Synthesis and structural characterization of a novel 2D supramolecular lead coordination polymer with phenanthroline derivate and adipic acid

A new metal-organic coordination polymer, [Pb(L)(adip)0.5] (1) was synthesized under hydrothermal conditions by using 1-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)naphthalen-2-ol (HL) and adipic acid (H2adip). The complex 1 was characterized by diffraction and elemental analyses. In complex 1, the b...

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Autores principales:	Song Yu, Yan Yu, Zhang Hua, Wang Xiuyan
Formato:	article
Lenguaje:	EN
Publicado:	De Gruyter 2021
Materias:	lead(ii) complex phenanthroline derivate π-π stacking crystal structure Chemistry QD1-999
Acceso en línea:	https://doaj.org/article/3bcc033de6ea4be1af95eb670052d29d
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spelling	oai:doaj.org-article:3bcc033de6ea4be1af95eb670052d29d2021-12-05T14:10:56ZSynthesis and structural characterization of a novel 2D supramolecular lead coordination polymer with phenanthroline derivate and adipic acid0792-12412191-021910.1515/mgmc-2021-0025https://doaj.org/article/3bcc033de6ea4be1af95eb670052d29d2021-09-01T00:00:00Zhttps://doi.org/10.1515/mgmc-2021-0025https://doaj.org/toc/0792-1241https://doaj.org/toc/2191-0219A new metal-organic coordination polymer, [Pb(L)(adip)0.5] (1) was synthesized under hydrothermal conditions by using 1-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)naphthalen-2-ol (HL) and adipic acid (H2adip). The complex 1 was characterized by diffraction and elemental analyses. In complex 1, the binuclear [Pb2L2] units were formed by the OH-deprotonation bridging neighboring Pb(II) atoms, and the adipate linked the binuclear [Pb2L2] units to form a symmetric one-dimensional chain. The 1D chain was further extended to the 2D supramolecular layer structure through π-π interactions between the L ligands.Song YuYan YuZhang HuaWang XiuyanDe Gruyterarticlelead(ii) complexphenanthroline derivateπ-π stackingcrystal structureChemistryQD1-999ENMain Group Metal Chemistry, Vol 44, Iss 1, Pp 239-242 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	lead(ii) complex phenanthroline derivate π-π stacking crystal structure Chemistry QD1-999
spellingShingle	lead(ii) complex phenanthroline derivate π-π stacking crystal structure Chemistry QD1-999 Song Yu Yan Yu Zhang Hua Wang Xiuyan Synthesis and structural characterization of a novel 2D supramolecular lead coordination polymer with phenanthroline derivate and adipic acid
description	A new metal-organic coordination polymer, [Pb(L)(adip)0.5] (1) was synthesized under hydrothermal conditions by using 1-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)naphthalen-2-ol (HL) and adipic acid (H2adip). The complex 1 was characterized by diffraction and elemental analyses. In complex 1, the binuclear [Pb2L2] units were formed by the OH-deprotonation bridging neighboring Pb(II) atoms, and the adipate linked the binuclear [Pb2L2] units to form a symmetric one-dimensional chain. The 1D chain was further extended to the 2D supramolecular layer structure through π-π interactions between the L ligands.
format	article
author	Song Yu Yan Yu Zhang Hua Wang Xiuyan
author_facet	Song Yu Yan Yu Zhang Hua Wang Xiuyan
author_sort	Song Yu
title	Synthesis and structural characterization of a novel 2D supramolecular lead coordination polymer with phenanthroline derivate and adipic acid
title_short	Synthesis and structural characterization of a novel 2D supramolecular lead coordination polymer with phenanthroline derivate and adipic acid
title_full	Synthesis and structural characterization of a novel 2D supramolecular lead coordination polymer with phenanthroline derivate and adipic acid
title_fullStr	Synthesis and structural characterization of a novel 2D supramolecular lead coordination polymer with phenanthroline derivate and adipic acid
title_full_unstemmed	Synthesis and structural characterization of a novel 2D supramolecular lead coordination polymer with phenanthroline derivate and adipic acid
title_sort	synthesis and structural characterization of a novel 2d supramolecular lead coordination polymer with phenanthroline derivate and adipic acid
publisher	De Gruyter
publishDate	2021
url	https://doaj.org/article/3bcc033de6ea4be1af95eb670052d29d
work_keys_str_mv	AT songyu synthesisandstructuralcharacterizationofanovel2dsupramolecularleadcoordinationpolymerwithphenanthrolinederivateandadipicacid AT yanyu synthesisandstructuralcharacterizationofanovel2dsupramolecularleadcoordinationpolymerwithphenanthrolinederivateandadipicacid AT zhanghua synthesisandstructuralcharacterizationofanovel2dsupramolecularleadcoordinationpolymerwithphenanthrolinederivateandadipicacid AT wangxiuyan synthesisandstructuralcharacterizationofanovel2dsupramolecularleadcoordinationpolymerwithphenanthrolinederivateandadipicacid
_version_	1718371597926006784

Synthesis and structural characterization of a novel 2D supramolecular lead coordination polymer with phenanthroline derivate and adipic acid

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