Fuel Properties of Torrefied Biomass from <i>Sapindus</i> Pericarp Extraction Residue under a Wide Range of Pyrolysis Conditions

In this work, a novel biomass, the extraction residue of <i>S</i><i>apindus</i> pericarp (SP), was torrefied by using an electronic oven under a wide range of temperature (i.e., 200–320 °C) and residence times (i.e., 0–60 min). From the results of the thermogravimetric analys...

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Autores principales: Wen-Tien Tsai, Tasi-Jung Jiang, Yu-Quan Lin, Xiang Zhang, Kung-Sheng Yeh, Chi-Hung Tsai
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Publicado: MDPI AG 2021
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spelling oai:doaj.org-article:3783405bc1ef4215961c52232a9fde102021-11-11T15:54:50ZFuel Properties of Torrefied Biomass from <i>Sapindus</i> Pericarp Extraction Residue under a Wide Range of Pyrolysis Conditions10.3390/en142171221996-1073https://doaj.org/article/3783405bc1ef4215961c52232a9fde102021-11-01T00:00:00Zhttps://www.mdpi.com/1996-1073/14/21/7122https://doaj.org/toc/1996-1073In this work, a novel biomass, the extraction residue of <i>S</i><i>apindus</i> pericarp (SP), was torrefied by using an electronic oven under a wide range of temperature (i.e., 200–320 °C) and residence times (i.e., 0–60 min). From the results of the thermogravimetric analysis (TGA) of SP, a significant weight loss was observed in the temperature range of 200–400 °C, which can be divided into the decompositions of hemicellulose (major)/lignin (minor) (200–320 °C) and cellulose (major)/lignin (minor) (320–400 °C). Based on the fuel properties of the feedstock SP and SP-torrefied products, the optimal torrefaction conditions can be found at around 280 °C for holding 30 min, showing that the calorific value, enhancement factor and energy yield of the torrefied biomass were enhanced to be 28.60 MJ/kg, 1.36 and 82.04 wt%, respectively. Consistently, the values of the calorific value, carbon content and molar carbon/hydrogen (C/H) ratio indicated an increasing trend at higher torrefaction temperatures and/or longer residence times. The findings showed that some SP-torrefied solids can be grouped into the characteristics of a lignite-like biomass by a van Krevelen diagram for all the SP-torrefied products. However, the SP-torrefied fuels would be particularly susceptible to the problems of slagging and fouling because of the relatively high contents of potassium (K) and calcium (Ca) based on the analytical results of the energy dispersive X-ray spectroscopy (EDS).Wen-Tien TsaiTasi-Jung JiangYu-Quan LinXiang ZhangKung-Sheng YehChi-Hung TsaiMDPI AGarticle<i>Sapindus</i> pericarptorrefactionfuel propertysolid fuellignite-like biomassTechnologyTENEnergies, Vol 14, Iss 7122, p 7122 (2021)
institution DOAJ
collection DOAJ
language EN
topic <i>Sapindus</i> pericarp
torrefaction
fuel property
solid fuel
lignite-like biomass
Technology
T
spellingShingle <i>Sapindus</i> pericarp
torrefaction
fuel property
solid fuel
lignite-like biomass
Technology
T
Wen-Tien Tsai
Tasi-Jung Jiang
Yu-Quan Lin
Xiang Zhang
Kung-Sheng Yeh
Chi-Hung Tsai
Fuel Properties of Torrefied Biomass from <i>Sapindus</i> Pericarp Extraction Residue under a Wide Range of Pyrolysis Conditions
description In this work, a novel biomass, the extraction residue of <i>S</i><i>apindus</i> pericarp (SP), was torrefied by using an electronic oven under a wide range of temperature (i.e., 200–320 °C) and residence times (i.e., 0–60 min). From the results of the thermogravimetric analysis (TGA) of SP, a significant weight loss was observed in the temperature range of 200–400 °C, which can be divided into the decompositions of hemicellulose (major)/lignin (minor) (200–320 °C) and cellulose (major)/lignin (minor) (320–400 °C). Based on the fuel properties of the feedstock SP and SP-torrefied products, the optimal torrefaction conditions can be found at around 280 °C for holding 30 min, showing that the calorific value, enhancement factor and energy yield of the torrefied biomass were enhanced to be 28.60 MJ/kg, 1.36 and 82.04 wt%, respectively. Consistently, the values of the calorific value, carbon content and molar carbon/hydrogen (C/H) ratio indicated an increasing trend at higher torrefaction temperatures and/or longer residence times. The findings showed that some SP-torrefied solids can be grouped into the characteristics of a lignite-like biomass by a van Krevelen diagram for all the SP-torrefied products. However, the SP-torrefied fuels would be particularly susceptible to the problems of slagging and fouling because of the relatively high contents of potassium (K) and calcium (Ca) based on the analytical results of the energy dispersive X-ray spectroscopy (EDS).
format article
author Wen-Tien Tsai
Tasi-Jung Jiang
Yu-Quan Lin
Xiang Zhang
Kung-Sheng Yeh
Chi-Hung Tsai
author_facet Wen-Tien Tsai
Tasi-Jung Jiang
Yu-Quan Lin
Xiang Zhang
Kung-Sheng Yeh
Chi-Hung Tsai
author_sort Wen-Tien Tsai
title Fuel Properties of Torrefied Biomass from <i>Sapindus</i> Pericarp Extraction Residue under a Wide Range of Pyrolysis Conditions
title_short Fuel Properties of Torrefied Biomass from <i>Sapindus</i> Pericarp Extraction Residue under a Wide Range of Pyrolysis Conditions
title_full Fuel Properties of Torrefied Biomass from <i>Sapindus</i> Pericarp Extraction Residue under a Wide Range of Pyrolysis Conditions
title_fullStr Fuel Properties of Torrefied Biomass from <i>Sapindus</i> Pericarp Extraction Residue under a Wide Range of Pyrolysis Conditions
title_full_unstemmed Fuel Properties of Torrefied Biomass from <i>Sapindus</i> Pericarp Extraction Residue under a Wide Range of Pyrolysis Conditions
title_sort fuel properties of torrefied biomass from <i>sapindus</i> pericarp extraction residue under a wide range of pyrolysis conditions
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/3783405bc1ef4215961c52232a9fde10
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