Co(II) coordination networks based on two rigiddicarboxylic acids: synthesis, structures, and applications: a literature over view (2005-2015)

Co(II) coordination networks as an integral part of metal-organic materials have been in focus of materials scientists and crystal engineers for the last two decades. This interest stems not only from their reported fascinating architectures and remarkable adsorption properties being the inherent pr...

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Autor principal:	Chişca, Diana
Formato:	article
Lenguaje:	EN
Publicado:	D.Ghitu Institute of Electronic Engineering and Nanotechnologies 2015
Materias:	Physics QC1-999 Electronics TK7800-8360
Acceso en línea:	https://doaj.org/article/3a489d8c579045089812387784f41426
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spelling	oai:doaj.org-article:3a489d8c579045089812387784f414262021-11-21T11:58:25ZCo(II) coordination networks based on two rigiddicarboxylic acids: synthesis, structures, and applications: a literature over view (2005-2015)53:544.22537-63651810-648Xhttps://doaj.org/article/3a489d8c579045089812387784f414262015-11-01T00:00:00Zhttps://mjps.nanotech.md/archive/2015/article/43387https://doaj.org/toc/1810-648Xhttps://doaj.org/toc/2537-6365Co(II) coordination networks as an integral part of metal-organic materials have been in focus of materials scientists and crystal engineers for the last two decades. This interest stems not only from their reported fascinating architectures and remarkable adsorption properties being the inherent properties of the majority of the so far known metal-organic frameworks, but also from the unique place that Co(II) atom occupies among the transition metals due to its pronounced magnetic properties and colorimetric features. This review highlights the Co(II) mixed-ligand polymeric dicarboxylates built on two rigid dicarboxylic acids, the widely used 1,4-benzenedicarboxylic acid (H2bdc) and its closest analogue, 4,4'-biphenyldicarboxylic acid (H2bpdc) that have been reported in the past 10 years. It is focused on: (1) the nature and coordination abilities of Co(II); (2) the synthetic pathways; (3) the impact of size and rigidity of the spacer ligands in the generated coordination networks; (4) examples of one-, two- and three-dimensional coordination polymers; and (5) potential applications of Co(II) coordination polymers. Chişca, DianaD.Ghitu Institute of Electronic Engineering and NanotechnologiesarticlePhysicsQC1-999ElectronicsTK7800-8360ENMoldavian Journal of the Physical Sciences, Vol 14, Iss 1-2, Pp 14-34 (2015)
institution	DOAJ
collection	DOAJ
language	EN
topic	Physics QC1-999 Electronics TK7800-8360
spellingShingle	Physics QC1-999 Electronics TK7800-8360 Chişca, Diana Co(II) coordination networks based on two rigiddicarboxylic acids: synthesis, structures, and applications: a literature over view (2005-2015)
description	Co(II) coordination networks as an integral part of metal-organic materials have been in focus of materials scientists and crystal engineers for the last two decades. This interest stems not only from their reported fascinating architectures and remarkable adsorption properties being the inherent properties of the majority of the so far known metal-organic frameworks, but also from the unique place that Co(II) atom occupies among the transition metals due to its pronounced magnetic properties and colorimetric features. This review highlights the Co(II) mixed-ligand polymeric dicarboxylates built on two rigid dicarboxylic acids, the widely used 1,4-benzenedicarboxylic acid (H2bdc) and its closest analogue, 4,4'-biphenyldicarboxylic acid (H2bpdc) that have been reported in the past 10 years. It is focused on: (1) the nature and coordination abilities of Co(II); (2) the synthetic pathways; (3) the impact of size and rigidity of the spacer ligands in the generated coordination networks; (4) examples of one-, two- and three-dimensional coordination polymers; and (5) potential applications of Co(II) coordination polymers.
format	article
author	Chişca, Diana
author_facet	Chişca, Diana
author_sort	Chişca, Diana
title	Co(II) coordination networks based on two rigiddicarboxylic acids: synthesis, structures, and applications: a literature over view (2005-2015)
title_short	Co(II) coordination networks based on two rigiddicarboxylic acids: synthesis, structures, and applications: a literature over view (2005-2015)
title_full	Co(II) coordination networks based on two rigiddicarboxylic acids: synthesis, structures, and applications: a literature over view (2005-2015)
title_fullStr	Co(II) coordination networks based on two rigiddicarboxylic acids: synthesis, structures, and applications: a literature over view (2005-2015)
title_full_unstemmed	Co(II) coordination networks based on two rigiddicarboxylic acids: synthesis, structures, and applications: a literature over view (2005-2015)
title_sort	co(ii) coordination networks based on two rigiddicarboxylic acids: synthesis, structures, and applications: a literature over view (2005-2015)
publisher	D.Ghitu Institute of Electronic Engineering and Nanotechnologies
publishDate	2015
url	https://doaj.org/article/3a489d8c579045089812387784f41426
work_keys_str_mv	AT chiscadiana coiicoordinationnetworksbasedontworigiddicarboxylicacidssynthesisstructuresandapplicationsaliteratureoverview20052015
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Co(II) coordination networks based on two rigiddicarboxylic acids: synthesis, structures, and applications: a literature over view (2005-2015)

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