Modifying electron transfer between photoredox and organocatalytic units via framework interpenetration for β-carbonyl functionalization

Metal organic frameworks are promising catalysts due to their porous structure and the possible incorporation of multiple active sites. Here, the authors show that interpenetrated metal-organic frameworks containing both a photocatalyst and an organocatalyst catalyse the β-alkylation of carbonyl com...

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Autores principales: Zhengqiang Xia, Cheng He, Xiaoge Wang, Chunying Duan
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2017
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Acceso en línea:https://doaj.org/article/36c17485147a4228a29370eb6205e355
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Sumario:Metal organic frameworks are promising catalysts due to their porous structure and the possible incorporation of multiple active sites. Here, the authors show that interpenetrated metal-organic frameworks containing both a photocatalyst and an organocatalyst catalyse the β-alkylation of carbonyl compounds.