Copper(I)-catalyzed asymmetric 1,6-conjugate allylation

Copper(I)-catalyzed asymmetric 1,6-conjugate allylation

Catalytic asymmetric conjugate allylation of unsaturated carbonyl compounds is usually difficult to achieve due to competing 1,2-addition. Here, the authors report a copper(I)-catalyzed asymmetric 1,6-conjugate allylation of 2,2-dimethyl-6-alkenyl-4H-1,3-dioxin-4-ones with good scope and high enanti...

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Autores principales: Chang-Yun Shi, Zhi-Zhou Pan, Ping Tian, Liang Yin
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2020
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Acceso en línea:https://doaj.org/article/39a60babeea245b0ad21ddf777b47158
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spelling oai:doaj.org-article:39a60babeea245b0ad21ddf777b471582021-12-02T15:33:50ZCopper(I)-catalyzed asymmetric 1,6-conjugate allylation10.1038/s41467-020-19293-92041-1723https://doaj.org/article/39a60babeea245b0ad21ddf777b471582020-10-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-19293-9https://doaj.org/toc/2041-1723Catalytic asymmetric conjugate allylation of unsaturated carbonyl compounds is usually difficult to achieve due to competing 1,2-addition. Here, the authors report a copper(I)-catalyzed asymmetric 1,6-conjugate allylation of 2,2-dimethyl-6-alkenyl-4H-1,3-dioxin-4-ones with good scope and high enantioselectivity.Chang-Yun ShiZhi-Zhou PanPing TianLiang YinNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-10 (2020)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Chang-Yun Shi
Zhi-Zhou Pan
Ping Tian
Liang Yin
Copper(I)-catalyzed asymmetric 1,6-conjugate allylation
description Catalytic asymmetric conjugate allylation of unsaturated carbonyl compounds is usually difficult to achieve due to competing 1,2-addition. Here, the authors report a copper(I)-catalyzed asymmetric 1,6-conjugate allylation of 2,2-dimethyl-6-alkenyl-4H-1,3-dioxin-4-ones with good scope and high enantioselectivity.
format article
author Chang-Yun Shi
Zhi-Zhou Pan
Ping Tian
Liang Yin
author_facet Chang-Yun Shi
Zhi-Zhou Pan
Ping Tian
Liang Yin
author_sort Chang-Yun Shi
title Copper(I)-catalyzed asymmetric 1,6-conjugate allylation
title_short Copper(I)-catalyzed asymmetric 1,6-conjugate allylation
title_full Copper(I)-catalyzed asymmetric 1,6-conjugate allylation
title_fullStr Copper(I)-catalyzed asymmetric 1,6-conjugate allylation
title_full_unstemmed Copper(I)-catalyzed asymmetric 1,6-conjugate allylation
title_sort copper(i)-catalyzed asymmetric 1,6-conjugate allylation
publisher Nature Portfolio
publishDate 2020
url https://doaj.org/article/39a60babeea245b0ad21ddf777b47158
work_keys_str_mv AT changyunshi coppericatalyzedasymmetric16conjugateallylation
AT zhizhoupan coppericatalyzedasymmetric16conjugateallylation
AT pingtian coppericatalyzedasymmetric16conjugateallylation
AT liangyin coppericatalyzedasymmetric16conjugateallylation
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