Optimising surface d charge of AuPd nanoalloy catalysts for enhanced catalytic activity
Understanding the catalytic mechanism of bimetallic nanocatalysts remains challenging. Here the authors demonstrate that the d-orbital charge on the surface of Pd in a well-defined AuPd nanoalloy serves as a descriptor to the adsorbate states and hence the catalytic performance.
Guardado en:
Autores principales: | , , , , , , , , , , |
---|---|
Formato: | article |
Lenguaje: | EN |
Publicado: |
Nature Portfolio
2019
|
Materias: | |
Acceso en línea: | https://doaj.org/article/393a7338b9444b94821651be1c9142cd |
Etiquetas: |
Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
|
id |
oai:doaj.org-article:393a7338b9444b94821651be1c9142cd |
---|---|
record_format |
dspace |
spelling |
oai:doaj.org-article:393a7338b9444b94821651be1c9142cd2021-12-02T15:35:07ZOptimising surface d charge of AuPd nanoalloy catalysts for enhanced catalytic activity10.1038/s41467-019-09421-52041-1723https://doaj.org/article/393a7338b9444b94821651be1c9142cd2019-03-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-09421-5https://doaj.org/toc/2041-1723Understanding the catalytic mechanism of bimetallic nanocatalysts remains challenging. Here the authors demonstrate that the d-orbital charge on the surface of Pd in a well-defined AuPd nanoalloy serves as a descriptor to the adsorbate states and hence the catalytic performance.Xiaojuan ZhuQishui GuoYafei SunShangjun ChenJian-Qiang WangMengmeng WuWenzhao FuYanqiang TangXuezhi DuanDe ChenYing WanNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-11 (2019) |
institution |
DOAJ |
collection |
DOAJ |
language |
EN |
topic |
Science Q |
spellingShingle |
Science Q Xiaojuan Zhu Qishui Guo Yafei Sun Shangjun Chen Jian-Qiang Wang Mengmeng Wu Wenzhao Fu Yanqiang Tang Xuezhi Duan De Chen Ying Wan Optimising surface d charge of AuPd nanoalloy catalysts for enhanced catalytic activity |
description |
Understanding the catalytic mechanism of bimetallic nanocatalysts remains challenging. Here the authors demonstrate that the d-orbital charge on the surface of Pd in a well-defined AuPd nanoalloy serves as a descriptor to the adsorbate states and hence the catalytic performance. |
format |
article |
author |
Xiaojuan Zhu Qishui Guo Yafei Sun Shangjun Chen Jian-Qiang Wang Mengmeng Wu Wenzhao Fu Yanqiang Tang Xuezhi Duan De Chen Ying Wan |
author_facet |
Xiaojuan Zhu Qishui Guo Yafei Sun Shangjun Chen Jian-Qiang Wang Mengmeng Wu Wenzhao Fu Yanqiang Tang Xuezhi Duan De Chen Ying Wan |
author_sort |
Xiaojuan Zhu |
title |
Optimising surface d charge of AuPd nanoalloy catalysts for enhanced catalytic activity |
title_short |
Optimising surface d charge of AuPd nanoalloy catalysts for enhanced catalytic activity |
title_full |
Optimising surface d charge of AuPd nanoalloy catalysts for enhanced catalytic activity |
title_fullStr |
Optimising surface d charge of AuPd nanoalloy catalysts for enhanced catalytic activity |
title_full_unstemmed |
Optimising surface d charge of AuPd nanoalloy catalysts for enhanced catalytic activity |
title_sort |
optimising surface d charge of aupd nanoalloy catalysts for enhanced catalytic activity |
publisher |
Nature Portfolio |
publishDate |
2019 |
url |
https://doaj.org/article/393a7338b9444b94821651be1c9142cd |
work_keys_str_mv |
AT xiaojuanzhu optimisingsurfacedchargeofaupdnanoalloycatalystsforenhancedcatalyticactivity AT qishuiguo optimisingsurfacedchargeofaupdnanoalloycatalystsforenhancedcatalyticactivity AT yafeisun optimisingsurfacedchargeofaupdnanoalloycatalystsforenhancedcatalyticactivity AT shangjunchen optimisingsurfacedchargeofaupdnanoalloycatalystsforenhancedcatalyticactivity AT jianqiangwang optimisingsurfacedchargeofaupdnanoalloycatalystsforenhancedcatalyticactivity AT mengmengwu optimisingsurfacedchargeofaupdnanoalloycatalystsforenhancedcatalyticactivity AT wenzhaofu optimisingsurfacedchargeofaupdnanoalloycatalystsforenhancedcatalyticactivity AT yanqiangtang optimisingsurfacedchargeofaupdnanoalloycatalystsforenhancedcatalyticactivity AT xuezhiduan optimisingsurfacedchargeofaupdnanoalloycatalystsforenhancedcatalyticactivity AT dechen optimisingsurfacedchargeofaupdnanoalloycatalystsforenhancedcatalyticactivity AT yingwan optimisingsurfacedchargeofaupdnanoalloycatalystsforenhancedcatalyticactivity |
_version_ |
1718386650653917184 |