Supported palladium nanoparticles synthesized by living plants as a catalyst for Suzuki-Miyaura reactions.

The metal accumulating ability of plants has previously been used to capture metal contaminants from the environment; however, the full potential of this process is yet to be realized. Herein, the first use of living plants to recover palladium and produce catalytically active palladium nanoparticle...

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Autores principales:	Helen L Parker, Elizabeth L Rylott, Andrew J Hunt, Jennifer R Dodson, Andrew F Taylor, Neil C Bruce, James H Clark
Formato:	article
Lenguaje:	EN
Publicado:	Public Library of Science (PLoS) 2014
Materias:	Medicine R Science Q
Acceso en línea:	https://doaj.org/article/3c6ed0b20fcc4805930343cb996bc0ce
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spelling	oai:doaj.org-article:3c6ed0b20fcc4805930343cb996bc0ce2021-11-18T08:35:01ZSupported palladium nanoparticles synthesized by living plants as a catalyst for Suzuki-Miyaura reactions.1932-620310.1371/journal.pone.0087192https://doaj.org/article/3c6ed0b20fcc4805930343cb996bc0ce2014-01-01T00:00:00Zhttps://www.ncbi.nlm.nih.gov/pmc/articles/pmid/24489869/?tool=EBIhttps://doaj.org/toc/1932-6203The metal accumulating ability of plants has previously been used to capture metal contaminants from the environment; however, the full potential of this process is yet to be realized. Herein, the first use of living plants to recover palladium and produce catalytically active palladium nanoparticles is reported. This process eliminates the necessity for nanoparticle extraction from the plant and reduces the number of production steps compared to traditional catalyst palladium on carbon. These heterogeneous plant catalysts have demonstrated high catalytic activity in Suzuki coupling reactions between phenylboronic acid and a range of aryl halides containing iodo-, bromo- and chloro- moieties.Helen L ParkerElizabeth L RylottAndrew J HuntJennifer R DodsonAndrew F TaylorNeil C BruceJames H ClarkPublic Library of Science (PLoS)articleMedicineRScienceQENPLoS ONE, Vol 9, Iss 1, p e87192 (2014)
institution	DOAJ
collection	DOAJ
language	EN
topic	Medicine R Science Q
spellingShingle	Medicine R Science Q Helen L Parker Elizabeth L Rylott Andrew J Hunt Jennifer R Dodson Andrew F Taylor Neil C Bruce James H Clark Supported palladium nanoparticles synthesized by living plants as a catalyst for Suzuki-Miyaura reactions.
description	The metal accumulating ability of plants has previously been used to capture metal contaminants from the environment; however, the full potential of this process is yet to be realized. Herein, the first use of living plants to recover palladium and produce catalytically active palladium nanoparticles is reported. This process eliminates the necessity for nanoparticle extraction from the plant and reduces the number of production steps compared to traditional catalyst palladium on carbon. These heterogeneous plant catalysts have demonstrated high catalytic activity in Suzuki coupling reactions between phenylboronic acid and a range of aryl halides containing iodo-, bromo- and chloro- moieties.
format	article
author	Helen L Parker Elizabeth L Rylott Andrew J Hunt Jennifer R Dodson Andrew F Taylor Neil C Bruce James H Clark
author_facet	Helen L Parker Elizabeth L Rylott Andrew J Hunt Jennifer R Dodson Andrew F Taylor Neil C Bruce James H Clark
author_sort	Helen L Parker
title	Supported palladium nanoparticles synthesized by living plants as a catalyst for Suzuki-Miyaura reactions.
title_short	Supported palladium nanoparticles synthesized by living plants as a catalyst for Suzuki-Miyaura reactions.
title_full	Supported palladium nanoparticles synthesized by living plants as a catalyst for Suzuki-Miyaura reactions.
title_fullStr	Supported palladium nanoparticles synthesized by living plants as a catalyst for Suzuki-Miyaura reactions.
title_full_unstemmed	Supported palladium nanoparticles synthesized by living plants as a catalyst for Suzuki-Miyaura reactions.
title_sort	supported palladium nanoparticles synthesized by living plants as a catalyst for suzuki-miyaura reactions.
publisher	Public Library of Science (PLoS)
publishDate	2014
url	https://doaj.org/article/3c6ed0b20fcc4805930343cb996bc0ce
work_keys_str_mv	AT helenlparker supportedpalladiumnanoparticlessynthesizedbylivingplantsasacatalystforsuzukimiyaurareactions AT elizabethlrylott supportedpalladiumnanoparticlessynthesizedbylivingplantsasacatalystforsuzukimiyaurareactions AT andrewjhunt supportedpalladiumnanoparticlessynthesizedbylivingplantsasacatalystforsuzukimiyaurareactions AT jenniferrdodson supportedpalladiumnanoparticlessynthesizedbylivingplantsasacatalystforsuzukimiyaurareactions AT andrewftaylor supportedpalladiumnanoparticlessynthesizedbylivingplantsasacatalystforsuzukimiyaurareactions AT neilcbruce supportedpalladiumnanoparticlessynthesizedbylivingplantsasacatalystforsuzukimiyaurareactions AT jameshclark supportedpalladiumnanoparticlessynthesizedbylivingplantsasacatalystforsuzukimiyaurareactions
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Supported palladium nanoparticles synthesized by living plants as a catalyst for Suzuki-Miyaura reactions.

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