Cooperative redox activation for carbon dioxide conversion
While CO2 can be converted to CO for further reactivity, typically this involves the generation of large amounts of waste. Here the authors report the conversion of CO2to CO, with the siloxane by-product being further used in a carbonylative Hiyama-Denmark coupling to form diarylketones.
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Nature Portfolio
2016
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oai:doaj.org-article:3fbd9e30e25b430ca52c538065ed0a3a2021-12-02T15:34:56ZCooperative redox activation for carbon dioxide conversion10.1038/ncomms137822041-1723https://doaj.org/article/3fbd9e30e25b430ca52c538065ed0a3a2016-12-01T00:00:00Zhttps://doi.org/10.1038/ncomms13782https://doaj.org/toc/2041-1723While CO2 can be converted to CO for further reactivity, typically this involves the generation of large amounts of waste. Here the authors report the conversion of CO2to CO, with the siloxane by-product being further used in a carbonylative Hiyama-Denmark coupling to form diarylketones.Zhong LianDennis U. NielsenAnders T. LindhardtKim DaasbjergTroels SkrydstrupNature PortfolioarticleScienceQENNature Communications, Vol 7, Iss 1, Pp 1-7 (2016) |
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Science Q Zhong Lian Dennis U. Nielsen Anders T. Lindhardt Kim Daasbjerg Troels Skrydstrup Cooperative redox activation for carbon dioxide conversion |
description |
While CO2 can be converted to CO for further reactivity, typically this involves the generation of large amounts of waste. Here the authors report the conversion of CO2to CO, with the siloxane by-product being further used in a carbonylative Hiyama-Denmark coupling to form diarylketones. |
format |
article |
author |
Zhong Lian Dennis U. Nielsen Anders T. Lindhardt Kim Daasbjerg Troels Skrydstrup |
author_facet |
Zhong Lian Dennis U. Nielsen Anders T. Lindhardt Kim Daasbjerg Troels Skrydstrup |
author_sort |
Zhong Lian |
title |
Cooperative redox activation for carbon dioxide conversion |
title_short |
Cooperative redox activation for carbon dioxide conversion |
title_full |
Cooperative redox activation for carbon dioxide conversion |
title_fullStr |
Cooperative redox activation for carbon dioxide conversion |
title_full_unstemmed |
Cooperative redox activation for carbon dioxide conversion |
title_sort |
cooperative redox activation for carbon dioxide conversion |
publisher |
Nature Portfolio |
publishDate |
2016 |
url |
https://doaj.org/article/3fbd9e30e25b430ca52c538065ed0a3a |
work_keys_str_mv |
AT zhonglian cooperativeredoxactivationforcarbondioxideconversion AT dennisunielsen cooperativeredoxactivationforcarbondioxideconversion AT anderstlindhardt cooperativeredoxactivationforcarbondioxideconversion AT kimdaasbjerg cooperativeredoxactivationforcarbondioxideconversion AT troelsskrydstrup cooperativeredoxactivationforcarbondioxideconversion |
_version_ |
1718386713720520704 |