Benzene-Toluene-Xylene (BTX) Removal from Polluted Airflow by Combined Filter of Zero Valence Iron and Copper oxide Nanoparticles on Iranian Amended Clinoptilolite Bed

BACKGROUND AND OBJECTIVE: The BTX compounds consist of benzene, toluene and xylenes are volatile organic compounds and are present in fuels and industrial solvents. Its emission to air and exposure to these compounds threats human health. Thus, it is necessary to control these compounds concentratio...

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Autor principal: Rostami R, Jonidi Jafari A, Rezaei Kalantari R, Gholami M, Esrafili A
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Publicado: Babol University of Medical Sciences 2011
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spelling oai:doaj.org-article:3d2d6ef6fead42f3997e3e230cd75e462021-11-10T08:57:07ZBenzene-Toluene-Xylene (BTX) Removal from Polluted Airflow by Combined Filter of Zero Valence Iron and Copper oxide Nanoparticles on Iranian Amended Clinoptilolite Bed1561-41072251-7170https://doaj.org/article/3d2d6ef6fead42f3997e3e230cd75e462011-12-01T00:00:00Zhttp://jbums.org/article-1-4028-en.htmlhttps://doaj.org/toc/1561-4107https://doaj.org/toc/2251-7170BACKGROUND AND OBJECTIVE: The BTX compounds consist of benzene, toluene and xylenes are volatile organic compounds and are present in fuels and industrial solvents. Its emission to air and exposure to these compounds threats human health. Thus, it is necessary to control these compounds concentration in acceptable limit. Therefore, the purpose of this research was to survey BTX removal ability of a compound of iron and copper oxide metallic nanoparticles which have catalytic properties and also Zeolite as a sorbent and media for nanoparticles.METHODS: In this experimental study, samples were taken from inlet and outlet airflow of reactor for BTX and CO2 concentration determination. Zeolite filters without nanoparticle and a compound of zeolite with zero valence iron and copper oxide nanoparticles which contains 4.5% of nanoparticles and with 1-2mm of zeolite grains size as much as 200g were prepared and the BTX removal by each filter in a 30cm in length and 4.5 cm in diameter column as reactor determined. FINDINGS: The removal efficiency of benzene in the filter without nanoparticle (78.30±5.37%) was more than Iron and copper oxide nanoparticles (49.64±4.19%). But, for the toluene (67.09±4.23%) and xylenes (39.86±2.04%, 47.59±3.24% and 80.73±5.98%, respectively for p, m and o-xylenes) in iron and copper oxide nanoparticles filter it was further than the filter without nanoparticles (toluene 62.10±3.25% and xylenes respectively 30.20±1.84%, 32.15±3.39% and 18.80±3.39%). Also, the pollutant complete decomposition was higher in the filter containing nanoparticles (82.78% versus 16.44%). Average removal efficiency of BTX in the filter without nanoparticle was 43.31% and in the filter with iron and copper oxide nanoparticles was as much as 56.98%. CONCLUSION: As the obtained results the filter of zeolite without nanoparticle mainly removes the BTX compounds by absorption or incomplete decomposition. While, the zeolite filter with iron and copper oxide nanoparticles performs decomposition of the BTX more completely to CO2.Rostami R, Jonidi Jafari A, Rezaei Kalantari R, Gholami M, Esrafili ABabol University of Medical Sciencesarticlenanoparticleironcopper oxideclinoptilolitebtxMedicineRMedicine (General)R5-920ENFAMajallah-i Dānishgāh-i ̒Ulūm-i Pizishkī-i Bābul, Vol 14, Iss 1, Pp 23-29 (2011)
institution DOAJ
collection DOAJ
language EN
FA
topic nanoparticle
iron
copper oxide
clinoptilolite
btx
Medicine
R
Medicine (General)
R5-920
spellingShingle nanoparticle
iron
copper oxide
clinoptilolite
btx
Medicine
R
Medicine (General)
R5-920
Rostami R, Jonidi Jafari A, Rezaei Kalantari R, Gholami M, Esrafili A
Benzene-Toluene-Xylene (BTX) Removal from Polluted Airflow by Combined Filter of Zero Valence Iron and Copper oxide Nanoparticles on Iranian Amended Clinoptilolite Bed
description BACKGROUND AND OBJECTIVE: The BTX compounds consist of benzene, toluene and xylenes are volatile organic compounds and are present in fuels and industrial solvents. Its emission to air and exposure to these compounds threats human health. Thus, it is necessary to control these compounds concentration in acceptable limit. Therefore, the purpose of this research was to survey BTX removal ability of a compound of iron and copper oxide metallic nanoparticles which have catalytic properties and also Zeolite as a sorbent and media for nanoparticles.METHODS: In this experimental study, samples were taken from inlet and outlet airflow of reactor for BTX and CO2 concentration determination. Zeolite filters without nanoparticle and a compound of zeolite with zero valence iron and copper oxide nanoparticles which contains 4.5% of nanoparticles and with 1-2mm of zeolite grains size as much as 200g were prepared and the BTX removal by each filter in a 30cm in length and 4.5 cm in diameter column as reactor determined. FINDINGS: The removal efficiency of benzene in the filter without nanoparticle (78.30±5.37%) was more than Iron and copper oxide nanoparticles (49.64±4.19%). But, for the toluene (67.09±4.23%) and xylenes (39.86±2.04%, 47.59±3.24% and 80.73±5.98%, respectively for p, m and o-xylenes) in iron and copper oxide nanoparticles filter it was further than the filter without nanoparticles (toluene 62.10±3.25% and xylenes respectively 30.20±1.84%, 32.15±3.39% and 18.80±3.39%). Also, the pollutant complete decomposition was higher in the filter containing nanoparticles (82.78% versus 16.44%). Average removal efficiency of BTX in the filter without nanoparticle was 43.31% and in the filter with iron and copper oxide nanoparticles was as much as 56.98%. CONCLUSION: As the obtained results the filter of zeolite without nanoparticle mainly removes the BTX compounds by absorption or incomplete decomposition. While, the zeolite filter with iron and copper oxide nanoparticles performs decomposition of the BTX more completely to CO2.
format article
author Rostami R, Jonidi Jafari A, Rezaei Kalantari R, Gholami M, Esrafili A
author_facet Rostami R, Jonidi Jafari A, Rezaei Kalantari R, Gholami M, Esrafili A
author_sort Rostami R, Jonidi Jafari A, Rezaei Kalantari R, Gholami M, Esrafili A
title Benzene-Toluene-Xylene (BTX) Removal from Polluted Airflow by Combined Filter of Zero Valence Iron and Copper oxide Nanoparticles on Iranian Amended Clinoptilolite Bed
title_short Benzene-Toluene-Xylene (BTX) Removal from Polluted Airflow by Combined Filter of Zero Valence Iron and Copper oxide Nanoparticles on Iranian Amended Clinoptilolite Bed
title_full Benzene-Toluene-Xylene (BTX) Removal from Polluted Airflow by Combined Filter of Zero Valence Iron and Copper oxide Nanoparticles on Iranian Amended Clinoptilolite Bed
title_fullStr Benzene-Toluene-Xylene (BTX) Removal from Polluted Airflow by Combined Filter of Zero Valence Iron and Copper oxide Nanoparticles on Iranian Amended Clinoptilolite Bed
title_full_unstemmed Benzene-Toluene-Xylene (BTX) Removal from Polluted Airflow by Combined Filter of Zero Valence Iron and Copper oxide Nanoparticles on Iranian Amended Clinoptilolite Bed
title_sort benzene-toluene-xylene (btx) removal from polluted airflow by combined filter of zero valence iron and copper oxide nanoparticles on iranian amended clinoptilolite bed
publisher Babol University of Medical Sciences
publishDate 2011
url https://doaj.org/article/3d2d6ef6fead42f3997e3e230cd75e46
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