In-Situ Ionic Imprinted Membrane (IIM) Synthesis Based on Acetic Polyeugenoxy Acetyl Tiophen Methanolate for Gold(III) Metal Ion Transports

In this research, Polyeugenoxy Acetyl Tiophen Methanolate (PEATM)-Au ionic imprinted membrane (IIM) was synthesized. IIM is a PEATM based membrane that has Au(III) ion molds. The PEATM synthesis was analyzed using FTIR spectroscopy, and its relative molecular weight was determined by the viscometry...

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Autores principales:	Muhammad Cholid Djunaidi, Pardoyo Pardoyo, Didik Setiyo Widodo, Retno Ariadi Lusiana, Anggun Yuliani
Formato:	article
Lenguaje:	EN
Publicado:	Department of Chemistry, Universitas Gadjah Mada 2020
Materias:	ionic imprinted membrane gold metal ion transport selectivity binary metal ions Chemistry QD1-999
Acceso en línea:	https://doaj.org/article/35bb7ddc53104231bd3136014e24a003
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spelling	oai:doaj.org-article:35bb7ddc53104231bd3136014e24a0032021-12-02T16:11:23ZIn-Situ Ionic Imprinted Membrane (IIM) Synthesis Based on Acetic Polyeugenoxy Acetyl Tiophen Methanolate for Gold(III) Metal Ion Transports1411-94202460-157810.22146/ijc.49941https://doaj.org/article/35bb7ddc53104231bd3136014e24a0032020-04-01T00:00:00Zhttps://jurnal.ugm.ac.id/ijc/article/view/49941https://doaj.org/toc/1411-9420https://doaj.org/toc/2460-1578In this research, Polyeugenoxy Acetyl Tiophen Methanolate (PEATM)-Au ionic imprinted membrane (IIM) was synthesized. IIM is a PEATM based membrane that has Au(III) ion molds. The PEATM synthesis was analyzed using FTIR spectroscopy, and its relative molecular weight was determined by the viscometry method. To find out the presence of Au(III) templates on IIM, FTIR spectroscopy and SEM-EDX were used. The results of FTIR spectroscopy & SEM-EDX analysis prove the existence of Au(III) metal ion templates at IIM. Through FTIR spectra, it could be seen that the absorption area of the -OH group was widening. In the IIM, the CS group wave number (702.9 cm–1) also shifted to a larger wavenumber (848.68 cm–1), this is likely due to the presence of PEGDE as a crosslinker agent and PVA as a plasticizer on the membrane that interacts with PEATM-Au, which influences the shift of vibrational wavenumber of CS bonds. It was also found that the most effective pH of the feed phase for the transport was at pH 3, and the most optimum transport time was 24 h for IIM and 48 h for NIM. The transport of Au in binary mixture of Au/Cd, Au/Fe, and Au/Pb also proves that the presence of Au(III) ions in IIM makes IIM more selective to Au(III) metal ions than NIM when used for the transport process as it transports Au more than the other metals. These results were as expected by using the HSAB theory as its groundwork.Muhammad Cholid DjunaidiPardoyo PardoyoDidik Setiyo WidodoRetno Ariadi LusianaAnggun YulianiDepartment of Chemistry, Universitas Gadjah Madaarticleionic imprinted membranegold metal iontransportselectivitybinary metal ionsChemistryQD1-999ENIndonesian Journal of Chemistry, Vol 20, Iss 6, Pp 1323-1331 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	ionic imprinted membrane gold metal ion transport selectivity binary metal ions Chemistry QD1-999
spellingShingle	ionic imprinted membrane gold metal ion transport selectivity binary metal ions Chemistry QD1-999 Muhammad Cholid Djunaidi Pardoyo Pardoyo Didik Setiyo Widodo Retno Ariadi Lusiana Anggun Yuliani In-Situ Ionic Imprinted Membrane (IIM) Synthesis Based on Acetic Polyeugenoxy Acetyl Tiophen Methanolate for Gold(III) Metal Ion Transports
description	In this research, Polyeugenoxy Acetyl Tiophen Methanolate (PEATM)-Au ionic imprinted membrane (IIM) was synthesized. IIM is a PEATM based membrane that has Au(III) ion molds. The PEATM synthesis was analyzed using FTIR spectroscopy, and its relative molecular weight was determined by the viscometry method. To find out the presence of Au(III) templates on IIM, FTIR spectroscopy and SEM-EDX were used. The results of FTIR spectroscopy & SEM-EDX analysis prove the existence of Au(III) metal ion templates at IIM. Through FTIR spectra, it could be seen that the absorption area of the -OH group was widening. In the IIM, the CS group wave number (702.9 cm–1) also shifted to a larger wavenumber (848.68 cm–1), this is likely due to the presence of PEGDE as a crosslinker agent and PVA as a plasticizer on the membrane that interacts with PEATM-Au, which influences the shift of vibrational wavenumber of CS bonds. It was also found that the most effective pH of the feed phase for the transport was at pH 3, and the most optimum transport time was 24 h for IIM and 48 h for NIM. The transport of Au in binary mixture of Au/Cd, Au/Fe, and Au/Pb also proves that the presence of Au(III) ions in IIM makes IIM more selective to Au(III) metal ions than NIM when used for the transport process as it transports Au more than the other metals. These results were as expected by using the HSAB theory as its groundwork.
format	article
author	Muhammad Cholid Djunaidi Pardoyo Pardoyo Didik Setiyo Widodo Retno Ariadi Lusiana Anggun Yuliani
author_facet	Muhammad Cholid Djunaidi Pardoyo Pardoyo Didik Setiyo Widodo Retno Ariadi Lusiana Anggun Yuliani
author_sort	Muhammad Cholid Djunaidi
title	In-Situ Ionic Imprinted Membrane (IIM) Synthesis Based on Acetic Polyeugenoxy Acetyl Tiophen Methanolate for Gold(III) Metal Ion Transports
title_short	In-Situ Ionic Imprinted Membrane (IIM) Synthesis Based on Acetic Polyeugenoxy Acetyl Tiophen Methanolate for Gold(III) Metal Ion Transports
title_full	In-Situ Ionic Imprinted Membrane (IIM) Synthesis Based on Acetic Polyeugenoxy Acetyl Tiophen Methanolate for Gold(III) Metal Ion Transports
title_fullStr	In-Situ Ionic Imprinted Membrane (IIM) Synthesis Based on Acetic Polyeugenoxy Acetyl Tiophen Methanolate for Gold(III) Metal Ion Transports
title_full_unstemmed	In-Situ Ionic Imprinted Membrane (IIM) Synthesis Based on Acetic Polyeugenoxy Acetyl Tiophen Methanolate for Gold(III) Metal Ion Transports
title_sort	in-situ ionic imprinted membrane (iim) synthesis based on acetic polyeugenoxy acetyl tiophen methanolate for gold(iii) metal ion transports
publisher	Department of Chemistry, Universitas Gadjah Mada
publishDate	2020
url	https://doaj.org/article/35bb7ddc53104231bd3136014e24a003
work_keys_str_mv	AT muhammadcholiddjunaidi insituionicimprintedmembraneiimsynthesisbasedonaceticpolyeugenoxyacetyltiophenmethanolateforgoldiiimetaliontransports AT pardoyopardoyo insituionicimprintedmembraneiimsynthesisbasedonaceticpolyeugenoxyacetyltiophenmethanolateforgoldiiimetaliontransports AT didiksetiyowidodo insituionicimprintedmembraneiimsynthesisbasedonaceticpolyeugenoxyacetyltiophenmethanolateforgoldiiimetaliontransports AT retnoariadilusiana insituionicimprintedmembraneiimsynthesisbasedonaceticpolyeugenoxyacetyltiophenmethanolateforgoldiiimetaliontransports AT anggunyuliani insituionicimprintedmembraneiimsynthesisbasedonaceticpolyeugenoxyacetyltiophenmethanolateforgoldiiimetaliontransports
_version_	1718384402870829056

In-Situ Ionic Imprinted Membrane (IIM) Synthesis Based on Acetic Polyeugenoxy Acetyl Tiophen Methanolate for Gold(III) Metal Ion Transports

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