Liquid-like cationic sub-lattice in copper selenide clusters
Copper selenide is super-ionic only at high temperatures. Here, the authors discover room temperature super-ionic behaviour in ultrasmall clusters of Cu2Se—but not in its larger or bulk forms—owing to an unusual liquid-like cationic sub-lattice, in which octahedral sites are stabilized by size-depen...
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Nature Portfolio
2017
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oai:doaj.org-article:38483a52f8c14ff296efc47379dff92f2021-12-02T17:06:00ZLiquid-like cationic sub-lattice in copper selenide clusters10.1038/ncomms145142041-1723https://doaj.org/article/38483a52f8c14ff296efc47379dff92f2017-02-01T00:00:00Zhttps://doi.org/10.1038/ncomms14514https://doaj.org/toc/2041-1723Copper selenide is super-ionic only at high temperatures. Here, the authors discover room temperature super-ionic behaviour in ultrasmall clusters of Cu2Se—but not in its larger or bulk forms—owing to an unusual liquid-like cationic sub-lattice, in which octahedral sites are stabilized by size-dependent compressive strain.Sarah L. WhiteProgna BanerjeePrashant K. JainNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-11 (2017) |
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Science Q Sarah L. White Progna Banerjee Prashant K. Jain Liquid-like cationic sub-lattice in copper selenide clusters |
description |
Copper selenide is super-ionic only at high temperatures. Here, the authors discover room temperature super-ionic behaviour in ultrasmall clusters of Cu2Se—but not in its larger or bulk forms—owing to an unusual liquid-like cationic sub-lattice, in which octahedral sites are stabilized by size-dependent compressive strain. |
format |
article |
author |
Sarah L. White Progna Banerjee Prashant K. Jain |
author_facet |
Sarah L. White Progna Banerjee Prashant K. Jain |
author_sort |
Sarah L. White |
title |
Liquid-like cationic sub-lattice in copper selenide clusters |
title_short |
Liquid-like cationic sub-lattice in copper selenide clusters |
title_full |
Liquid-like cationic sub-lattice in copper selenide clusters |
title_fullStr |
Liquid-like cationic sub-lattice in copper selenide clusters |
title_full_unstemmed |
Liquid-like cationic sub-lattice in copper selenide clusters |
title_sort |
liquid-like cationic sub-lattice in copper selenide clusters |
publisher |
Nature Portfolio |
publishDate |
2017 |
url |
https://doaj.org/article/38483a52f8c14ff296efc47379dff92f |
work_keys_str_mv |
AT sarahlwhite liquidlikecationicsublatticeincopperselenideclusters AT prognabanerjee liquidlikecationicsublatticeincopperselenideclusters AT prashantkjain liquidlikecationicsublatticeincopperselenideclusters |
_version_ |
1718381785210945536 |