Self-Organized Micro-Spiral of Single-Walled Carbon Nanotubes

Abstract Single-walled carbon nanotubes (SWCNTs) are reported to spontaneously align in a rotational pattern by drying a liquid droplet of toluene containing polyfluorene as a dispersant. By situating a droplet of an SWCNT solution around a glass bead, spiral patterns are generated. The parallel ali...

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Autores principales: Keisuke Mae, Hidetoshi Toyama, Erika Nawa-Okita, Daigo Yamamoto, Yong-Jun Chen, Kenichi Yoshikawa, Fumiyuki Toshimitsu, Naotoshi Nakashima, Kazunari Matsuda, Akihisa Shioi
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Publicado: Nature Portfolio 2017
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Acceso en línea:https://doaj.org/article/37d805092cbf4c0fb4018912e698e012
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spelling oai:doaj.org-article:37d805092cbf4c0fb4018912e698e0122021-12-02T11:41:10ZSelf-Organized Micro-Spiral of Single-Walled Carbon Nanotubes10.1038/s41598-017-05558-92045-2322https://doaj.org/article/37d805092cbf4c0fb4018912e698e0122017-07-01T00:00:00Zhttps://doi.org/10.1038/s41598-017-05558-9https://doaj.org/toc/2045-2322Abstract Single-walled carbon nanotubes (SWCNTs) are reported to spontaneously align in a rotational pattern by drying a liquid droplet of toluene containing polyfluorene as a dispersant. By situating a droplet of an SWCNT solution around a glass bead, spiral patterns are generated. The parallel alignment of SWCNTs along one stripe of such a pattern is confirmed using scanning electron microscopy and polarized optical microscopy. The orientation order increases toward the outer edge of a stripe. The stripe width in the pattern is proportional to the solute concentration, and the width and position of the stripes follow geometric sequences. The growth of the rotational pattern is also observed in real time. The process of spiral pattern formation is visualized, indicating the role of the annihilation of counter-traveling accompanied by continuous depinning. The geometric sequences for the stripe width and position are explained by the near-constant traveling speed and solute enrichment at the droplet periphery.Keisuke MaeHidetoshi ToyamaErika Nawa-OkitaDaigo YamamotoYong-Jun ChenKenichi YoshikawaFumiyuki ToshimitsuNaotoshi NakashimaKazunari MatsudaAkihisa ShioiNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 7, Iss 1, Pp 1-12 (2017)
institution DOAJ
collection DOAJ
language EN
topic Medicine
R
Science
Q
spellingShingle Medicine
R
Science
Q
Keisuke Mae
Hidetoshi Toyama
Erika Nawa-Okita
Daigo Yamamoto
Yong-Jun Chen
Kenichi Yoshikawa
Fumiyuki Toshimitsu
Naotoshi Nakashima
Kazunari Matsuda
Akihisa Shioi
Self-Organized Micro-Spiral of Single-Walled Carbon Nanotubes
description Abstract Single-walled carbon nanotubes (SWCNTs) are reported to spontaneously align in a rotational pattern by drying a liquid droplet of toluene containing polyfluorene as a dispersant. By situating a droplet of an SWCNT solution around a glass bead, spiral patterns are generated. The parallel alignment of SWCNTs along one stripe of such a pattern is confirmed using scanning electron microscopy and polarized optical microscopy. The orientation order increases toward the outer edge of a stripe. The stripe width in the pattern is proportional to the solute concentration, and the width and position of the stripes follow geometric sequences. The growth of the rotational pattern is also observed in real time. The process of spiral pattern formation is visualized, indicating the role of the annihilation of counter-traveling accompanied by continuous depinning. The geometric sequences for the stripe width and position are explained by the near-constant traveling speed and solute enrichment at the droplet periphery.
format article
author Keisuke Mae
Hidetoshi Toyama
Erika Nawa-Okita
Daigo Yamamoto
Yong-Jun Chen
Kenichi Yoshikawa
Fumiyuki Toshimitsu
Naotoshi Nakashima
Kazunari Matsuda
Akihisa Shioi
author_facet Keisuke Mae
Hidetoshi Toyama
Erika Nawa-Okita
Daigo Yamamoto
Yong-Jun Chen
Kenichi Yoshikawa
Fumiyuki Toshimitsu
Naotoshi Nakashima
Kazunari Matsuda
Akihisa Shioi
author_sort Keisuke Mae
title Self-Organized Micro-Spiral of Single-Walled Carbon Nanotubes
title_short Self-Organized Micro-Spiral of Single-Walled Carbon Nanotubes
title_full Self-Organized Micro-Spiral of Single-Walled Carbon Nanotubes
title_fullStr Self-Organized Micro-Spiral of Single-Walled Carbon Nanotubes
title_full_unstemmed Self-Organized Micro-Spiral of Single-Walled Carbon Nanotubes
title_sort self-organized micro-spiral of single-walled carbon nanotubes
publisher Nature Portfolio
publishDate 2017
url https://doaj.org/article/37d805092cbf4c0fb4018912e698e012
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