pH effects on the electrochemical reduction of CO(2) towards C2 products on stepped copper

CO2 conversion to reduced products provides a use for greenhouse gases, but reaction complexity stymies mechanistic studies. Here, authors present a microkinetic model for CO2 and CO reduction on copper, based on ab initio simulations, to elucidate pH’s impact on competitive reaction pathways.

Guardado en:

Detalles Bibliográficos
Autores principales:	Xinyan Liu, Philomena Schlexer, Jianping Xiao, Yongfei Ji, Lei Wang, Robert B. Sandberg, Michael Tang, Kristopher S. Brown, Hongjie Peng, Stefan Ringe, Christopher Hahn, Thomas F. Jaramillo, Jens K. Nørskov, Karen Chan
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2019
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/3f7e27bb02e64903833bc82183e46104
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:doaj.org-article:3f7e27bb02e64903833bc82183e46104
record_format	dspace
spelling	oai:doaj.org-article:3f7e27bb02e64903833bc82183e461042021-12-02T15:35:55ZpH effects on the electrochemical reduction of CO(2) towards C2 products on stepped copper10.1038/s41467-018-07970-92041-1723https://doaj.org/article/3f7e27bb02e64903833bc82183e461042019-01-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-07970-9https://doaj.org/toc/2041-1723CO2 conversion to reduced products provides a use for greenhouse gases, but reaction complexity stymies mechanistic studies. Here, authors present a microkinetic model for CO2 and CO reduction on copper, based on ab initio simulations, to elucidate pH’s impact on competitive reaction pathways.Xinyan LiuPhilomena SchlexerJianping XiaoYongfei JiLei WangRobert B. SandbergMichael TangKristopher S. BrownHongjie PengStefan RingeChristopher HahnThomas F. JaramilloJens K. NørskovKaren ChanNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-10 (2019)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Xinyan Liu Philomena Schlexer Jianping Xiao Yongfei Ji Lei Wang Robert B. Sandberg Michael Tang Kristopher S. Brown Hongjie Peng Stefan Ringe Christopher Hahn Thomas F. Jaramillo Jens K. Nørskov Karen Chan pH effects on the electrochemical reduction of CO(2) towards C2 products on stepped copper
description	CO2 conversion to reduced products provides a use for greenhouse gases, but reaction complexity stymies mechanistic studies. Here, authors present a microkinetic model for CO2 and CO reduction on copper, based on ab initio simulations, to elucidate pH’s impact on competitive reaction pathways.
format	article
author	Xinyan Liu Philomena Schlexer Jianping Xiao Yongfei Ji Lei Wang Robert B. Sandberg Michael Tang Kristopher S. Brown Hongjie Peng Stefan Ringe Christopher Hahn Thomas F. Jaramillo Jens K. Nørskov Karen Chan
author_facet	Xinyan Liu Philomena Schlexer Jianping Xiao Yongfei Ji Lei Wang Robert B. Sandberg Michael Tang Kristopher S. Brown Hongjie Peng Stefan Ringe Christopher Hahn Thomas F. Jaramillo Jens K. Nørskov Karen Chan
author_sort	Xinyan Liu
title	pH effects on the electrochemical reduction of CO(2) towards C2 products on stepped copper
title_short	pH effects on the electrochemical reduction of CO(2) towards C2 products on stepped copper
title_full	pH effects on the electrochemical reduction of CO(2) towards C2 products on stepped copper
title_fullStr	pH effects on the electrochemical reduction of CO(2) towards C2 products on stepped copper
title_full_unstemmed	pH effects on the electrochemical reduction of CO(2) towards C2 products on stepped copper
title_sort	ph effects on the electrochemical reduction of co(2) towards c2 products on stepped copper
publisher	Nature Portfolio
publishDate	2019
url	https://doaj.org/article/3f7e27bb02e64903833bc82183e46104
work_keys_str_mv	AT xinyanliu pheffectsontheelectrochemicalreductionofco2towardsc2productsonsteppedcopper AT philomenaschlexer pheffectsontheelectrochemicalreductionofco2towardsc2productsonsteppedcopper AT jianpingxiao pheffectsontheelectrochemicalreductionofco2towardsc2productsonsteppedcopper AT yongfeiji pheffectsontheelectrochemicalreductionofco2towardsc2productsonsteppedcopper AT leiwang pheffectsontheelectrochemicalreductionofco2towardsc2productsonsteppedcopper AT robertbsandberg pheffectsontheelectrochemicalreductionofco2towardsc2productsonsteppedcopper AT michaeltang pheffectsontheelectrochemicalreductionofco2towardsc2productsonsteppedcopper AT kristophersbrown pheffectsontheelectrochemicalreductionofco2towardsc2productsonsteppedcopper AT hongjiepeng pheffectsontheelectrochemicalreductionofco2towardsc2productsonsteppedcopper AT stefanringe pheffectsontheelectrochemicalreductionofco2towardsc2productsonsteppedcopper AT christopherhahn pheffectsontheelectrochemicalreductionofco2towardsc2productsonsteppedcopper AT thomasfjaramillo pheffectsontheelectrochemicalreductionofco2towardsc2productsonsteppedcopper AT jensknørskov pheffectsontheelectrochemicalreductionofco2towardsc2productsonsteppedcopper AT karenchan pheffectsontheelectrochemicalreductionofco2towardsc2productsonsteppedcopper
_version_	1718386406463635456

pH effects on the electrochemical reduction of CO(2) towards C2 products on stepped copper

Ejemplares similares