Trapping gases in metal-organic frameworks with a selective surface molecular barrier layer

Metal-organic frameworks are extensively studied for gas storage applications, but one potential limitation is their relatively weak adsorption of gases. Here, the authors report that the exposure of metal-organic frameworks to ethylenediamine forms a monolayer thick cap which improves gas molecule...

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Autores principales: Kui Tan, Sebastian Zuluaga, Erika Fuentes, Eric C. Mattson, Jean-François Veyan, Hao Wang, Jing Li, Timo Thonhauser, Yves J. Chabal
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2016
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Acceso en línea:https://doaj.org/article/3647611553f742e5ad606ccdee0c0434
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Sumario:Metal-organic frameworks are extensively studied for gas storage applications, but one potential limitation is their relatively weak adsorption of gases. Here, the authors report that the exposure of metal-organic frameworks to ethylenediamine forms a monolayer thick cap which improves gas molecule retention.