Modifying electron transfer between photoredox and organocatalytic units via framework interpenetration for β-carbonyl functionalization
Metal organic frameworks are promising catalysts due to their porous structure and the possible incorporation of multiple active sites. Here, the authors show that interpenetrated metal-organic frameworks containing both a photocatalyst and an organocatalyst catalyse the β-alkylation of carbonyl com...
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Nature Portfolio
2017
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oai:doaj.org-article:36c17485147a4228a29370eb6205e3552021-12-02T17:06:20ZModifying electron transfer between photoredox and organocatalytic units via framework interpenetration for β-carbonyl functionalization10.1038/s41467-017-00416-82041-1723https://doaj.org/article/36c17485147a4228a29370eb6205e3552017-08-01T00:00:00Zhttps://doi.org/10.1038/s41467-017-00416-8https://doaj.org/toc/2041-1723Metal organic frameworks are promising catalysts due to their porous structure and the possible incorporation of multiple active sites. Here, the authors show that interpenetrated metal-organic frameworks containing both a photocatalyst and an organocatalyst catalyse the β-alkylation of carbonyl compounds.Zhengqiang XiaCheng HeXiaoge WangChunying DuanNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-11 (2017) |
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Science Q Zhengqiang Xia Cheng He Xiaoge Wang Chunying Duan Modifying electron transfer between photoredox and organocatalytic units via framework interpenetration for β-carbonyl functionalization |
description |
Metal organic frameworks are promising catalysts due to their porous structure and the possible incorporation of multiple active sites. Here, the authors show that interpenetrated metal-organic frameworks containing both a photocatalyst and an organocatalyst catalyse the β-alkylation of carbonyl compounds. |
format |
article |
author |
Zhengqiang Xia Cheng He Xiaoge Wang Chunying Duan |
author_facet |
Zhengqiang Xia Cheng He Xiaoge Wang Chunying Duan |
author_sort |
Zhengqiang Xia |
title |
Modifying electron transfer between photoredox and organocatalytic units via framework interpenetration for β-carbonyl functionalization |
title_short |
Modifying electron transfer between photoredox and organocatalytic units via framework interpenetration for β-carbonyl functionalization |
title_full |
Modifying electron transfer between photoredox and organocatalytic units via framework interpenetration for β-carbonyl functionalization |
title_fullStr |
Modifying electron transfer between photoredox and organocatalytic units via framework interpenetration for β-carbonyl functionalization |
title_full_unstemmed |
Modifying electron transfer between photoredox and organocatalytic units via framework interpenetration for β-carbonyl functionalization |
title_sort |
modifying electron transfer between photoredox and organocatalytic units via framework interpenetration for β-carbonyl functionalization |
publisher |
Nature Portfolio |
publishDate |
2017 |
url |
https://doaj.org/article/36c17485147a4228a29370eb6205e355 |
work_keys_str_mv |
AT zhengqiangxia modifyingelectrontransferbetweenphotoredoxandorganocatalyticunitsviaframeworkinterpenetrationforbcarbonylfunctionalization AT chenghe modifyingelectrontransferbetweenphotoredoxandorganocatalyticunitsviaframeworkinterpenetrationforbcarbonylfunctionalization AT xiaogewang modifyingelectrontransferbetweenphotoredoxandorganocatalyticunitsviaframeworkinterpenetrationforbcarbonylfunctionalization AT chunyingduan modifyingelectrontransferbetweenphotoredoxandorganocatalyticunitsviaframeworkinterpenetrationforbcarbonylfunctionalization |
_version_ |
1718381605633916928 |