Fast room temperature lability of aluminosilicate zeolites
While aluminosilicate zeolites are of interest for many applications, the affect of water on zeolite stability in mild aqueous conditions has yet to be established. Here, using ab initio calculations and NMR spectroscopy, the authors show that covalent bonds in the zeolite chabazite are labile when...
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Nature Portfolio
2019
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oai:doaj.org-article:3fbdfc384c7b4d0b98913b793089d74f2021-12-02T15:35:18ZFast room temperature lability of aluminosilicate zeolites10.1038/s41467-019-12752-y2041-1723https://doaj.org/article/3fbdfc384c7b4d0b98913b793089d74f2019-10-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-12752-yhttps://doaj.org/toc/2041-1723While aluminosilicate zeolites are of interest for many applications, the affect of water on zeolite stability in mild aqueous conditions has yet to be established. Here, using ab initio calculations and NMR spectroscopy, the authors show that covalent bonds in the zeolite chabazite are labile when in contact with neutral liquid water.Christopher J. HeardLukas GrajciarCameron M. RiceSuzi M. PughPetr NachtigallSharon E. AshbrookRussell E. MorrisNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-7 (2019) |
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Science Q Christopher J. Heard Lukas Grajciar Cameron M. Rice Suzi M. Pugh Petr Nachtigall Sharon E. Ashbrook Russell E. Morris Fast room temperature lability of aluminosilicate zeolites |
description |
While aluminosilicate zeolites are of interest for many applications, the affect of water on zeolite stability in mild aqueous conditions has yet to be established. Here, using ab initio calculations and NMR spectroscopy, the authors show that covalent bonds in the zeolite chabazite are labile when in contact with neutral liquid water. |
format |
article |
author |
Christopher J. Heard Lukas Grajciar Cameron M. Rice Suzi M. Pugh Petr Nachtigall Sharon E. Ashbrook Russell E. Morris |
author_facet |
Christopher J. Heard Lukas Grajciar Cameron M. Rice Suzi M. Pugh Petr Nachtigall Sharon E. Ashbrook Russell E. Morris |
author_sort |
Christopher J. Heard |
title |
Fast room temperature lability of aluminosilicate zeolites |
title_short |
Fast room temperature lability of aluminosilicate zeolites |
title_full |
Fast room temperature lability of aluminosilicate zeolites |
title_fullStr |
Fast room temperature lability of aluminosilicate zeolites |
title_full_unstemmed |
Fast room temperature lability of aluminosilicate zeolites |
title_sort |
fast room temperature lability of aluminosilicate zeolites |
publisher |
Nature Portfolio |
publishDate |
2019 |
url |
https://doaj.org/article/3fbdfc384c7b4d0b98913b793089d74f |
work_keys_str_mv |
AT christopherjheard fastroomtemperaturelabilityofaluminosilicatezeolites AT lukasgrajciar fastroomtemperaturelabilityofaluminosilicatezeolites AT cameronmrice fastroomtemperaturelabilityofaluminosilicatezeolites AT suzimpugh fastroomtemperaturelabilityofaluminosilicatezeolites AT petrnachtigall fastroomtemperaturelabilityofaluminosilicatezeolites AT sharoneashbrook fastroomtemperaturelabilityofaluminosilicatezeolites AT russellemorris fastroomtemperaturelabilityofaluminosilicatezeolites |
_version_ |
1718386590564220928 |