Fast room temperature lability of aluminosilicate zeolites

While aluminosilicate zeolites are of interest for many applications, the affect of water on zeolite stability in mild aqueous conditions has yet to be established. Here, using ab initio calculations and NMR spectroscopy, the authors show that covalent bonds in the zeolite chabazite are labile when...

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Autores principales: Christopher J. Heard, Lukas Grajciar, Cameron M. Rice, Suzi M. Pugh, Petr Nachtigall, Sharon E. Ashbrook, Russell E. Morris
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Lenguaje:EN
Publicado: Nature Portfolio 2019
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Acceso en línea:https://doaj.org/article/3fbdfc384c7b4d0b98913b793089d74f
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spelling oai:doaj.org-article:3fbdfc384c7b4d0b98913b793089d74f2021-12-02T15:35:18ZFast room temperature lability of aluminosilicate zeolites10.1038/s41467-019-12752-y2041-1723https://doaj.org/article/3fbdfc384c7b4d0b98913b793089d74f2019-10-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-12752-yhttps://doaj.org/toc/2041-1723While aluminosilicate zeolites are of interest for many applications, the affect of water on zeolite stability in mild aqueous conditions has yet to be established. Here, using ab initio calculations and NMR spectroscopy, the authors show that covalent bonds in the zeolite chabazite are labile when in contact with neutral liquid water.Christopher J. HeardLukas GrajciarCameron M. RiceSuzi M. PughPetr NachtigallSharon E. AshbrookRussell E. MorrisNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-7 (2019)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Christopher J. Heard
Lukas Grajciar
Cameron M. Rice
Suzi M. Pugh
Petr Nachtigall
Sharon E. Ashbrook
Russell E. Morris
Fast room temperature lability of aluminosilicate zeolites
description While aluminosilicate zeolites are of interest for many applications, the affect of water on zeolite stability in mild aqueous conditions has yet to be established. Here, using ab initio calculations and NMR spectroscopy, the authors show that covalent bonds in the zeolite chabazite are labile when in contact with neutral liquid water.
format article
author Christopher J. Heard
Lukas Grajciar
Cameron M. Rice
Suzi M. Pugh
Petr Nachtigall
Sharon E. Ashbrook
Russell E. Morris
author_facet Christopher J. Heard
Lukas Grajciar
Cameron M. Rice
Suzi M. Pugh
Petr Nachtigall
Sharon E. Ashbrook
Russell E. Morris
author_sort Christopher J. Heard
title Fast room temperature lability of aluminosilicate zeolites
title_short Fast room temperature lability of aluminosilicate zeolites
title_full Fast room temperature lability of aluminosilicate zeolites
title_fullStr Fast room temperature lability of aluminosilicate zeolites
title_full_unstemmed Fast room temperature lability of aluminosilicate zeolites
title_sort fast room temperature lability of aluminosilicate zeolites
publisher Nature Portfolio
publishDate 2019
url https://doaj.org/article/3fbdfc384c7b4d0b98913b793089d74f
work_keys_str_mv AT christopherjheard fastroomtemperaturelabilityofaluminosilicatezeolites
AT lukasgrajciar fastroomtemperaturelabilityofaluminosilicatezeolites
AT cameronmrice fastroomtemperaturelabilityofaluminosilicatezeolites
AT suzimpugh fastroomtemperaturelabilityofaluminosilicatezeolites
AT petrnachtigall fastroomtemperaturelabilityofaluminosilicatezeolites
AT sharoneashbrook fastroomtemperaturelabilityofaluminosilicatezeolites
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