ANALYSIS OF THE EFFECT OF SOLUTION CHARACTERISTICS ON THE ELECTROPHYSICAL PARAMETERS OF TRANSPARENT CONDUCTIVE OXIDES

Background. The aim of the study is to analyze the effect of the solution parameters on the electrophysical parameters of transparent conducting oxides during their synthesis by spray pyrolysis. Materials and methods. In the considered technology for the synthesis of transparent conductive oxides...

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Autores principales: T.O. Zinchenko, E.A. Pecherskaya, G.V. Kozlov, V.I. Kondrashin, Yu.A. Varenik, V.S. Alexandrov
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RU
Publicado: Penza State University Publishing House 2021
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spelling oai:doaj.org-article:3f154fb1031e4c4a87812ebe7fa3d6f12021-11-24T10:49:22ZANALYSIS OF THE EFFECT OF SOLUTION CHARACTERISTICS ON THE ELECTROPHYSICAL PARAMETERS OF TRANSPARENT CONDUCTIVE OXIDES10.21685/2307-5538-2021-3-92307-5538https://doaj.org/article/3f154fb1031e4c4a87812ebe7fa3d6f12021-11-01T00:00:00Zhttps://doaj.org/toc/2307-5538Background. The aim of the study is to analyze the effect of the solution parameters on the electrophysical parameters of transparent conducting oxides during their synthesis by spray pyrolysis. Materials and methods. In the considered technology for the synthesis of transparent conductive oxides by spray pyrolysis, the method of hydrolysis of solutions of chlorine tin is used. It is convenient for testing and selecting the amount and type of alloying additives to SnO2. The formation of the oxide film is carried out on the heated surface of the substrate by surface hydrolysis of metal chloride. Results. It is shown that one of the important quality parameters of transparent conducting oxides (resistivity, and hence conductivity) is significantly affected by the characteristics of the solution (volume, impurity and its concentration, precursors and their concentration). Conclusions. The results of the experiments and their analysis confirmed that in order to reduce the surface resistance of PPO, it is necessary to increase the volume of the solution, the concentration of antimony impurities, and the concentration of precursors. Antimony atoms, replacing tin atoms in the lattice, are donors and lead to the formation of excess free electrons and an increase in conductivity.T.O. ZinchenkoE.A. PecherskayaG.V. KozlovV.I. KondrashinYu.A. VarenikV.S. AlexandrovPenza State University Publishing Housearticlesolution parameterstin tetrachloride pentahydrateantimony trichlorideprecursorimpurityresistivityconductivityEngineering (General). Civil engineering (General)TA1-2040ENRUИзмерение, мониторинг, управление, контроль, Iss 3 (2021)
institution DOAJ
collection DOAJ
language EN
RU
topic solution parameters
tin tetrachloride pentahydrate
antimony trichloride
precursor
impurity
resistivity
conductivity
Engineering (General). Civil engineering (General)
TA1-2040
spellingShingle solution parameters
tin tetrachloride pentahydrate
antimony trichloride
precursor
impurity
resistivity
conductivity
Engineering (General). Civil engineering (General)
TA1-2040
T.O. Zinchenko
E.A. Pecherskaya
G.V. Kozlov
V.I. Kondrashin
Yu.A. Varenik
V.S. Alexandrov
ANALYSIS OF THE EFFECT OF SOLUTION CHARACTERISTICS ON THE ELECTROPHYSICAL PARAMETERS OF TRANSPARENT CONDUCTIVE OXIDES
description Background. The aim of the study is to analyze the effect of the solution parameters on the electrophysical parameters of transparent conducting oxides during their synthesis by spray pyrolysis. Materials and methods. In the considered technology for the synthesis of transparent conductive oxides by spray pyrolysis, the method of hydrolysis of solutions of chlorine tin is used. It is convenient for testing and selecting the amount and type of alloying additives to SnO2. The formation of the oxide film is carried out on the heated surface of the substrate by surface hydrolysis of metal chloride. Results. It is shown that one of the important quality parameters of transparent conducting oxides (resistivity, and hence conductivity) is significantly affected by the characteristics of the solution (volume, impurity and its concentration, precursors and their concentration). Conclusions. The results of the experiments and their analysis confirmed that in order to reduce the surface resistance of PPO, it is necessary to increase the volume of the solution, the concentration of antimony impurities, and the concentration of precursors. Antimony atoms, replacing tin atoms in the lattice, are donors and lead to the formation of excess free electrons and an increase in conductivity.
format article
author T.O. Zinchenko
E.A. Pecherskaya
G.V. Kozlov
V.I. Kondrashin
Yu.A. Varenik
V.S. Alexandrov
author_facet T.O. Zinchenko
E.A. Pecherskaya
G.V. Kozlov
V.I. Kondrashin
Yu.A. Varenik
V.S. Alexandrov
author_sort T.O. Zinchenko
title ANALYSIS OF THE EFFECT OF SOLUTION CHARACTERISTICS ON THE ELECTROPHYSICAL PARAMETERS OF TRANSPARENT CONDUCTIVE OXIDES
title_short ANALYSIS OF THE EFFECT OF SOLUTION CHARACTERISTICS ON THE ELECTROPHYSICAL PARAMETERS OF TRANSPARENT CONDUCTIVE OXIDES
title_full ANALYSIS OF THE EFFECT OF SOLUTION CHARACTERISTICS ON THE ELECTROPHYSICAL PARAMETERS OF TRANSPARENT CONDUCTIVE OXIDES
title_fullStr ANALYSIS OF THE EFFECT OF SOLUTION CHARACTERISTICS ON THE ELECTROPHYSICAL PARAMETERS OF TRANSPARENT CONDUCTIVE OXIDES
title_full_unstemmed ANALYSIS OF THE EFFECT OF SOLUTION CHARACTERISTICS ON THE ELECTROPHYSICAL PARAMETERS OF TRANSPARENT CONDUCTIVE OXIDES
title_sort analysis of the effect of solution characteristics on the electrophysical parameters of transparent conductive oxides
publisher Penza State University Publishing House
publishDate 2021
url https://doaj.org/article/3f154fb1031e4c4a87812ebe7fa3d6f1
work_keys_str_mv AT tozinchenko analysisoftheeffectofsolutioncharacteristicsontheelectrophysicalparametersoftransparentconductiveoxides
AT eapecherskaya analysisoftheeffectofsolutioncharacteristicsontheelectrophysicalparametersoftransparentconductiveoxides
AT gvkozlov analysisoftheeffectofsolutioncharacteristicsontheelectrophysicalparametersoftransparentconductiveoxides
AT vikondrashin analysisoftheeffectofsolutioncharacteristicsontheelectrophysicalparametersoftransparentconductiveoxides
AT yuavarenik analysisoftheeffectofsolutioncharacteristicsontheelectrophysicalparametersoftransparentconductiveoxides
AT vsalexandrov analysisoftheeffectofsolutioncharacteristicsontheelectrophysicalparametersoftransparentconductiveoxides
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