Study on Optimum IUPAC Adsorption Isotherm Models Employing Sensitivity of Parameters for Rigorous Adsorption System Performance Evaluation

Adsorption cooling technologies driven by low-grade thermal or solar power are used as an energy-efficient alternative to conventional refrigeration and air conditioning systems. Explicit understanding of the adsorption cycles requires precise determination of the performance parameters, replication...

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Autores principales:	Md. Matiar Rahman, Abu Zar Shafiullah, Animesh Pal, Md. Amirul Islam, Israt Jahan, Bidyut Baran Saha
Formato:	article
Lenguaje:	EN
Publicado:	MDPI AG 2021
Materias:	ANOVA IUPAC optimum isotherm statistical analysis Tukey HSD Technology T
Acceso en línea:	https://doaj.org/article/3ee458d3ea6143a59860f6971dfdb0a0
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spelling	oai:doaj.org-article:3ee458d3ea6143a59860f6971dfdb0a02021-11-25T17:25:53ZStudy on Optimum IUPAC Adsorption Isotherm Models Employing Sensitivity of Parameters for Rigorous Adsorption System Performance Evaluation10.3390/en142274781996-1073https://doaj.org/article/3ee458d3ea6143a59860f6971dfdb0a02021-11-01T00:00:00Zhttps://www.mdpi.com/1996-1073/14/22/7478https://doaj.org/toc/1996-1073Adsorption cooling technologies driven by low-grade thermal or solar power are used as an energy-efficient alternative to conventional refrigeration and air conditioning systems. Explicit understanding of the adsorption cycles requires precise determination of the performance parameters, replication of the experimental data, and the rigorous study of the adsorption heat transformation method. Hence, the optimum adsorption isotherms model must be identified. Scientists often face difficulties in selecting the suitable isotherm model as there are many models for a particular form of adsorption isotherm. The present study introduces a novel approach for choosing the optimal models for each type of International Union of Pure and Applied Chemistry (IUPAC) classified adsorption isotherm using robust statistical methods. First, the box-and-whisker plots of error identification are employed. Tóth for Type-I(a) and Type-I(b), modified BET for Type-II, GAB for Type-III, Universal for Type-IV(a), and Type-IV(b), Sun Chakrabarty for Type-V, and Yahia et al. for Type-VI were found lower than the other candidate models in box-and-whisker plot. The optimality of our selected models was further verified using analysis of variance (ANOVA), pairwise Tukey honest significant difference (HSD) test, Kruskal–Wallis rank-sum test, and pairwise Wilcoxon rank-sum test. In short, rigorous statistical analysis was performed to identify the best model for each type of isotherm by minimizing error. Moreover, specific cooling effect (SCE) of Maxsorb III/ethanol and silica gel/water pairs were determined. Results showed that Tóth is the optimal isotherm model for the studied pairs, and the SCE values obtained from the model agree well with experimental data. The optimum isotherm model is indispensable for the precise designing of the next generation adsorption cooling cycles.Md. Matiar RahmanAbu Zar ShafiullahAnimesh PalMd. Amirul IslamIsrat JahanBidyut Baran SahaMDPI AGarticleANOVAIUPACoptimum isothermstatistical analysisTukey HSDTechnologyTENEnergies, Vol 14, Iss 7478, p 7478 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	ANOVA IUPAC optimum isotherm statistical analysis Tukey HSD Technology T
spellingShingle	ANOVA IUPAC optimum isotherm statistical analysis Tukey HSD Technology T Md. Matiar Rahman Abu Zar Shafiullah Animesh Pal Md. Amirul Islam Israt Jahan Bidyut Baran Saha Study on Optimum IUPAC Adsorption Isotherm Models Employing Sensitivity of Parameters for Rigorous Adsorption System Performance Evaluation
description	Adsorption cooling technologies driven by low-grade thermal or solar power are used as an energy-efficient alternative to conventional refrigeration and air conditioning systems. Explicit understanding of the adsorption cycles requires precise determination of the performance parameters, replication of the experimental data, and the rigorous study of the adsorption heat transformation method. Hence, the optimum adsorption isotherms model must be identified. Scientists often face difficulties in selecting the suitable isotherm model as there are many models for a particular form of adsorption isotherm. The present study introduces a novel approach for choosing the optimal models for each type of International Union of Pure and Applied Chemistry (IUPAC) classified adsorption isotherm using robust statistical methods. First, the box-and-whisker plots of error identification are employed. Tóth for Type-I(a) and Type-I(b), modified BET for Type-II, GAB for Type-III, Universal for Type-IV(a), and Type-IV(b), Sun Chakrabarty for Type-V, and Yahia et al. for Type-VI were found lower than the other candidate models in box-and-whisker plot. The optimality of our selected models was further verified using analysis of variance (ANOVA), pairwise Tukey honest significant difference (HSD) test, Kruskal–Wallis rank-sum test, and pairwise Wilcoxon rank-sum test. In short, rigorous statistical analysis was performed to identify the best model for each type of isotherm by minimizing error. Moreover, specific cooling effect (SCE) of Maxsorb III/ethanol and silica gel/water pairs were determined. Results showed that Tóth is the optimal isotherm model for the studied pairs, and the SCE values obtained from the model agree well with experimental data. The optimum isotherm model is indispensable for the precise designing of the next generation adsorption cooling cycles.
format	article
author	Md. Matiar Rahman Abu Zar Shafiullah Animesh Pal Md. Amirul Islam Israt Jahan Bidyut Baran Saha
author_facet	Md. Matiar Rahman Abu Zar Shafiullah Animesh Pal Md. Amirul Islam Israt Jahan Bidyut Baran Saha
author_sort	Md. Matiar Rahman
title	Study on Optimum IUPAC Adsorption Isotherm Models Employing Sensitivity of Parameters for Rigorous Adsorption System Performance Evaluation
title_short	Study on Optimum IUPAC Adsorption Isotherm Models Employing Sensitivity of Parameters for Rigorous Adsorption System Performance Evaluation
title_full	Study on Optimum IUPAC Adsorption Isotherm Models Employing Sensitivity of Parameters for Rigorous Adsorption System Performance Evaluation
title_fullStr	Study on Optimum IUPAC Adsorption Isotherm Models Employing Sensitivity of Parameters for Rigorous Adsorption System Performance Evaluation
title_full_unstemmed	Study on Optimum IUPAC Adsorption Isotherm Models Employing Sensitivity of Parameters for Rigorous Adsorption System Performance Evaluation
title_sort	study on optimum iupac adsorption isotherm models employing sensitivity of parameters for rigorous adsorption system performance evaluation
publisher	MDPI AG
publishDate	2021
url	https://doaj.org/article/3ee458d3ea6143a59860f6971dfdb0a0
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Study on Optimum IUPAC Adsorption Isotherm Models Employing Sensitivity of Parameters for Rigorous Adsorption System Performance Evaluation

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