Studies of the potential of a native natural biosorbent for the elimination of an anionic textile dye Cibacron Blue in aqueous solution

Abstract This work is devoted to the adsorption of Cibacron Blue (CB) an anionic textile dye, on bean peel (BP) an agricultural waste with neither activation nor carbonization. The adsorption was realized in batch configuration at ambient temperature in acidic medium. The adsorbent was characterized...

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Autores principales: Hocine Grabi, Fazia Derridj, Wahiba Lemlikchi, Erwann Guénin
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Lenguaje:EN
Publicado: Nature Portfolio 2021
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Acceso en línea:https://doaj.org/article/381a57355bf1487a960b8170395c1df0
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spelling oai:doaj.org-article:381a57355bf1487a960b8170395c1df02021-12-02T14:41:52ZStudies of the potential of a native natural biosorbent for the elimination of an anionic textile dye Cibacron Blue in aqueous solution10.1038/s41598-021-88657-y2045-2322https://doaj.org/article/381a57355bf1487a960b8170395c1df02021-05-01T00:00:00Zhttps://doi.org/10.1038/s41598-021-88657-yhttps://doaj.org/toc/2045-2322Abstract This work is devoted to the adsorption of Cibacron Blue (CB) an anionic textile dye, on bean peel (BP) an agricultural waste with neither activation nor carbonization. The adsorption was realized in batch configuration at ambient temperature in acidic medium. The adsorbent was characterized by FTIR, SEM and BET analyses; the equilibrium isotherms and kinetics were also studied. It has been found that this waste could be used as a low-cost biosorbent for CB elimination under optimal working conditions. The rate of CB elimination reaches 95% on bean bark (3.6 g/L) at pH 2.2 and a reject concentration of 25 mg/L. The pseudo-second-order describes suitably the experimental data and the external diffusion is the rate-determining step. The Freundlich isotherm fits better the CB adsorption with a correlation coefficient (R2) of 0.94 and an RMSE = 1.5115. The negative enthalpy (ΔH) and free enthalpy (ΔG°) indicate a physical and spontaneous nature of the CB biosorption onto the biomaterial.Hocine GrabiFazia DerridjWahiba LemlikchiErwann GuéninNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 11, Iss 1, Pp 1-13 (2021)
institution DOAJ
collection DOAJ
language EN
topic Medicine
R
Science
Q
spellingShingle Medicine
R
Science
Q
Hocine Grabi
Fazia Derridj
Wahiba Lemlikchi
Erwann Guénin
Studies of the potential of a native natural biosorbent for the elimination of an anionic textile dye Cibacron Blue in aqueous solution
description Abstract This work is devoted to the adsorption of Cibacron Blue (CB) an anionic textile dye, on bean peel (BP) an agricultural waste with neither activation nor carbonization. The adsorption was realized in batch configuration at ambient temperature in acidic medium. The adsorbent was characterized by FTIR, SEM and BET analyses; the equilibrium isotherms and kinetics were also studied. It has been found that this waste could be used as a low-cost biosorbent for CB elimination under optimal working conditions. The rate of CB elimination reaches 95% on bean bark (3.6 g/L) at pH 2.2 and a reject concentration of 25 mg/L. The pseudo-second-order describes suitably the experimental data and the external diffusion is the rate-determining step. The Freundlich isotherm fits better the CB adsorption with a correlation coefficient (R2) of 0.94 and an RMSE = 1.5115. The negative enthalpy (ΔH) and free enthalpy (ΔG°) indicate a physical and spontaneous nature of the CB biosorption onto the biomaterial.
format article
author Hocine Grabi
Fazia Derridj
Wahiba Lemlikchi
Erwann Guénin
author_facet Hocine Grabi
Fazia Derridj
Wahiba Lemlikchi
Erwann Guénin
author_sort Hocine Grabi
title Studies of the potential of a native natural biosorbent for the elimination of an anionic textile dye Cibacron Blue in aqueous solution
title_short Studies of the potential of a native natural biosorbent for the elimination of an anionic textile dye Cibacron Blue in aqueous solution
title_full Studies of the potential of a native natural biosorbent for the elimination of an anionic textile dye Cibacron Blue in aqueous solution
title_fullStr Studies of the potential of a native natural biosorbent for the elimination of an anionic textile dye Cibacron Blue in aqueous solution
title_full_unstemmed Studies of the potential of a native natural biosorbent for the elimination of an anionic textile dye Cibacron Blue in aqueous solution
title_sort studies of the potential of a native natural biosorbent for the elimination of an anionic textile dye cibacron blue in aqueous solution
publisher Nature Portfolio
publishDate 2021
url https://doaj.org/article/381a57355bf1487a960b8170395c1df0
work_keys_str_mv AT hocinegrabi studiesofthepotentialofanativenaturalbiosorbentfortheeliminationofananionictextiledyecibacronblueinaqueoussolution
AT faziaderridj studiesofthepotentialofanativenaturalbiosorbentfortheeliminationofananionictextiledyecibacronblueinaqueoussolution
AT wahibalemlikchi studiesofthepotentialofanativenaturalbiosorbentfortheeliminationofananionictextiledyecibacronblueinaqueoussolution
AT erwannguenin studiesofthepotentialofanativenaturalbiosorbentfortheeliminationofananionictextiledyecibacronblueinaqueoussolution
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