Isolation and characterization of a covalent CeIV-Aryl complex with an anomalous 13C chemical shift

Ce(IV) organometallic compounds are rare due to Ce(IV) being a powerful oxidant. Herein, the authors explore the covalency of a pair of organocerium complexes bearing a Ce(IV)-C(aryl) bond and examine their structure by NMR spectroscopy, X-ray diffraction analysis, and computational calculations.

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Autores principales:	Grace B. Panetti, Dumitru-Claudiu Sergentu, Michael R. Gau, Patrick J. Carroll, Jochen Autschbach, Patrick J. Walsh, Eric J. Schelter
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/353226de13d34f4f95d8e07ece1a0bc0
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spelling	oai:doaj.org-article:353226de13d34f4f95d8e07ece1a0bc02021-12-02T17:04:51ZIsolation and characterization of a covalent CeIV-Aryl complex with an anomalous 13C chemical shift10.1038/s41467-021-21766-42041-1723https://doaj.org/article/353226de13d34f4f95d8e07ece1a0bc02021-03-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-21766-4https://doaj.org/toc/2041-1723Ce(IV) organometallic compounds are rare due to Ce(IV) being a powerful oxidant. Herein, the authors explore the covalency of a pair of organocerium complexes bearing a Ce(IV)-C(aryl) bond and examine their structure by NMR spectroscopy, X-ray diffraction analysis, and computational calculations.Grace B. PanettiDumitru-Claudiu SergentuMichael R. GauPatrick J. CarrollJochen AutschbachPatrick J. WalshEric J. SchelterNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-7 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Grace B. Panetti Dumitru-Claudiu Sergentu Michael R. Gau Patrick J. Carroll Jochen Autschbach Patrick J. Walsh Eric J. Schelter Isolation and characterization of a covalent CeIV-Aryl complex with an anomalous 13C chemical shift
description	Ce(IV) organometallic compounds are rare due to Ce(IV) being a powerful oxidant. Herein, the authors explore the covalency of a pair of organocerium complexes bearing a Ce(IV)-C(aryl) bond and examine their structure by NMR spectroscopy, X-ray diffraction analysis, and computational calculations.
format	article
author	Grace B. Panetti Dumitru-Claudiu Sergentu Michael R. Gau Patrick J. Carroll Jochen Autschbach Patrick J. Walsh Eric J. Schelter
author_facet	Grace B. Panetti Dumitru-Claudiu Sergentu Michael R. Gau Patrick J. Carroll Jochen Autschbach Patrick J. Walsh Eric J. Schelter
author_sort	Grace B. Panetti
title	Isolation and characterization of a covalent CeIV-Aryl complex with an anomalous 13C chemical shift
title_short	Isolation and characterization of a covalent CeIV-Aryl complex with an anomalous 13C chemical shift
title_full	Isolation and characterization of a covalent CeIV-Aryl complex with an anomalous 13C chemical shift
title_fullStr	Isolation and characterization of a covalent CeIV-Aryl complex with an anomalous 13C chemical shift
title_full_unstemmed	Isolation and characterization of a covalent CeIV-Aryl complex with an anomalous 13C chemical shift
title_sort	isolation and characterization of a covalent ceiv-aryl complex with an anomalous 13c chemical shift
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/353226de13d34f4f95d8e07ece1a0bc0
work_keys_str_mv	AT gracebpanetti isolationandcharacterizationofacovalentceivarylcomplexwithananomalous13cchemicalshift AT dumitruclaudiusergentu isolationandcharacterizationofacovalentceivarylcomplexwithananomalous13cchemicalshift AT michaelrgau isolationandcharacterizationofacovalentceivarylcomplexwithananomalous13cchemicalshift AT patrickjcarroll isolationandcharacterizationofacovalentceivarylcomplexwithananomalous13cchemicalshift AT jochenautschbach isolationandcharacterizationofacovalentceivarylcomplexwithananomalous13cchemicalshift AT patrickjwalsh isolationandcharacterizationofacovalentceivarylcomplexwithananomalous13cchemicalshift AT ericjschelter isolationandcharacterizationofacovalentceivarylcomplexwithananomalous13cchemicalshift
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Isolation and characterization of a covalent CeIV-Aryl complex with an anomalous 13C chemical shift

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