Nanopore structure comparison between shale oil and shale gas: examples from the Bakken and Longmaxi Formations

Abstract In order to analyze and compare the differences in pore structures between shale gas and shale oil formations, a few samples from the Longmaxi and Bakken Formations were collected and studied using X-ray diffraction, LECO TOC measurement, gas adsorption and field-emission scanning electron...

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Autores principales: Kouqi Liu, Liang Wang, Mehdi Ostadhassan, Jie Zou, Bailey Bubach, Reza Rezaee
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Publicado: KeAi Communications Co., Ltd. 2018
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spelling oai:doaj.org-article:385cb30cd3cf45c1aa3c1d42cf07521c2021-12-02T10:01:11ZNanopore structure comparison between shale oil and shale gas: examples from the Bakken and Longmaxi Formations10.1007/s12182-018-0277-31672-51071995-8226https://doaj.org/article/385cb30cd3cf45c1aa3c1d42cf07521c2018-11-01T00:00:00Zhttp://link.springer.com/article/10.1007/s12182-018-0277-3https://doaj.org/toc/1672-5107https://doaj.org/toc/1995-8226Abstract In order to analyze and compare the differences in pore structures between shale gas and shale oil formations, a few samples from the Longmaxi and Bakken Formations were collected and studied using X-ray diffraction, LECO TOC measurement, gas adsorption and field-emission scanning electron microscope. The results show that samples from the Bakken Formation have a higher TOC than those from the Longmaxi Formation. The Longmaxi Formation has higher micropore volume and larger micropore surface area and exhibited a smaller average distribution of microsize pores compared to the Bakken Formation. Both formations have similar meso-macropore volume. The Longmaxi Formation has a much larger meso-macropore surface area, which is corresponding to a smaller average meso-macropore size. CO2 adsorption data processing shows that the pore size of the majority of the micropores in the samples from the Longmaxi Formation is less than 1 nm, while the pore size of the most of the micropores in the samples from the Bakken Formation is larger than 1 nm. Both formations have the same number of pore clusters in the 2–20 nm range, but the Bakken Formation has two additional pore size groups with mean pore size diameters larger than 20 nm. Multifractal analysis of pore size distribution curves that was derived from gas adsorption indicates that the samples from the Longmaxi Formation have more significant micropore heterogeneity and less meso-macropore heterogeneity. Abundant micropores as well as meso-macropores exist in the organic matter in the Longmaxi Formation, while the organic matter of the Bakken Formation hosts mainly micropores.Kouqi LiuLiang WangMehdi OstadhassanJie ZouBailey BubachReza RezaeeKeAi Communications Co., Ltd.articleShale gasShale oilPore structureGas adsorptionPore familyMultifractal analysisScienceQPetrologyQE420-499ENPetroleum Science, Vol 16, Iss 1, Pp 77-93 (2018)
institution DOAJ
collection DOAJ
language EN
topic Shale gas
Shale oil
Pore structure
Gas adsorption
Pore family
Multifractal analysis
Science
Q
Petrology
QE420-499
spellingShingle Shale gas
Shale oil
Pore structure
Gas adsorption
Pore family
Multifractal analysis
Science
Q
Petrology
QE420-499
Kouqi Liu
Liang Wang
Mehdi Ostadhassan
Jie Zou
Bailey Bubach
Reza Rezaee
Nanopore structure comparison between shale oil and shale gas: examples from the Bakken and Longmaxi Formations
description Abstract In order to analyze and compare the differences in pore structures between shale gas and shale oil formations, a few samples from the Longmaxi and Bakken Formations were collected and studied using X-ray diffraction, LECO TOC measurement, gas adsorption and field-emission scanning electron microscope. The results show that samples from the Bakken Formation have a higher TOC than those from the Longmaxi Formation. The Longmaxi Formation has higher micropore volume and larger micropore surface area and exhibited a smaller average distribution of microsize pores compared to the Bakken Formation. Both formations have similar meso-macropore volume. The Longmaxi Formation has a much larger meso-macropore surface area, which is corresponding to a smaller average meso-macropore size. CO2 adsorption data processing shows that the pore size of the majority of the micropores in the samples from the Longmaxi Formation is less than 1 nm, while the pore size of the most of the micropores in the samples from the Bakken Formation is larger than 1 nm. Both formations have the same number of pore clusters in the 2–20 nm range, but the Bakken Formation has two additional pore size groups with mean pore size diameters larger than 20 nm. Multifractal analysis of pore size distribution curves that was derived from gas adsorption indicates that the samples from the Longmaxi Formation have more significant micropore heterogeneity and less meso-macropore heterogeneity. Abundant micropores as well as meso-macropores exist in the organic matter in the Longmaxi Formation, while the organic matter of the Bakken Formation hosts mainly micropores.
format article
author Kouqi Liu
Liang Wang
Mehdi Ostadhassan
Jie Zou
Bailey Bubach
Reza Rezaee
author_facet Kouqi Liu
Liang Wang
Mehdi Ostadhassan
Jie Zou
Bailey Bubach
Reza Rezaee
author_sort Kouqi Liu
title Nanopore structure comparison between shale oil and shale gas: examples from the Bakken and Longmaxi Formations
title_short Nanopore structure comparison between shale oil and shale gas: examples from the Bakken and Longmaxi Formations
title_full Nanopore structure comparison between shale oil and shale gas: examples from the Bakken and Longmaxi Formations
title_fullStr Nanopore structure comparison between shale oil and shale gas: examples from the Bakken and Longmaxi Formations
title_full_unstemmed Nanopore structure comparison between shale oil and shale gas: examples from the Bakken and Longmaxi Formations
title_sort nanopore structure comparison between shale oil and shale gas: examples from the bakken and longmaxi formations
publisher KeAi Communications Co., Ltd.
publishDate 2018
url https://doaj.org/article/385cb30cd3cf45c1aa3c1d42cf07521c
work_keys_str_mv AT kouqiliu nanoporestructurecomparisonbetweenshaleoilandshalegasexamplesfromthebakkenandlongmaxiformations
AT liangwang nanoporestructurecomparisonbetweenshaleoilandshalegasexamplesfromthebakkenandlongmaxiformations
AT mehdiostadhassan nanoporestructurecomparisonbetweenshaleoilandshalegasexamplesfromthebakkenandlongmaxiformations
AT jiezou nanoporestructurecomparisonbetweenshaleoilandshalegasexamplesfromthebakkenandlongmaxiformations
AT baileybubach nanoporestructurecomparisonbetweenshaleoilandshalegasexamplesfromthebakkenandlongmaxiformations
AT rezarezaee nanoporestructurecomparisonbetweenshaleoilandshalegasexamplesfromthebakkenandlongmaxiformations
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