Electrodeposition, Characterization, and Corrosion Behavior of CoCrFeMnNi High-Entropy Alloy Thin Films

Potentiostatic electrodeposition was used to obtain CoCrFeMnNi high-entropy alloy (HEA) thin films on copper substrate. An electrolyte based on a DMSO (dimethyl sulfoxide)-CH<sub>3</sub>CN (acetonitrile) organic compound was used for the HEA deposition. The microstructure of the high-ent...

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Autores principales: Ana-Maria Julieta Popescu, Florina Branzoi, Ionut Constantin, Mihai Anastasescu, Marian Burada, Dumitru Mitrică, Ioana Anasiei, Mihai-Tudor Olaru, Virgil Constantin
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Publicado: MDPI AG 2021
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Acceso en línea:https://doaj.org/article/373fa51bead143249ac8ad7a12af0de5
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spelling oai:doaj.org-article:373fa51bead143249ac8ad7a12af0de52021-11-25T17:16:32ZElectrodeposition, Characterization, and Corrosion Behavior of CoCrFeMnNi High-Entropy Alloy Thin Films10.3390/coatings111113672079-6412https://doaj.org/article/373fa51bead143249ac8ad7a12af0de52021-11-01T00:00:00Zhttps://www.mdpi.com/2079-6412/11/11/1367https://doaj.org/toc/2079-6412Potentiostatic electrodeposition was used to obtain CoCrFeMnNi high-entropy alloy (HEA) thin films on copper substrate. An electrolyte based on a DMSO (dimethyl sulfoxide)-CH<sub>3</sub>CN (acetonitrile) organic compound was used for the HEA deposition. The microstructure of the high-entropy deposits before and after corrosion in artificial seawater was investigated by scanning electron microscopy (SEM) and energy dispersive spectrometry (EDS) investigation. SEM analysis revealed that compact and uniform film consists of compact and uniform 50 nm–5 μm particles that form the HEA films. The successful co-deposition of all five elements was highlighted by the energy dispersive spectrometry investigation (EDS). Electrochemical measurements carried out in an aerated artificial seawater solution under ambient conditions demonstrated the promising potential for application in the field of anti-corrosion protection, due to the protective behavior of the HEA thin films.Ana-Maria Julieta PopescuFlorina BranzoiIonut ConstantinMihai AnastasescuMarian BuradaDumitru MitricăIoana AnasieiMihai-Tudor OlaruVirgil ConstantinMDPI AGarticleelectrodepositionhigh-entropy alloythin filmssurface analysiscorrosion protectionEngineering (General). Civil engineering (General)TA1-2040ENCoatings, Vol 11, Iss 1367, p 1367 (2021)
institution DOAJ
collection DOAJ
language EN
topic electrodeposition
high-entropy alloy
thin films
surface analysis
corrosion protection
Engineering (General). Civil engineering (General)
TA1-2040
spellingShingle electrodeposition
high-entropy alloy
thin films
surface analysis
corrosion protection
Engineering (General). Civil engineering (General)
TA1-2040
Ana-Maria Julieta Popescu
Florina Branzoi
Ionut Constantin
Mihai Anastasescu
Marian Burada
Dumitru Mitrică
Ioana Anasiei
Mihai-Tudor Olaru
Virgil Constantin
Electrodeposition, Characterization, and Corrosion Behavior of CoCrFeMnNi High-Entropy Alloy Thin Films
description Potentiostatic electrodeposition was used to obtain CoCrFeMnNi high-entropy alloy (HEA) thin films on copper substrate. An electrolyte based on a DMSO (dimethyl sulfoxide)-CH<sub>3</sub>CN (acetonitrile) organic compound was used for the HEA deposition. The microstructure of the high-entropy deposits before and after corrosion in artificial seawater was investigated by scanning electron microscopy (SEM) and energy dispersive spectrometry (EDS) investigation. SEM analysis revealed that compact and uniform film consists of compact and uniform 50 nm–5 μm particles that form the HEA films. The successful co-deposition of all five elements was highlighted by the energy dispersive spectrometry investigation (EDS). Electrochemical measurements carried out in an aerated artificial seawater solution under ambient conditions demonstrated the promising potential for application in the field of anti-corrosion protection, due to the protective behavior of the HEA thin films.
format article
author Ana-Maria Julieta Popescu
Florina Branzoi
Ionut Constantin
Mihai Anastasescu
Marian Burada
Dumitru Mitrică
Ioana Anasiei
Mihai-Tudor Olaru
Virgil Constantin
author_facet Ana-Maria Julieta Popescu
Florina Branzoi
Ionut Constantin
Mihai Anastasescu
Marian Burada
Dumitru Mitrică
Ioana Anasiei
Mihai-Tudor Olaru
Virgil Constantin
author_sort Ana-Maria Julieta Popescu
title Electrodeposition, Characterization, and Corrosion Behavior of CoCrFeMnNi High-Entropy Alloy Thin Films
title_short Electrodeposition, Characterization, and Corrosion Behavior of CoCrFeMnNi High-Entropy Alloy Thin Films
title_full Electrodeposition, Characterization, and Corrosion Behavior of CoCrFeMnNi High-Entropy Alloy Thin Films
title_fullStr Electrodeposition, Characterization, and Corrosion Behavior of CoCrFeMnNi High-Entropy Alloy Thin Films
title_full_unstemmed Electrodeposition, Characterization, and Corrosion Behavior of CoCrFeMnNi High-Entropy Alloy Thin Films
title_sort electrodeposition, characterization, and corrosion behavior of cocrfemnni high-entropy alloy thin films
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/373fa51bead143249ac8ad7a12af0de5
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