Catalytic N-radical cascade reaction of hydrazones by oxidative deprotonation electron transfer and TEMPO mediation

The use of N-centred radicals is limited by the difficulties in their preparation. Here, the authors report a photoredox method for the formation of N-centred radicals on hydrazones and their use for the synthesis of heterocyclic compounds through a radical cascade reaction.

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Detalles Bibliográficos
Autores principales: Xiao-Qiang Hu, Xiaotian Qi, Jia-Rong Chen, Quan-Qing Zhao, Qiang Wei, Yu Lan, Wen-Jing Xiao
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2016
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Acceso en línea:https://doaj.org/article/39bf6059c2b54846a1580653b55abaac
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Sumario:The use of N-centred radicals is limited by the difficulties in their preparation. Here, the authors report a photoredox method for the formation of N-centred radicals on hydrazones and their use for the synthesis of heterocyclic compounds through a radical cascade reaction.