Corrosion Resistance of CoCrFeNiMn High Entropy Alloy Coating Prepared through Plasma Transfer Arc Claddings
High entropy alloy attracts great attention for its high thermal stability and corrosion resistance. A CoCrFeNiMn high-entropy alloy coating was deposited on grey cast iron through plasma transfer arc cladding. It formed fine acicular martensite near the grey cast iron, with columnar grains perpendi...
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2021
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oai:doaj.org-article:3e06b5a718d24cfc93e7e4f55e21cfd42021-11-25T18:22:35ZCorrosion Resistance of CoCrFeNiMn High Entropy Alloy Coating Prepared through Plasma Transfer Arc Claddings10.3390/met111118762075-4701https://doaj.org/article/3e06b5a718d24cfc93e7e4f55e21cfd42021-11-01T00:00:00Zhttps://www.mdpi.com/2075-4701/11/11/1876https://doaj.org/toc/2075-4701High entropy alloy attracts great attention for its high thermal stability and corrosion resistance. A CoCrFeNiMn high-entropy alloy coating was deposited on grey cast iron through plasma transfer arc cladding. It formed fine acicular martensite near the grey cast iron, with columnar grains perpendicular to the interface between the grey cast iron substrate and the cladding layer as well as dendrite in the middle part of the coatings. Simple FCC solid solutions present in the coatings which were similar to the powder’s structure. The coating had a microhardness of 300 ± 21.5 HV<sub>0.2</sub> when the cladding current was 80 A for the solid solution strengthening. The HEA coating had the highest corrosion potential of −0.253 V when the plasma current was 60 A, which was much higher than the grey cast iron’s corrosion potential of −0.708 V. Meanwhile, the coating had a much lower corrosion current density of 9.075 × 10<sup>−7</sup> mA/cm<sup>2</sup> than the grey cast iron’s 2.4825 × 10<sup>−6</sup> mA/cm<sup>2</sup>, which reflected that the CoCrFeNiMn HEA coating had much better corrosion resistance and lower corrosion rate than the grey cast iron for single FCC solid solution phase and a relatively higher concentration of Cr in the grain boundaries than in the grains and this could lead to corrosion protection effects.Pei-Hu GaoRui-Tao FuBai-Yang ChenSheng-Cong ZengBo ZhangZhong YangYong-Chun GuoMin-Xian LiangJian-Ping LiYong-Qing LuLu JiaDan ZhaoMDPI AGarticlehigh-entropy alloy coatingplasma claddingmicrostructurecorrosionMining engineering. MetallurgyTN1-997ENMetals, Vol 11, Iss 1876, p 1876 (2021) |
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high-entropy alloy coating plasma cladding microstructure corrosion Mining engineering. Metallurgy TN1-997 |
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high-entropy alloy coating plasma cladding microstructure corrosion Mining engineering. Metallurgy TN1-997 Pei-Hu Gao Rui-Tao Fu Bai-Yang Chen Sheng-Cong Zeng Bo Zhang Zhong Yang Yong-Chun Guo Min-Xian Liang Jian-Ping Li Yong-Qing Lu Lu Jia Dan Zhao Corrosion Resistance of CoCrFeNiMn High Entropy Alloy Coating Prepared through Plasma Transfer Arc Claddings |
description |
High entropy alloy attracts great attention for its high thermal stability and corrosion resistance. A CoCrFeNiMn high-entropy alloy coating was deposited on grey cast iron through plasma transfer arc cladding. It formed fine acicular martensite near the grey cast iron, with columnar grains perpendicular to the interface between the grey cast iron substrate and the cladding layer as well as dendrite in the middle part of the coatings. Simple FCC solid solutions present in the coatings which were similar to the powder’s structure. The coating had a microhardness of 300 ± 21.5 HV<sub>0.2</sub> when the cladding current was 80 A for the solid solution strengthening. The HEA coating had the highest corrosion potential of −0.253 V when the plasma current was 60 A, which was much higher than the grey cast iron’s corrosion potential of −0.708 V. Meanwhile, the coating had a much lower corrosion current density of 9.075 × 10<sup>−7</sup> mA/cm<sup>2</sup> than the grey cast iron’s 2.4825 × 10<sup>−6</sup> mA/cm<sup>2</sup>, which reflected that the CoCrFeNiMn HEA coating had much better corrosion resistance and lower corrosion rate than the grey cast iron for single FCC solid solution phase and a relatively higher concentration of Cr in the grain boundaries than in the grains and this could lead to corrosion protection effects. |
format |
article |
author |
Pei-Hu Gao Rui-Tao Fu Bai-Yang Chen Sheng-Cong Zeng Bo Zhang Zhong Yang Yong-Chun Guo Min-Xian Liang Jian-Ping Li Yong-Qing Lu Lu Jia Dan Zhao |
author_facet |
Pei-Hu Gao Rui-Tao Fu Bai-Yang Chen Sheng-Cong Zeng Bo Zhang Zhong Yang Yong-Chun Guo Min-Xian Liang Jian-Ping Li Yong-Qing Lu Lu Jia Dan Zhao |
author_sort |
Pei-Hu Gao |
title |
Corrosion Resistance of CoCrFeNiMn High Entropy Alloy Coating Prepared through Plasma Transfer Arc Claddings |
title_short |
Corrosion Resistance of CoCrFeNiMn High Entropy Alloy Coating Prepared through Plasma Transfer Arc Claddings |
title_full |
Corrosion Resistance of CoCrFeNiMn High Entropy Alloy Coating Prepared through Plasma Transfer Arc Claddings |
title_fullStr |
Corrosion Resistance of CoCrFeNiMn High Entropy Alloy Coating Prepared through Plasma Transfer Arc Claddings |
title_full_unstemmed |
Corrosion Resistance of CoCrFeNiMn High Entropy Alloy Coating Prepared through Plasma Transfer Arc Claddings |
title_sort |
corrosion resistance of cocrfenimn high entropy alloy coating prepared through plasma transfer arc claddings |
publisher |
MDPI AG |
publishDate |
2021 |
url |
https://doaj.org/article/3e06b5a718d24cfc93e7e4f55e21cfd4 |
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