Corrosion Resistance of CoCrFeNiMn High Entropy Alloy Coating Prepared through Plasma Transfer Arc Claddings

High entropy alloy attracts great attention for its high thermal stability and corrosion resistance. A CoCrFeNiMn high-entropy alloy coating was deposited on grey cast iron through plasma transfer arc cladding. It formed fine acicular martensite near the grey cast iron, with columnar grains perpendi...

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Autores principales: Pei-Hu Gao, Rui-Tao Fu, Bai-Yang Chen, Sheng-Cong Zeng, Bo Zhang, Zhong Yang, Yong-Chun Guo, Min-Xian Liang, Jian-Ping Li, Yong-Qing Lu, Lu Jia, Dan Zhao
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Publicado: MDPI AG 2021
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Acceso en línea:https://doaj.org/article/3e06b5a718d24cfc93e7e4f55e21cfd4
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spelling oai:doaj.org-article:3e06b5a718d24cfc93e7e4f55e21cfd42021-11-25T18:22:35ZCorrosion Resistance of CoCrFeNiMn High Entropy Alloy Coating Prepared through Plasma Transfer Arc Claddings10.3390/met111118762075-4701https://doaj.org/article/3e06b5a718d24cfc93e7e4f55e21cfd42021-11-01T00:00:00Zhttps://www.mdpi.com/2075-4701/11/11/1876https://doaj.org/toc/2075-4701High entropy alloy attracts great attention for its high thermal stability and corrosion resistance. A CoCrFeNiMn high-entropy alloy coating was deposited on grey cast iron through plasma transfer arc cladding. It formed fine acicular martensite near the grey cast iron, with columnar grains perpendicular to the interface between the grey cast iron substrate and the cladding layer as well as dendrite in the middle part of the coatings. Simple FCC solid solutions present in the coatings which were similar to the powder’s structure. The coating had a microhardness of 300 ± 21.5 HV<sub>0.2</sub> when the cladding current was 80 A for the solid solution strengthening. The HEA coating had the highest corrosion potential of −0.253 V when the plasma current was 60 A, which was much higher than the grey cast iron’s corrosion potential of −0.708 V. Meanwhile, the coating had a much lower corrosion current density of 9.075 × 10<sup>−7</sup> mA/cm<sup>2</sup> than the grey cast iron’s 2.4825 × 10<sup>−6</sup> mA/cm<sup>2</sup>, which reflected that the CoCrFeNiMn HEA coating had much better corrosion resistance and lower corrosion rate than the grey cast iron for single FCC solid solution phase and a relatively higher concentration of Cr in the grain boundaries than in the grains and this could lead to corrosion protection effects.Pei-Hu GaoRui-Tao FuBai-Yang ChenSheng-Cong ZengBo ZhangZhong YangYong-Chun GuoMin-Xian LiangJian-Ping LiYong-Qing LuLu JiaDan ZhaoMDPI AGarticlehigh-entropy alloy coatingplasma claddingmicrostructurecorrosionMining engineering. MetallurgyTN1-997ENMetals, Vol 11, Iss 1876, p 1876 (2021)
institution DOAJ
collection DOAJ
language EN
topic high-entropy alloy coating
plasma cladding
microstructure
corrosion
Mining engineering. Metallurgy
TN1-997
spellingShingle high-entropy alloy coating
plasma cladding
microstructure
corrosion
Mining engineering. Metallurgy
TN1-997
Pei-Hu Gao
Rui-Tao Fu
Bai-Yang Chen
Sheng-Cong Zeng
Bo Zhang
Zhong Yang
Yong-Chun Guo
Min-Xian Liang
Jian-Ping Li
Yong-Qing Lu
Lu Jia
Dan Zhao
Corrosion Resistance of CoCrFeNiMn High Entropy Alloy Coating Prepared through Plasma Transfer Arc Claddings
description High entropy alloy attracts great attention for its high thermal stability and corrosion resistance. A CoCrFeNiMn high-entropy alloy coating was deposited on grey cast iron through plasma transfer arc cladding. It formed fine acicular martensite near the grey cast iron, with columnar grains perpendicular to the interface between the grey cast iron substrate and the cladding layer as well as dendrite in the middle part of the coatings. Simple FCC solid solutions present in the coatings which were similar to the powder’s structure. The coating had a microhardness of 300 ± 21.5 HV<sub>0.2</sub> when the cladding current was 80 A for the solid solution strengthening. The HEA coating had the highest corrosion potential of −0.253 V when the plasma current was 60 A, which was much higher than the grey cast iron’s corrosion potential of −0.708 V. Meanwhile, the coating had a much lower corrosion current density of 9.075 × 10<sup>−7</sup> mA/cm<sup>2</sup> than the grey cast iron’s 2.4825 × 10<sup>−6</sup> mA/cm<sup>2</sup>, which reflected that the CoCrFeNiMn HEA coating had much better corrosion resistance and lower corrosion rate than the grey cast iron for single FCC solid solution phase and a relatively higher concentration of Cr in the grain boundaries than in the grains and this could lead to corrosion protection effects.
format article
author Pei-Hu Gao
Rui-Tao Fu
Bai-Yang Chen
Sheng-Cong Zeng
Bo Zhang
Zhong Yang
Yong-Chun Guo
Min-Xian Liang
Jian-Ping Li
Yong-Qing Lu
Lu Jia
Dan Zhao
author_facet Pei-Hu Gao
Rui-Tao Fu
Bai-Yang Chen
Sheng-Cong Zeng
Bo Zhang
Zhong Yang
Yong-Chun Guo
Min-Xian Liang
Jian-Ping Li
Yong-Qing Lu
Lu Jia
Dan Zhao
author_sort Pei-Hu Gao
title Corrosion Resistance of CoCrFeNiMn High Entropy Alloy Coating Prepared through Plasma Transfer Arc Claddings
title_short Corrosion Resistance of CoCrFeNiMn High Entropy Alloy Coating Prepared through Plasma Transfer Arc Claddings
title_full Corrosion Resistance of CoCrFeNiMn High Entropy Alloy Coating Prepared through Plasma Transfer Arc Claddings
title_fullStr Corrosion Resistance of CoCrFeNiMn High Entropy Alloy Coating Prepared through Plasma Transfer Arc Claddings
title_full_unstemmed Corrosion Resistance of CoCrFeNiMn High Entropy Alloy Coating Prepared through Plasma Transfer Arc Claddings
title_sort corrosion resistance of cocrfenimn high entropy alloy coating prepared through plasma transfer arc claddings
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/3e06b5a718d24cfc93e7e4f55e21cfd4
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