Organocatalytic synthesis of chiral tetrasubstituted allenes from racemic propargylic alcohols

Axially chiral allenes that are normally present in natural products, bioactive molecules, organocatalysts, and functional materials are usually produced from propargylic derivatives. Here, the authors show direct use of propargylic alcohols for catalytic asymmetric allene synthesis.

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Autores principales:	Deyun Qian, LinLin Wu, Zhenyang Lin, Jianwei Sun
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2017
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/3c7fb279c3b34ad4816767bc0dd7f93e
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spelling	oai:doaj.org-article:3c7fb279c3b34ad4816767bc0dd7f93e2021-12-02T14:40:22ZOrganocatalytic synthesis of chiral tetrasubstituted allenes from racemic propargylic alcohols10.1038/s41467-017-00251-x2041-1723https://doaj.org/article/3c7fb279c3b34ad4816767bc0dd7f93e2017-09-01T00:00:00Zhttps://doi.org/10.1038/s41467-017-00251-xhttps://doaj.org/toc/2041-1723Axially chiral allenes that are normally present in natural products, bioactive molecules, organocatalysts, and functional materials are usually produced from propargylic derivatives. Here, the authors show direct use of propargylic alcohols for catalytic asymmetric allene synthesis.Deyun QianLinLin WuZhenyang LinJianwei SunNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-9 (2017)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Deyun Qian LinLin Wu Zhenyang Lin Jianwei Sun Organocatalytic synthesis of chiral tetrasubstituted allenes from racemic propargylic alcohols
description	Axially chiral allenes that are normally present in natural products, bioactive molecules, organocatalysts, and functional materials are usually produced from propargylic derivatives. Here, the authors show direct use of propargylic alcohols for catalytic asymmetric allene synthesis.
format	article
author	Deyun Qian LinLin Wu Zhenyang Lin Jianwei Sun
author_facet	Deyun Qian LinLin Wu Zhenyang Lin Jianwei Sun
author_sort	Deyun Qian
title	Organocatalytic synthesis of chiral tetrasubstituted allenes from racemic propargylic alcohols
title_short	Organocatalytic synthesis of chiral tetrasubstituted allenes from racemic propargylic alcohols
title_full	Organocatalytic synthesis of chiral tetrasubstituted allenes from racemic propargylic alcohols
title_fullStr	Organocatalytic synthesis of chiral tetrasubstituted allenes from racemic propargylic alcohols
title_full_unstemmed	Organocatalytic synthesis of chiral tetrasubstituted allenes from racemic propargylic alcohols
title_sort	organocatalytic synthesis of chiral tetrasubstituted allenes from racemic propargylic alcohols
publisher	Nature Portfolio
publishDate	2017
url	https://doaj.org/article/3c7fb279c3b34ad4816767bc0dd7f93e
work_keys_str_mv	AT deyunqian organocatalyticsynthesisofchiraltetrasubstitutedallenesfromracemicpropargylicalcohols AT linlinwu organocatalyticsynthesisofchiraltetrasubstitutedallenesfromracemicpropargylicalcohols AT zhenyanglin organocatalyticsynthesisofchiraltetrasubstitutedallenesfromracemicpropargylicalcohols AT jianweisun organocatalyticsynthesisofchiraltetrasubstitutedallenesfromracemicpropargylicalcohols
_version_	1718390289334272000

Organocatalytic synthesis of chiral tetrasubstituted allenes from racemic propargylic alcohols

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