Direct dehydrogenative alkyl Heck-couplings of vinylarenes with umpolung aldehydes catalyzed by nickel

Heck coupling of alkenes with organic halides, arenes or organometallics poses sustainability issues due to hazardous waste formation and use of oxidants. Here, the authors show an oxidant-free alkyl Heck-coupling of vinylarenes with umpolung aldehydes, liberating H2, N2 and H2O as sole side product...

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Autores principales:	Leiyang Lv, Dianhu Zhu, Chao-Jun Li
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2019
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/37a086ff19bf46e8a97886c45c65e674
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id	oai:doaj.org-article:37a086ff19bf46e8a97886c45c65e674
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spelling	oai:doaj.org-article:37a086ff19bf46e8a97886c45c65e6742021-12-02T14:38:59ZDirect dehydrogenative alkyl Heck-couplings of vinylarenes with umpolung aldehydes catalyzed by nickel10.1038/s41467-019-08631-12041-1723https://doaj.org/article/37a086ff19bf46e8a97886c45c65e6742019-02-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-08631-1https://doaj.org/toc/2041-1723Heck coupling of alkenes with organic halides, arenes or organometallics poses sustainability issues due to hazardous waste formation and use of oxidants. Here, the authors show an oxidant-free alkyl Heck-coupling of vinylarenes with umpolung aldehydes, liberating H2, N2 and H2O as sole side products.Leiyang LvDianhu ZhuChao-Jun LiNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-8 (2019)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Leiyang Lv Dianhu Zhu Chao-Jun Li Direct dehydrogenative alkyl Heck-couplings of vinylarenes with umpolung aldehydes catalyzed by nickel
description	Heck coupling of alkenes with organic halides, arenes or organometallics poses sustainability issues due to hazardous waste formation and use of oxidants. Here, the authors show an oxidant-free alkyl Heck-coupling of vinylarenes with umpolung aldehydes, liberating H2, N2 and H2O as sole side products.
format	article
author	Leiyang Lv Dianhu Zhu Chao-Jun Li
author_facet	Leiyang Lv Dianhu Zhu Chao-Jun Li
author_sort	Leiyang Lv
title	Direct dehydrogenative alkyl Heck-couplings of vinylarenes with umpolung aldehydes catalyzed by nickel
title_short	Direct dehydrogenative alkyl Heck-couplings of vinylarenes with umpolung aldehydes catalyzed by nickel
title_full	Direct dehydrogenative alkyl Heck-couplings of vinylarenes with umpolung aldehydes catalyzed by nickel
title_fullStr	Direct dehydrogenative alkyl Heck-couplings of vinylarenes with umpolung aldehydes catalyzed by nickel
title_full_unstemmed	Direct dehydrogenative alkyl Heck-couplings of vinylarenes with umpolung aldehydes catalyzed by nickel
title_sort	direct dehydrogenative alkyl heck-couplings of vinylarenes with umpolung aldehydes catalyzed by nickel
publisher	Nature Portfolio
publishDate	2019
url	https://doaj.org/article/37a086ff19bf46e8a97886c45c65e674
work_keys_str_mv	AT leiyanglv directdehydrogenativealkylheckcouplingsofvinylareneswithumpolungaldehydescatalyzedbynickel AT dianhuzhu directdehydrogenativealkylheckcouplingsofvinylareneswithumpolungaldehydescatalyzedbynickel AT chaojunli directdehydrogenativealkylheckcouplingsofvinylareneswithumpolungaldehydescatalyzedbynickel
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Direct dehydrogenative alkyl Heck-couplings of vinylarenes with umpolung aldehydes catalyzed by nickel

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