface plasmon resonance
localized surface plasmon resonance
ag nanodisks
organic solar cells
imprinted grating
Optics. Light
QC350-467
Putnin Thitirat
Lertvachirapaiboon Chutiparn
Ishikawa Ryousuke
Shinbo Kazunari
Kato Keizo
Ekgasit Sanong
Ounnunkad Kontad
Baba Akira
Enhanced organic solar cell performance: Multiple surface plasmon resonance and incorporation of silver nanodisks into a grating‐structure electrode
description In this study, plasmonic nanostructures were examined to enhance the light harvesting of organic thin-film solar cells (OSCs) by multiple surface plasmon resonance (SPR) phenomena originating from the grating-coupled configuration with a Blu-ray Disc recordable (BD-R)-imprinted aluminum (Al) grating structure and the incorporation of a series of silver nanodisks (Ag NDs). The devices with such a configuration maximize the light utilization inside OSCs via light absorption, light scattering, and trapping via multiple surface plasmon resonances. Different types and sizes of metallic nanoparticles (NPs), i.e., gold nanoparticles (Au NPs), Ag nanospheres (Ag NSs), and Ag NDs, were used, which were blended separately in a PEDOT:PSS hole transport layer (HTL). The device structure comprised of grating-imprinted-Al/P3HT:PCBM/Ag ND:PEDOT:PSS/ITO. Results obtained from the J–V curves revealed that the power conversion efficiency (PCE) of grating-structured Al/P3HT:PCBM/PEDOT:PSS/ITO is 3.16%; this value is ~6% higher than that of a flat substrate. On the other hand, devices with flat Al and incorporated Au NPs, Ag NSs, or Ag NDs in the HTL exhibited PCEs ranging from 3.15% to 3.37%. Furthermore, OSCs with an Al grating substrate were developed by the incorporation of the Ag ND series into the PEDOT:PSS layer. Compared with that of a reference device, the PCEs of the devices increased to 3.32%–3.59% (11%–20% improvement), indicating that the light absorption enhancement at the active layer corresponds to the grating-coupled surface plasmon resonance and localized surface plasmon resonance excitations with strong near-field distributions penetrating into the active layer leading to higher efficiencies and subsequent better current generation.
format article
author Putnin Thitirat
Lertvachirapaiboon Chutiparn
Ishikawa Ryousuke
Shinbo Kazunari
Kato Keizo
Ekgasit Sanong
Ounnunkad Kontad
Baba Akira
author_facet Putnin Thitirat
Lertvachirapaiboon Chutiparn
Ishikawa Ryousuke
Shinbo Kazunari
Kato Keizo
Ekgasit Sanong
Ounnunkad Kontad
Baba Akira
author_sort Putnin Thitirat
title Enhanced organic solar cell performance: Multiple surface plasmon resonance and incorporation of silver nanodisks into a grating‐structure electrode
title_short Enhanced organic solar cell performance: Multiple surface plasmon resonance and incorporation of silver nanodisks into a grating‐structure electrode
title_full Enhanced organic solar cell performance: Multiple surface plasmon resonance and incorporation of silver nanodisks into a grating‐structure electrode
title_fullStr Enhanced organic solar cell performance: Multiple surface plasmon resonance and incorporation of silver nanodisks into a grating‐structure electrode
title_full_unstemmed Enhanced organic solar cell performance: Multiple surface plasmon resonance and incorporation of silver nanodisks into a grating‐structure electrode
title_sort enhanced organic solar cell performance: multiple surface plasmon resonance and incorporation of silver nanodisks into a grating‐structure electrode
publisher Institue of Optics and Electronics, Chinese Academy of Sciences
publishDate 2019
url https://doaj.org/article/34a21339d26947798d0e0d3823fcd80b
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