Catalytic N-radical cascade reaction of hydrazones by oxidative deprotonation electron transfer and TEMPO mediation

The use of N-centred radicals is limited by the difficulties in their preparation. Here, the authors report a photoredox method for the formation of N-centred radicals on hydrazones and their use for the synthesis of heterocyclic compounds through a radical cascade reaction.

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Autores principales:	Xiao-Qiang Hu, Xiaotian Qi, Jia-Rong Chen, Quan-Qing Zhao, Qiang Wei, Yu Lan, Wen-Jing Xiao
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2016
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/39bf6059c2b54846a1580653b55abaac
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spelling	oai:doaj.org-article:39bf6059c2b54846a1580653b55abaac2021-12-02T16:58:12ZCatalytic N-radical cascade reaction of hydrazones by oxidative deprotonation electron transfer and TEMPO mediation10.1038/ncomms111882041-1723https://doaj.org/article/39bf6059c2b54846a1580653b55abaac2016-04-01T00:00:00Zhttps://doi.org/10.1038/ncomms11188https://doaj.org/toc/2041-1723The use of N-centred radicals is limited by the difficulties in their preparation. Here, the authors report a photoredox method for the formation of N-centred radicals on hydrazones and their use for the synthesis of heterocyclic compounds through a radical cascade reaction.Xiao-Qiang HuXiaotian QiJia-Rong ChenQuan-Qing ZhaoQiang WeiYu LanWen-Jing XiaoNature PortfolioarticleScienceQENNature Communications, Vol 7, Iss 1, Pp 1-12 (2016)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Xiao-Qiang Hu Xiaotian Qi Jia-Rong Chen Quan-Qing Zhao Qiang Wei Yu Lan Wen-Jing Xiao Catalytic N-radical cascade reaction of hydrazones by oxidative deprotonation electron transfer and TEMPO mediation
description	The use of N-centred radicals is limited by the difficulties in their preparation. Here, the authors report a photoredox method for the formation of N-centred radicals on hydrazones and their use for the synthesis of heterocyclic compounds through a radical cascade reaction.
format	article
author	Xiao-Qiang Hu Xiaotian Qi Jia-Rong Chen Quan-Qing Zhao Qiang Wei Yu Lan Wen-Jing Xiao
author_facet	Xiao-Qiang Hu Xiaotian Qi Jia-Rong Chen Quan-Qing Zhao Qiang Wei Yu Lan Wen-Jing Xiao
author_sort	Xiao-Qiang Hu
title	Catalytic N-radical cascade reaction of hydrazones by oxidative deprotonation electron transfer and TEMPO mediation
title_short	Catalytic N-radical cascade reaction of hydrazones by oxidative deprotonation electron transfer and TEMPO mediation
title_full	Catalytic N-radical cascade reaction of hydrazones by oxidative deprotonation electron transfer and TEMPO mediation
title_fullStr	Catalytic N-radical cascade reaction of hydrazones by oxidative deprotonation electron transfer and TEMPO mediation
title_full_unstemmed	Catalytic N-radical cascade reaction of hydrazones by oxidative deprotonation electron transfer and TEMPO mediation
title_sort	catalytic n-radical cascade reaction of hydrazones by oxidative deprotonation electron transfer and tempo mediation
publisher	Nature Portfolio
publishDate	2016
url	https://doaj.org/article/39bf6059c2b54846a1580653b55abaac
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Catalytic N-radical cascade reaction of hydrazones by oxidative deprotonation electron transfer and TEMPO mediation

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