A flat carborane with multiple aromaticity beyond Wade–Mingos’ rules

A flat carborane with multiple aromaticity beyond Wade–Mingos’ rules

The polyhedral skeletal electron pair theory (PESPT), also known as Wade-Mingos’ rules, defines a relationship between skeletal bonding electron pairs and structure of clusters. Here the authors report the synthesis, structure and computational studies of planar C2B4R4 carboranes that do not adhere...

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Autores principales: Wei Lu, Dinh Cao Huan Do, Rei Kinjo
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2020
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Acceso en línea:https://doaj.org/article/3d2dad4fdf8d47a2a30e33b48da288b1
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spelling oai:doaj.org-article:3d2dad4fdf8d47a2a30e33b48da288b12021-12-02T15:39:44ZA flat carborane with multiple aromaticity beyond Wade–Mingos’ rules10.1038/s41467-020-17166-92041-1723https://doaj.org/article/3d2dad4fdf8d47a2a30e33b48da288b12020-07-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-17166-9https://doaj.org/toc/2041-1723The polyhedral skeletal electron pair theory (PESPT), also known as Wade-Mingos’ rules, defines a relationship between skeletal bonding electron pairs and structure of clusters. Here the authors report the synthesis, structure and computational studies of planar C2B4R4 carboranes that do not adhere to PESPT.Wei LuDinh Cao Huan DoRei KinjoNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-7 (2020)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Wei Lu
Dinh Cao Huan Do
Rei Kinjo
A flat carborane with multiple aromaticity beyond Wade–Mingos’ rules
description The polyhedral skeletal electron pair theory (PESPT), also known as Wade-Mingos’ rules, defines a relationship between skeletal bonding electron pairs and structure of clusters. Here the authors report the synthesis, structure and computational studies of planar C2B4R4 carboranes that do not adhere to PESPT.
format article
author Wei Lu
Dinh Cao Huan Do
Rei Kinjo
author_facet Wei Lu
Dinh Cao Huan Do
Rei Kinjo
author_sort Wei Lu
title A flat carborane with multiple aromaticity beyond Wade–Mingos’ rules
title_short A flat carborane with multiple aromaticity beyond Wade–Mingos’ rules
title_full A flat carborane with multiple aromaticity beyond Wade–Mingos’ rules
title_fullStr A flat carborane with multiple aromaticity beyond Wade–Mingos’ rules
title_full_unstemmed A flat carborane with multiple aromaticity beyond Wade–Mingos’ rules
title_sort flat carborane with multiple aromaticity beyond wade–mingos’ rules
publisher Nature Portfolio
publishDate 2020
url https://doaj.org/article/3d2dad4fdf8d47a2a30e33b48da288b1
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