Low-temperature paddlewheel effect in glassy solid electrolytes

Glasses are promising electrolytes for solid-state lithium batteries; however, due to their amorphous structure, the ionic conduction mechanism remains poorly understood. Here, atomic-scale modeling reveals that lithium migration occurs via concerted hopping of Li-ions coupled to quasi-permanent rot...

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Autores principales:	Jeffrey G. Smith, Donald J. Siegel
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2020
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/39d0ef583f834a68a2db9cd0d4955d3e
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id	oai:doaj.org-article:39d0ef583f834a68a2db9cd0d4955d3e
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spelling	oai:doaj.org-article:39d0ef583f834a68a2db9cd0d4955d3e2021-12-02T14:42:12ZLow-temperature paddlewheel effect in glassy solid electrolytes10.1038/s41467-020-15245-52041-1723https://doaj.org/article/39d0ef583f834a68a2db9cd0d4955d3e2020-03-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-15245-5https://doaj.org/toc/2041-1723Glasses are promising electrolytes for solid-state lithium batteries; however, due to their amorphous structure, the ionic conduction mechanism remains poorly understood. Here, atomic-scale modeling reveals that lithium migration occurs via concerted hopping of Li-ions coupled to quasi-permanent rotations of tetrahedral anions.Jeffrey G. SmithDonald J. SiegelNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-11 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Jeffrey G. Smith Donald J. Siegel Low-temperature paddlewheel effect in glassy solid electrolytes
description	Glasses are promising electrolytes for solid-state lithium batteries; however, due to their amorphous structure, the ionic conduction mechanism remains poorly understood. Here, atomic-scale modeling reveals that lithium migration occurs via concerted hopping of Li-ions coupled to quasi-permanent rotations of tetrahedral anions.
format	article
author	Jeffrey G. Smith Donald J. Siegel
author_facet	Jeffrey G. Smith Donald J. Siegel
author_sort	Jeffrey G. Smith
title	Low-temperature paddlewheel effect in glassy solid electrolytes
title_short	Low-temperature paddlewheel effect in glassy solid electrolytes
title_full	Low-temperature paddlewheel effect in glassy solid electrolytes
title_fullStr	Low-temperature paddlewheel effect in glassy solid electrolytes
title_full_unstemmed	Low-temperature paddlewheel effect in glassy solid electrolytes
title_sort	low-temperature paddlewheel effect in glassy solid electrolytes
publisher	Nature Portfolio
publishDate	2020
url	https://doaj.org/article/39d0ef583f834a68a2db9cd0d4955d3e
work_keys_str_mv	AT jeffreygsmith lowtemperaturepaddlewheeleffectinglassysolidelectrolytes AT donaldjsiegel lowtemperaturepaddlewheeleffectinglassysolidelectrolytes
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Low-temperature paddlewheel effect in glassy solid electrolytes

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