Optimising surface d charge of AuPd nanoalloy catalysts for enhanced catalytic activity

Understanding the catalytic mechanism of bimetallic nanocatalysts remains challenging. Here the authors demonstrate that the d-orbital charge on the surface of Pd in a well-defined AuPd nanoalloy serves as a descriptor to the adsorbate states and hence the catalytic performance.

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Autores principales: Xiaojuan Zhu, Qishui Guo, Yafei Sun, Shangjun Chen, Jian-Qiang Wang, Mengmeng Wu, Wenzhao Fu, Yanqiang Tang, Xuezhi Duan, De Chen, Ying Wan
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2019
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Acceso en línea:https://doaj.org/article/393a7338b9444b94821651be1c9142cd
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spelling oai:doaj.org-article:393a7338b9444b94821651be1c9142cd2021-12-02T15:35:07ZOptimising surface d charge of AuPd nanoalloy catalysts for enhanced catalytic activity10.1038/s41467-019-09421-52041-1723https://doaj.org/article/393a7338b9444b94821651be1c9142cd2019-03-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-09421-5https://doaj.org/toc/2041-1723Understanding the catalytic mechanism of bimetallic nanocatalysts remains challenging. Here the authors demonstrate that the d-orbital charge on the surface of Pd in a well-defined AuPd nanoalloy serves as a descriptor to the adsorbate states and hence the catalytic performance.Xiaojuan ZhuQishui GuoYafei SunShangjun ChenJian-Qiang WangMengmeng WuWenzhao FuYanqiang TangXuezhi DuanDe ChenYing WanNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-11 (2019)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Xiaojuan Zhu
Qishui Guo
Yafei Sun
Shangjun Chen
Jian-Qiang Wang
Mengmeng Wu
Wenzhao Fu
Yanqiang Tang
Xuezhi Duan
De Chen
Ying Wan
Optimising surface d charge of AuPd nanoalloy catalysts for enhanced catalytic activity
description Understanding the catalytic mechanism of bimetallic nanocatalysts remains challenging. Here the authors demonstrate that the d-orbital charge on the surface of Pd in a well-defined AuPd nanoalloy serves as a descriptor to the adsorbate states and hence the catalytic performance.
format article
author Xiaojuan Zhu
Qishui Guo
Yafei Sun
Shangjun Chen
Jian-Qiang Wang
Mengmeng Wu
Wenzhao Fu
Yanqiang Tang
Xuezhi Duan
De Chen
Ying Wan
author_facet Xiaojuan Zhu
Qishui Guo
Yafei Sun
Shangjun Chen
Jian-Qiang Wang
Mengmeng Wu
Wenzhao Fu
Yanqiang Tang
Xuezhi Duan
De Chen
Ying Wan
author_sort Xiaojuan Zhu
title Optimising surface d charge of AuPd nanoalloy catalysts for enhanced catalytic activity
title_short Optimising surface d charge of AuPd nanoalloy catalysts for enhanced catalytic activity
title_full Optimising surface d charge of AuPd nanoalloy catalysts for enhanced catalytic activity
title_fullStr Optimising surface d charge of AuPd nanoalloy catalysts for enhanced catalytic activity
title_full_unstemmed Optimising surface d charge of AuPd nanoalloy catalysts for enhanced catalytic activity
title_sort optimising surface d charge of aupd nanoalloy catalysts for enhanced catalytic activity
publisher Nature Portfolio
publishDate 2019
url https://doaj.org/article/393a7338b9444b94821651be1c9142cd
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