Cooperative redox activation for carbon dioxide conversion

While CO2 can be converted to CO for further reactivity, typically this involves the generation of large amounts of waste. Here the authors report the conversion of CO2to CO, with the siloxane by-product being further used in a carbonylative Hiyama-Denmark coupling to form diarylketones.

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Detalles Bibliográficos
Autores principales: Zhong Lian, Dennis U. Nielsen, Anders T. Lindhardt, Kim Daasbjerg, Troels Skrydstrup
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2016
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Acceso en línea:https://doaj.org/article/3fbd9e30e25b430ca52c538065ed0a3a
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Descripción
Sumario:While CO2 can be converted to CO for further reactivity, typically this involves the generation of large amounts of waste. Here the authors report the conversion of CO2to CO, with the siloxane by-product being further used in a carbonylative Hiyama-Denmark coupling to form diarylketones.