Lignin Biopolymer for the Synthesis of Iron Nanoparticles and the Composite Applied for the Removal of Methylene Blue

In the current study, lignin, an abundant natural polymer, was dissolved in ethylene glycol and acidic H<sub>2</sub>O to form nanoscale lignin. Then, zero-valent iron (ZVI) nanoparticles were synthesized in nanoscale lignin, producing a nZVI/n-lignin composite, via the borohydride reduct...

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Autores principales: Fang-Yi Peng, Pei-Wen Wang, Weisheng Liao, Ing-Song Yu
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Publicado: MDPI AG 2021
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spelling oai:doaj.org-article:36bd4718180845d7a325b0bfdc308e7e2021-11-11T18:49:01ZLignin Biopolymer for the Synthesis of Iron Nanoparticles and the Composite Applied for the Removal of Methylene Blue10.3390/polym132138472073-4360https://doaj.org/article/36bd4718180845d7a325b0bfdc308e7e2021-11-01T00:00:00Zhttps://www.mdpi.com/2073-4360/13/21/3847https://doaj.org/toc/2073-4360In the current study, lignin, an abundant natural polymer, was dissolved in ethylene glycol and acidic H<sub>2</sub>O to form nanoscale lignin. Then, zero-valent iron (ZVI) nanoparticles were synthesized in nanoscale lignin, producing a nZVI/n-lignin composite, via the borohydride reduction method. The use of nZVI/n-lignin for environmental remediation was tested by the removal of methylene blue in aqueous solutions at room temperature. The nZVI/n-lignin composite achieved a higher methylene blue removal ratio than that achieved by traditional nZVIs. Moreover, its excellent dispersibility in water and stability against oxidation in the air were observed. The functions of the nanoscale lignin in the composite material are (1) prevention of further growth and aggregation of the nZVI nanoparticles, (2) protection of nZVI from serious oxidation by H<sub>2</sub>O/O<sub>2</sub>, and (3) allowing better dispersibility of nZVI in aqueous solutions. These three functions are important for the field applications of nZVI/n-lignin, namely, to travel long distances before making contact with environmental pollutants. The present method for producing nZVI/n-lignin is straightforward, and the combination of nZVI and lignin is an efficient and environmentally friendly material for environmental applications.Fang-Yi PengPei-Wen WangWeisheng LiaoIng-Song YuMDPI AGarticleligninzero valent ironnanoparticlesethylene glycolmethylene blueOrganic chemistryQD241-441ENPolymers, Vol 13, Iss 3847, p 3847 (2021)
institution DOAJ
collection DOAJ
language EN
topic lignin
zero valent iron
nanoparticles
ethylene glycol
methylene blue
Organic chemistry
QD241-441
spellingShingle lignin
zero valent iron
nanoparticles
ethylene glycol
methylene blue
Organic chemistry
QD241-441
Fang-Yi Peng
Pei-Wen Wang
Weisheng Liao
Ing-Song Yu
Lignin Biopolymer for the Synthesis of Iron Nanoparticles and the Composite Applied for the Removal of Methylene Blue
description In the current study, lignin, an abundant natural polymer, was dissolved in ethylene glycol and acidic H<sub>2</sub>O to form nanoscale lignin. Then, zero-valent iron (ZVI) nanoparticles were synthesized in nanoscale lignin, producing a nZVI/n-lignin composite, via the borohydride reduction method. The use of nZVI/n-lignin for environmental remediation was tested by the removal of methylene blue in aqueous solutions at room temperature. The nZVI/n-lignin composite achieved a higher methylene blue removal ratio than that achieved by traditional nZVIs. Moreover, its excellent dispersibility in water and stability against oxidation in the air were observed. The functions of the nanoscale lignin in the composite material are (1) prevention of further growth and aggregation of the nZVI nanoparticles, (2) protection of nZVI from serious oxidation by H<sub>2</sub>O/O<sub>2</sub>, and (3) allowing better dispersibility of nZVI in aqueous solutions. These three functions are important for the field applications of nZVI/n-lignin, namely, to travel long distances before making contact with environmental pollutants. The present method for producing nZVI/n-lignin is straightforward, and the combination of nZVI and lignin is an efficient and environmentally friendly material for environmental applications.
format article
author Fang-Yi Peng
Pei-Wen Wang
Weisheng Liao
Ing-Song Yu
author_facet Fang-Yi Peng
Pei-Wen Wang
Weisheng Liao
Ing-Song Yu
author_sort Fang-Yi Peng
title Lignin Biopolymer for the Synthesis of Iron Nanoparticles and the Composite Applied for the Removal of Methylene Blue
title_short Lignin Biopolymer for the Synthesis of Iron Nanoparticles and the Composite Applied for the Removal of Methylene Blue
title_full Lignin Biopolymer for the Synthesis of Iron Nanoparticles and the Composite Applied for the Removal of Methylene Blue
title_fullStr Lignin Biopolymer for the Synthesis of Iron Nanoparticles and the Composite Applied for the Removal of Methylene Blue
title_full_unstemmed Lignin Biopolymer for the Synthesis of Iron Nanoparticles and the Composite Applied for the Removal of Methylene Blue
title_sort lignin biopolymer for the synthesis of iron nanoparticles and the composite applied for the removal of methylene blue
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/36bd4718180845d7a325b0bfdc308e7e
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AT weishengliao ligninbiopolymerforthesynthesisofironnanoparticlesandthecompositeappliedfortheremovalofmethyleneblue
AT ingsongyu ligninbiopolymerforthesynthesisofironnanoparticlesandthecompositeappliedfortheremovalofmethyleneblue
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