Synthesis of Fe(II)/Co(II)-Fused Triphenyl Porphyrin Dimer as Candidate for Oxygen Reduction Reaction Catalyst

This paper reports the synthesis of Fe(II)/Co(II) fused triphenyl porphyrin dimers as candidate of hybrid organic metal electrocatalyst. The synthesis was conducted in five-step reactions using the starting materials pyrrole and benzaldehyde. The fuse oxidative reaction was done via free-base form o...

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Autores principales:	Atmanto Heru Wibowo, Anggit Pradifta, Abu Masykur, Ken-ichi Yamashita, Yosuke Tani, Ari Yustisia Akbar, Takuji Ogawa
Formato:	article
Lenguaje:	EN
Publicado:	Department of Chemistry, Universitas Gadjah Mada 2021
Materias:	fused triphenyl porphyrin metal insertion oxidative reaction planar structure Chemistry QD1-999
Acceso en línea:	https://doaj.org/article/39de4b8c4f364d8eaab1ffe83e945a2d
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spelling	oai:doaj.org-article:39de4b8c4f364d8eaab1ffe83e945a2d2021-12-02T16:25:41ZSynthesis of Fe(II)/Co(II)-Fused Triphenyl Porphyrin Dimer as Candidate for Oxygen Reduction Reaction Catalyst1411-94202460-157810.22146/ijc.61671https://doaj.org/article/39de4b8c4f364d8eaab1ffe83e945a2d2021-07-01T00:00:00Zhttps://jurnal.ugm.ac.id/ijc/article/view/61671https://doaj.org/toc/1411-9420https://doaj.org/toc/2460-1578This paper reports the synthesis of Fe(II)/Co(II) fused triphenyl porphyrin dimers as candidate of hybrid organic metal electrocatalyst. The synthesis was conducted in five-step reactions using the starting materials pyrrole and benzaldehyde. The fuse oxidative reaction was done via free-base form of triphenyl porphyrin to omit metal insertions/removals of intermediate products. This strategy is very beneficial for the synthesis of metal fused triphenyl porphyrin that needs less reactions where phenyliodine(III) bis(trifluoroacetate) (PIFA) was successfully deployed in the oxidative reaction of two free-base triphenyl porphyrins. Here, the comparisons of NMR spectra were presented to see the changes of the starting material to the product. Initial electrochemical tests showed that reduction current of planar structure of Fe/Co fused triphenyl porphyrin dimer was on the potential range at -1.10 V to 0.45 V vs Au. Fe-fused triphenyl porphyrin dimer with 7.58 × 10–4 A (-1.05 V) showed slightly better performance than Co-fused triphenyl porphyrin dimer with 5.67 × 10–4 A (-0.97 V).Atmanto Heru WibowoAnggit PradiftaAbu MasykurKen-ichi YamashitaYosuke TaniAri Yustisia AkbarTakuji OgawaDepartment of Chemistry, Universitas Gadjah Madaarticlefused triphenyl porphyrinmetal insertionoxidative reactionplanar structureChemistryQD1-999ENIndonesian Journal of Chemistry, Vol 21, Iss 4, Pp 871-881 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	fused triphenyl porphyrin metal insertion oxidative reaction planar structure Chemistry QD1-999
spellingShingle	fused triphenyl porphyrin metal insertion oxidative reaction planar structure Chemistry QD1-999 Atmanto Heru Wibowo Anggit Pradifta Abu Masykur Ken-ichi Yamashita Yosuke Tani Ari Yustisia Akbar Takuji Ogawa Synthesis of Fe(II)/Co(II)-Fused Triphenyl Porphyrin Dimer as Candidate for Oxygen Reduction Reaction Catalyst
description	This paper reports the synthesis of Fe(II)/Co(II) fused triphenyl porphyrin dimers as candidate of hybrid organic metal electrocatalyst. The synthesis was conducted in five-step reactions using the starting materials pyrrole and benzaldehyde. The fuse oxidative reaction was done via free-base form of triphenyl porphyrin to omit metal insertions/removals of intermediate products. This strategy is very beneficial for the synthesis of metal fused triphenyl porphyrin that needs less reactions where phenyliodine(III) bis(trifluoroacetate) (PIFA) was successfully deployed in the oxidative reaction of two free-base triphenyl porphyrins. Here, the comparisons of NMR spectra were presented to see the changes of the starting material to the product. Initial electrochemical tests showed that reduction current of planar structure of Fe/Co fused triphenyl porphyrin dimer was on the potential range at -1.10 V to 0.45 V vs Au. Fe-fused triphenyl porphyrin dimer with 7.58 × 10–4 A (-1.05 V) showed slightly better performance than Co-fused triphenyl porphyrin dimer with 5.67 × 10–4 A (-0.97 V).
format	article
author	Atmanto Heru Wibowo Anggit Pradifta Abu Masykur Ken-ichi Yamashita Yosuke Tani Ari Yustisia Akbar Takuji Ogawa
author_facet	Atmanto Heru Wibowo Anggit Pradifta Abu Masykur Ken-ichi Yamashita Yosuke Tani Ari Yustisia Akbar Takuji Ogawa
author_sort	Atmanto Heru Wibowo
title	Synthesis of Fe(II)/Co(II)-Fused Triphenyl Porphyrin Dimer as Candidate for Oxygen Reduction Reaction Catalyst
title_short	Synthesis of Fe(II)/Co(II)-Fused Triphenyl Porphyrin Dimer as Candidate for Oxygen Reduction Reaction Catalyst
title_full	Synthesis of Fe(II)/Co(II)-Fused Triphenyl Porphyrin Dimer as Candidate for Oxygen Reduction Reaction Catalyst
title_fullStr	Synthesis of Fe(II)/Co(II)-Fused Triphenyl Porphyrin Dimer as Candidate for Oxygen Reduction Reaction Catalyst
title_full_unstemmed	Synthesis of Fe(II)/Co(II)-Fused Triphenyl Porphyrin Dimer as Candidate for Oxygen Reduction Reaction Catalyst
title_sort	synthesis of fe(ii)/co(ii)-fused triphenyl porphyrin dimer as candidate for oxygen reduction reaction catalyst
publisher	Department of Chemistry, Universitas Gadjah Mada
publishDate	2021
url	https://doaj.org/article/39de4b8c4f364d8eaab1ffe83e945a2d
work_keys_str_mv	AT atmantoheruwibowo synthesisoffeiicoiifusedtriphenylporphyrindimerascandidateforoxygenreductionreactioncatalyst AT anggitpradifta synthesisoffeiicoiifusedtriphenylporphyrindimerascandidateforoxygenreductionreactioncatalyst AT abumasykur synthesisoffeiicoiifusedtriphenylporphyrindimerascandidateforoxygenreductionreactioncatalyst AT kenichiyamashita synthesisoffeiicoiifusedtriphenylporphyrindimerascandidateforoxygenreductionreactioncatalyst AT yosuketani synthesisoffeiicoiifusedtriphenylporphyrindimerascandidateforoxygenreductionreactioncatalyst AT ariyustisiaakbar synthesisoffeiicoiifusedtriphenylporphyrindimerascandidateforoxygenreductionreactioncatalyst AT takujiogawa synthesisoffeiicoiifusedtriphenylporphyrindimerascandidateforoxygenreductionreactioncatalyst
_version_	1718384045779320832

Synthesis of Fe(II)/Co(II)-Fused Triphenyl Porphyrin Dimer as Candidate for Oxygen Reduction Reaction Catalyst

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