STUDY OF THE INFLUENCE OF MAGNESIUM HYDROXIDE ON THE COMBUSTIBILITY PERFORMANCE OF POLYMER COMPOSITIONS BASED ON ETHYLENE VINYL ACETATE COPOLYMER

Purpose. To obtain the flame retardants polymer compositions for cables tested the effect of use EVA compositions with magnesium hydroxide, on indicators combustibility polymer. Methodology. We used the method of differential scanning calorimetry and defined heat flux dependence on the test time for...

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Autores principales: E.V. Chuleyeva, V.M. Zolotaryov
Formato: article
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RU
UK
Publicado: National Technical University "Kharkiv Polytechnic Institute" 2017
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spelling oai:doaj.org-article:361839af5cbc424ab8137a952eea24752021-12-02T17:25:15ZSTUDY OF THE INFLUENCE OF MAGNESIUM HYDROXIDE ON THE COMBUSTIBILITY PERFORMANCE OF POLYMER COMPOSITIONS BASED ON ETHYLENE VINYL ACETATE COPOLYMER10.20998/2074-272X.2017.2.072074-272X2309-3404https://doaj.org/article/361839af5cbc424ab8137a952eea24752017-04-01T00:00:00Zhttp://eie.khpi.edu.ua/article/view/2074-272X.2017.2.07/95894https://doaj.org/toc/2074-272Xhttps://doaj.org/toc/2309-3404Purpose. To obtain the flame retardants polymer compositions for cables tested the effect of use EVA compositions with magnesium hydroxide, on indicators combustibility polymer. Methodology. We used the method of differential scanning calorimetry and defined heat flux dependence on the test time for each composition at temperatures from 20 °C to 600 °C rate of temperature rise: 50 °C/min, 75 °C/min, 100 °C/min. Using the model of free kinetics we determined dependence of the activation energy from the conversion, a dependence of the conversion on the time of the test, the dependence of the time of the conversion from the temperature for each concentration. To comparison of these parameters for each composition we plotted the dependence of the time of the conversion from the temperature and the dependence the degree of conversion from the time of temperature exposure during the combustion of each of the compositions. Results. We obtained the kinetic characteristics, allowing to determine the composition, which provided the best results to reducing the kinetic parameters of flammability of polymeric compositions. Originality. For the first time we used the DSC and model-free kinetics to determine the effect properties of ingredients of the polymer compositions on the combustibility performance. Practical use. The research results can be used to develop polymer compositions for cable products. E.V. ChuleyevaV.M. Zolotaryov National Technical University "Kharkiv Polytechnic Institute"articleethylene vinyl acetate copolymermagnesium hydroxidecombustibilitypolymeric compositionkineticsElectrical engineering. Electronics. Nuclear engineeringTK1-9971ENRUUKElectrical engineering & Electromechanics, Iss 2, Pp 43-48 (2017)
institution DOAJ
collection DOAJ
language EN
RU
UK
topic ethylene vinyl acetate copolymer
magnesium hydroxide
combustibility
polymeric composition
kinetics
Electrical engineering. Electronics. Nuclear engineering
TK1-9971
spellingShingle ethylene vinyl acetate copolymer
magnesium hydroxide
combustibility
polymeric composition
kinetics
Electrical engineering. Electronics. Nuclear engineering
TK1-9971
E.V. Chuleyeva
V.M. Zolotaryov
STUDY OF THE INFLUENCE OF MAGNESIUM HYDROXIDE ON THE COMBUSTIBILITY PERFORMANCE OF POLYMER COMPOSITIONS BASED ON ETHYLENE VINYL ACETATE COPOLYMER
description Purpose. To obtain the flame retardants polymer compositions for cables tested the effect of use EVA compositions with magnesium hydroxide, on indicators combustibility polymer. Methodology. We used the method of differential scanning calorimetry and defined heat flux dependence on the test time for each composition at temperatures from 20 °C to 600 °C rate of temperature rise: 50 °C/min, 75 °C/min, 100 °C/min. Using the model of free kinetics we determined dependence of the activation energy from the conversion, a dependence of the conversion on the time of the test, the dependence of the time of the conversion from the temperature for each concentration. To comparison of these parameters for each composition we plotted the dependence of the time of the conversion from the temperature and the dependence the degree of conversion from the time of temperature exposure during the combustion of each of the compositions. Results. We obtained the kinetic characteristics, allowing to determine the composition, which provided the best results to reducing the kinetic parameters of flammability of polymeric compositions. Originality. For the first time we used the DSC and model-free kinetics to determine the effect properties of ingredients of the polymer compositions on the combustibility performance. Practical use. The research results can be used to develop polymer compositions for cable products.
format article
author E.V. Chuleyeva
V.M. Zolotaryov
author_facet E.V. Chuleyeva
V.M. Zolotaryov
author_sort E.V. Chuleyeva
title STUDY OF THE INFLUENCE OF MAGNESIUM HYDROXIDE ON THE COMBUSTIBILITY PERFORMANCE OF POLYMER COMPOSITIONS BASED ON ETHYLENE VINYL ACETATE COPOLYMER
title_short STUDY OF THE INFLUENCE OF MAGNESIUM HYDROXIDE ON THE COMBUSTIBILITY PERFORMANCE OF POLYMER COMPOSITIONS BASED ON ETHYLENE VINYL ACETATE COPOLYMER
title_full STUDY OF THE INFLUENCE OF MAGNESIUM HYDROXIDE ON THE COMBUSTIBILITY PERFORMANCE OF POLYMER COMPOSITIONS BASED ON ETHYLENE VINYL ACETATE COPOLYMER
title_fullStr STUDY OF THE INFLUENCE OF MAGNESIUM HYDROXIDE ON THE COMBUSTIBILITY PERFORMANCE OF POLYMER COMPOSITIONS BASED ON ETHYLENE VINYL ACETATE COPOLYMER
title_full_unstemmed STUDY OF THE INFLUENCE OF MAGNESIUM HYDROXIDE ON THE COMBUSTIBILITY PERFORMANCE OF POLYMER COMPOSITIONS BASED ON ETHYLENE VINYL ACETATE COPOLYMER
title_sort study of the influence of magnesium hydroxide on the combustibility performance of polymer compositions based on ethylene vinyl acetate copolymer
publisher National Technical University "Kharkiv Polytechnic Institute"
publishDate 2017
url https://doaj.org/article/361839af5cbc424ab8137a952eea2475
work_keys_str_mv AT evchuleyeva studyoftheinfluenceofmagnesiumhydroxideonthecombustibilityperformanceofpolymercompositionsbasedonethylenevinylacetatecopolymer
AT vmzolotaryov studyoftheinfluenceofmagnesiumhydroxideonthecombustibilityperformanceofpolymercompositionsbasedonethylenevinylacetatecopolymer
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