Air-stable 18-electron adducts of Schrock catalysts with tuned stability constants for spontaneous release of the active species

Air-sensitive molybdenum olefin metathesis catalysts are known to form stable but inactive adducts with appropriate chelating ligands, but regenerating the active catalyst requires the use of Lewis acids and vigorous conditions. Here, tuning the electron donor capacity of the ligands leads to air-st...

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Autores principales: Henrik Gulyás, Shigetaka Hayano, Ádám Madarász, Imre Pápai, Márk Szabó, Ágota Bucsai, Eddy Martin, Jordi Benet-Buchholz
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2021
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Acceso en línea:https://doaj.org/article/3534933d432a426aa3ec32108001b96d
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