Cooperative redox activation for carbon dioxide conversion

While CO2 can be converted to CO for further reactivity, typically this involves the generation of large amounts of waste. Here the authors report the conversion of CO2to CO, with the siloxane by-product being further used in a carbonylative Hiyama-Denmark coupling to form diarylketones.

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Autores principales: Zhong Lian, Dennis U. Nielsen, Anders T. Lindhardt, Kim Daasbjerg, Troels Skrydstrup
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2016
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Acceso en línea:https://doaj.org/article/3fbd9e30e25b430ca52c538065ed0a3a
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spelling oai:doaj.org-article:3fbd9e30e25b430ca52c538065ed0a3a2021-12-02T15:34:56ZCooperative redox activation for carbon dioxide conversion10.1038/ncomms137822041-1723https://doaj.org/article/3fbd9e30e25b430ca52c538065ed0a3a2016-12-01T00:00:00Zhttps://doi.org/10.1038/ncomms13782https://doaj.org/toc/2041-1723While CO2 can be converted to CO for further reactivity, typically this involves the generation of large amounts of waste. Here the authors report the conversion of CO2to CO, with the siloxane by-product being further used in a carbonylative Hiyama-Denmark coupling to form diarylketones.Zhong LianDennis U. NielsenAnders T. LindhardtKim DaasbjergTroels SkrydstrupNature PortfolioarticleScienceQENNature Communications, Vol 7, Iss 1, Pp 1-7 (2016)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Zhong Lian
Dennis U. Nielsen
Anders T. Lindhardt
Kim Daasbjerg
Troels Skrydstrup
Cooperative redox activation for carbon dioxide conversion
description While CO2 can be converted to CO for further reactivity, typically this involves the generation of large amounts of waste. Here the authors report the conversion of CO2to CO, with the siloxane by-product being further used in a carbonylative Hiyama-Denmark coupling to form diarylketones.
format article
author Zhong Lian
Dennis U. Nielsen
Anders T. Lindhardt
Kim Daasbjerg
Troels Skrydstrup
author_facet Zhong Lian
Dennis U. Nielsen
Anders T. Lindhardt
Kim Daasbjerg
Troels Skrydstrup
author_sort Zhong Lian
title Cooperative redox activation for carbon dioxide conversion
title_short Cooperative redox activation for carbon dioxide conversion
title_full Cooperative redox activation for carbon dioxide conversion
title_fullStr Cooperative redox activation for carbon dioxide conversion
title_full_unstemmed Cooperative redox activation for carbon dioxide conversion
title_sort cooperative redox activation for carbon dioxide conversion
publisher Nature Portfolio
publishDate 2016
url https://doaj.org/article/3fbd9e30e25b430ca52c538065ed0a3a
work_keys_str_mv AT zhonglian cooperativeredoxactivationforcarbondioxideconversion
AT dennisunielsen cooperativeredoxactivationforcarbondioxideconversion
AT anderstlindhardt cooperativeredoxactivationforcarbondioxideconversion
AT kimdaasbjerg cooperativeredoxactivationforcarbondioxideconversion
AT troelsskrydstrup cooperativeredoxactivationforcarbondioxideconversion
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