Modifying electron transfer between photoredox and organocatalytic units via framework interpenetration for β-carbonyl functionalization

Metal organic frameworks are promising catalysts due to their porous structure and the possible incorporation of multiple active sites. Here, the authors show that interpenetrated metal-organic frameworks containing both a photocatalyst and an organocatalyst catalyse the β-alkylation of carbonyl com...

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Autores principales: Zhengqiang Xia, Cheng He, Xiaoge Wang, Chunying Duan
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2017
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Acceso en línea:https://doaj.org/article/36c17485147a4228a29370eb6205e355
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spelling oai:doaj.org-article:36c17485147a4228a29370eb6205e3552021-12-02T17:06:20ZModifying electron transfer between photoredox and organocatalytic units via framework interpenetration for β-carbonyl functionalization10.1038/s41467-017-00416-82041-1723https://doaj.org/article/36c17485147a4228a29370eb6205e3552017-08-01T00:00:00Zhttps://doi.org/10.1038/s41467-017-00416-8https://doaj.org/toc/2041-1723Metal organic frameworks are promising catalysts due to their porous structure and the possible incorporation of multiple active sites. Here, the authors show that interpenetrated metal-organic frameworks containing both a photocatalyst and an organocatalyst catalyse the β-alkylation of carbonyl compounds.Zhengqiang XiaCheng HeXiaoge WangChunying DuanNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-11 (2017)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Zhengqiang Xia
Cheng He
Xiaoge Wang
Chunying Duan
Modifying electron transfer between photoredox and organocatalytic units via framework interpenetration for β-carbonyl functionalization
description Metal organic frameworks are promising catalysts due to their porous structure and the possible incorporation of multiple active sites. Here, the authors show that interpenetrated metal-organic frameworks containing both a photocatalyst and an organocatalyst catalyse the β-alkylation of carbonyl compounds.
format article
author Zhengqiang Xia
Cheng He
Xiaoge Wang
Chunying Duan
author_facet Zhengqiang Xia
Cheng He
Xiaoge Wang
Chunying Duan
author_sort Zhengqiang Xia
title Modifying electron transfer between photoredox and organocatalytic units via framework interpenetration for β-carbonyl functionalization
title_short Modifying electron transfer between photoredox and organocatalytic units via framework interpenetration for β-carbonyl functionalization
title_full Modifying electron transfer between photoredox and organocatalytic units via framework interpenetration for β-carbonyl functionalization
title_fullStr Modifying electron transfer between photoredox and organocatalytic units via framework interpenetration for β-carbonyl functionalization
title_full_unstemmed Modifying electron transfer between photoredox and organocatalytic units via framework interpenetration for β-carbonyl functionalization
title_sort modifying electron transfer between photoredox and organocatalytic units via framework interpenetration for β-carbonyl functionalization
publisher Nature Portfolio
publishDate 2017
url https://doaj.org/article/36c17485147a4228a29370eb6205e355
work_keys_str_mv AT zhengqiangxia modifyingelectrontransferbetweenphotoredoxandorganocatalyticunitsviaframeworkinterpenetrationforbcarbonylfunctionalization
AT chenghe modifyingelectrontransferbetweenphotoredoxandorganocatalyticunitsviaframeworkinterpenetrationforbcarbonylfunctionalization
AT xiaogewang modifyingelectrontransferbetweenphotoredoxandorganocatalyticunitsviaframeworkinterpenetrationforbcarbonylfunctionalization
AT chunyingduan modifyingelectrontransferbetweenphotoredoxandorganocatalyticunitsviaframeworkinterpenetrationforbcarbonylfunctionalization
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