Direct transfer of tri- and di-fluoroethanol units enabled by radical activation of organosilicon reagents

Methods for direct incorporation of tri- and di-fluoroethanol units in molecules are relatively limited. Here, the authors report two organosilicon reagents which are applied to allylation, alkylation and alkenylation reactions as tri- and di-fluoroethanol transfer reagents.

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Autores principales: Xiang Chen, Xingxing Gong, Zhengyu Li, Gang Zhou, Zhihong Zhu, Weilu Zhang, Shanshan Liu, Xiao Shen
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2020
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Acceso en línea:https://doaj.org/article/4052f92859434aa6ba2aefe2fece0ec4
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Sumario:Methods for direct incorporation of tri- and di-fluoroethanol units in molecules are relatively limited. Here, the authors report two organosilicon reagents which are applied to allylation, alkylation and alkenylation reactions as tri- and di-fluoroethanol transfer reagents.