Self-Organized Micro-Spiral of Single-Walled Carbon Nanotubes
Abstract Single-walled carbon nanotubes (SWCNTs) are reported to spontaneously align in a rotational pattern by drying a liquid droplet of toluene containing polyfluorene as a dispersant. By situating a droplet of an SWCNT solution around a glass bead, spiral patterns are generated. The parallel ali...
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Nature Portfolio
2017
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oai:doaj.org-article:37d805092cbf4c0fb4018912e698e0122021-12-02T11:41:10ZSelf-Organized Micro-Spiral of Single-Walled Carbon Nanotubes10.1038/s41598-017-05558-92045-2322https://doaj.org/article/37d805092cbf4c0fb4018912e698e0122017-07-01T00:00:00Zhttps://doi.org/10.1038/s41598-017-05558-9https://doaj.org/toc/2045-2322Abstract Single-walled carbon nanotubes (SWCNTs) are reported to spontaneously align in a rotational pattern by drying a liquid droplet of toluene containing polyfluorene as a dispersant. By situating a droplet of an SWCNT solution around a glass bead, spiral patterns are generated. The parallel alignment of SWCNTs along one stripe of such a pattern is confirmed using scanning electron microscopy and polarized optical microscopy. The orientation order increases toward the outer edge of a stripe. The stripe width in the pattern is proportional to the solute concentration, and the width and position of the stripes follow geometric sequences. The growth of the rotational pattern is also observed in real time. The process of spiral pattern formation is visualized, indicating the role of the annihilation of counter-traveling accompanied by continuous depinning. The geometric sequences for the stripe width and position are explained by the near-constant traveling speed and solute enrichment at the droplet periphery.Keisuke MaeHidetoshi ToyamaErika Nawa-OkitaDaigo YamamotoYong-Jun ChenKenichi YoshikawaFumiyuki ToshimitsuNaotoshi NakashimaKazunari MatsudaAkihisa ShioiNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 7, Iss 1, Pp 1-12 (2017) |
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Medicine R Science Q Keisuke Mae Hidetoshi Toyama Erika Nawa-Okita Daigo Yamamoto Yong-Jun Chen Kenichi Yoshikawa Fumiyuki Toshimitsu Naotoshi Nakashima Kazunari Matsuda Akihisa Shioi Self-Organized Micro-Spiral of Single-Walled Carbon Nanotubes |
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Abstract Single-walled carbon nanotubes (SWCNTs) are reported to spontaneously align in a rotational pattern by drying a liquid droplet of toluene containing polyfluorene as a dispersant. By situating a droplet of an SWCNT solution around a glass bead, spiral patterns are generated. The parallel alignment of SWCNTs along one stripe of such a pattern is confirmed using scanning electron microscopy and polarized optical microscopy. The orientation order increases toward the outer edge of a stripe. The stripe width in the pattern is proportional to the solute concentration, and the width and position of the stripes follow geometric sequences. The growth of the rotational pattern is also observed in real time. The process of spiral pattern formation is visualized, indicating the role of the annihilation of counter-traveling accompanied by continuous depinning. The geometric sequences for the stripe width and position are explained by the near-constant traveling speed and solute enrichment at the droplet periphery. |
format |
article |
author |
Keisuke Mae Hidetoshi Toyama Erika Nawa-Okita Daigo Yamamoto Yong-Jun Chen Kenichi Yoshikawa Fumiyuki Toshimitsu Naotoshi Nakashima Kazunari Matsuda Akihisa Shioi |
author_facet |
Keisuke Mae Hidetoshi Toyama Erika Nawa-Okita Daigo Yamamoto Yong-Jun Chen Kenichi Yoshikawa Fumiyuki Toshimitsu Naotoshi Nakashima Kazunari Matsuda Akihisa Shioi |
author_sort |
Keisuke Mae |
title |
Self-Organized Micro-Spiral of Single-Walled Carbon Nanotubes |
title_short |
Self-Organized Micro-Spiral of Single-Walled Carbon Nanotubes |
title_full |
Self-Organized Micro-Spiral of Single-Walled Carbon Nanotubes |
title_fullStr |
Self-Organized Micro-Spiral of Single-Walled Carbon Nanotubes |
title_full_unstemmed |
Self-Organized Micro-Spiral of Single-Walled Carbon Nanotubes |
title_sort |
self-organized micro-spiral of single-walled carbon nanotubes |
publisher |
Nature Portfolio |
publishDate |
2017 |
url |
https://doaj.org/article/37d805092cbf4c0fb4018912e698e012 |
work_keys_str_mv |
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