Chloride Ions’ Penetration of Fly Ash and Ground Granulated Blast Furnace Slags-Based Alkali-Activated Mortars

Due to the need to reduce the CO<sub>2</sub> emissions of mineral binders, researchers are considering the use of alkali-activated materials (AAMs) as an alternative to cementitious binders. The properties of AAMs can be more advantageous than those presented by cementitious binders, and...

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Autores principales: Patrycja Duży, Mateusz Sitarz, Marcin Adamczyk, Marta Choińska, Izabela Hager
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Lenguaje:EN
Publicado: MDPI AG 2021
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spelling oai:doaj.org-article:37d47a7947e5487cb3e2e71a8ca650f92021-11-11T18:07:49ZChloride Ions’ Penetration of Fly Ash and Ground Granulated Blast Furnace Slags-Based Alkali-Activated Mortars10.3390/ma142165831996-1944https://doaj.org/article/37d47a7947e5487cb3e2e71a8ca650f92021-11-01T00:00:00Zhttps://www.mdpi.com/1996-1944/14/21/6583https://doaj.org/toc/1996-1944Due to the need to reduce the CO<sub>2</sub> emissions of mineral binders, researchers are considering the use of alkali-activated materials (AAMs) as an alternative to cementitious binders. The properties of AAMs can be more advantageous than those presented by cementitious binders, and thus they can replace Portland cement binders in some applications. Mechanical tests of AAMs are being conducted on an ongoing basis; however, durability issues related to reinforcing steel in conditions in which steel members interact with chloride ions remain unsolved. In this paper, the precursors for AAM preparations are blends of fly ash (FA) and ground granulated blast-furnace slag (GGBFS) in four slag proportions: 0%, 10%, 30% and 50% expressed as a percent of FA mass. Four alkali-activated mortars were prepared, denominated as AAM 0, AAM 10, AAM 30 and AAM 50, respectively. Their basic physical and mechanical characteristics were investigated, as were their gas transport properties. The nitrogen Cembureau method was applied to determine the permeability of the mortar. The transport properties of the chloride ions were determined using the modified NT BUILD 492 migration test. The comparison of results obtained demonstrated a positive effect of GGBFS addition in terms of an increase in bulk density, permeability, porosity and, at the same time, a reduction in chloride ion penetration. The water absorption tests also provided insight into the open pore structures of mortars. The measurements revealed a strong dependence between fluid transport through the mortars and the water absorption and initial water content of materials.Patrycja DużyMateusz SitarzMarcin AdamczykMarta ChoińskaIzabela HagerMDPI AGarticlealkali-activated materialsfly ashchloride ionsgas permeabilitywater absorptionTechnologyTElectrical engineering. Electronics. Nuclear engineeringTK1-9971Engineering (General). Civil engineering (General)TA1-2040MicroscopyQH201-278.5Descriptive and experimental mechanicsQC120-168.85ENMaterials, Vol 14, Iss 6583, p 6583 (2021)
institution DOAJ
collection DOAJ
language EN
topic alkali-activated materials
fly ash
chloride ions
gas permeability
water absorption
Technology
T
Electrical engineering. Electronics. Nuclear engineering
TK1-9971
Engineering (General). Civil engineering (General)
TA1-2040
Microscopy
QH201-278.5
Descriptive and experimental mechanics
QC120-168.85
spellingShingle alkali-activated materials
fly ash
chloride ions
gas permeability
water absorption
Technology
T
Electrical engineering. Electronics. Nuclear engineering
TK1-9971
Engineering (General). Civil engineering (General)
TA1-2040
Microscopy
QH201-278.5
Descriptive and experimental mechanics
QC120-168.85
Patrycja Duży
Mateusz Sitarz
Marcin Adamczyk
Marta Choińska
Izabela Hager
Chloride Ions’ Penetration of Fly Ash and Ground Granulated Blast Furnace Slags-Based Alkali-Activated Mortars
description Due to the need to reduce the CO<sub>2</sub> emissions of mineral binders, researchers are considering the use of alkali-activated materials (AAMs) as an alternative to cementitious binders. The properties of AAMs can be more advantageous than those presented by cementitious binders, and thus they can replace Portland cement binders in some applications. Mechanical tests of AAMs are being conducted on an ongoing basis; however, durability issues related to reinforcing steel in conditions in which steel members interact with chloride ions remain unsolved. In this paper, the precursors for AAM preparations are blends of fly ash (FA) and ground granulated blast-furnace slag (GGBFS) in four slag proportions: 0%, 10%, 30% and 50% expressed as a percent of FA mass. Four alkali-activated mortars were prepared, denominated as AAM 0, AAM 10, AAM 30 and AAM 50, respectively. Their basic physical and mechanical characteristics were investigated, as were their gas transport properties. The nitrogen Cembureau method was applied to determine the permeability of the mortar. The transport properties of the chloride ions were determined using the modified NT BUILD 492 migration test. The comparison of results obtained demonstrated a positive effect of GGBFS addition in terms of an increase in bulk density, permeability, porosity and, at the same time, a reduction in chloride ion penetration. The water absorption tests also provided insight into the open pore structures of mortars. The measurements revealed a strong dependence between fluid transport through the mortars and the water absorption and initial water content of materials.
format article
author Patrycja Duży
Mateusz Sitarz
Marcin Adamczyk
Marta Choińska
Izabela Hager
author_facet Patrycja Duży
Mateusz Sitarz
Marcin Adamczyk
Marta Choińska
Izabela Hager
author_sort Patrycja Duży
title Chloride Ions’ Penetration of Fly Ash and Ground Granulated Blast Furnace Slags-Based Alkali-Activated Mortars
title_short Chloride Ions’ Penetration of Fly Ash and Ground Granulated Blast Furnace Slags-Based Alkali-Activated Mortars
title_full Chloride Ions’ Penetration of Fly Ash and Ground Granulated Blast Furnace Slags-Based Alkali-Activated Mortars
title_fullStr Chloride Ions’ Penetration of Fly Ash and Ground Granulated Blast Furnace Slags-Based Alkali-Activated Mortars
title_full_unstemmed Chloride Ions’ Penetration of Fly Ash and Ground Granulated Blast Furnace Slags-Based Alkali-Activated Mortars
title_sort chloride ions’ penetration of fly ash and ground granulated blast furnace slags-based alkali-activated mortars
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/37d47a7947e5487cb3e2e71a8ca650f9
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AT mateuszsitarz chlorideionspenetrationofflyashandgroundgranulatedblastfurnaceslagsbasedalkaliactivatedmortars
AT marcinadamczyk chlorideionspenetrationofflyashandgroundgranulatedblastfurnaceslagsbasedalkaliactivatedmortars
AT martachoinska chlorideionspenetrationofflyashandgroundgranulatedblastfurnaceslagsbasedalkaliactivatedmortars
AT izabelahager chlorideionspenetrationofflyashandgroundgranulatedblastfurnaceslagsbasedalkaliactivatedmortars
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