Direct transfer of tri- and di-fluoroethanol units enabled by radical activation of organosilicon reagents

Methods for direct incorporation of tri- and di-fluoroethanol units in molecules are relatively limited. Here, the authors report two organosilicon reagents which are applied to allylation, alkylation and alkenylation reactions as tri- and di-fluoroethanol transfer reagents.

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Autores principales:	Xiang Chen, Xingxing Gong, Zhengyu Li, Gang Zhou, Zhihong Zhu, Weilu Zhang, Shanshan Liu, Xiao Shen
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2020
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/4052f92859434aa6ba2aefe2fece0ec4
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spelling	oai:doaj.org-article:4052f92859434aa6ba2aefe2fece0ec42021-12-02T18:24:58ZDirect transfer of tri- and di-fluoroethanol units enabled by radical activation of organosilicon reagents10.1038/s41467-020-16380-92041-1723https://doaj.org/article/4052f92859434aa6ba2aefe2fece0ec42020-06-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-16380-9https://doaj.org/toc/2041-1723Methods for direct incorporation of tri- and di-fluoroethanol units in molecules are relatively limited. Here, the authors report two organosilicon reagents which are applied to allylation, alkylation and alkenylation reactions as tri- and di-fluoroethanol transfer reagents.Xiang ChenXingxing GongZhengyu LiGang ZhouZhihong ZhuWeilu ZhangShanshan LiuXiao ShenNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-9 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Xiang Chen Xingxing Gong Zhengyu Li Gang Zhou Zhihong Zhu Weilu Zhang Shanshan Liu Xiao Shen Direct transfer of tri- and di-fluoroethanol units enabled by radical activation of organosilicon reagents
description	Methods for direct incorporation of tri- and di-fluoroethanol units in molecules are relatively limited. Here, the authors report two organosilicon reagents which are applied to allylation, alkylation and alkenylation reactions as tri- and di-fluoroethanol transfer reagents.
format	article
author	Xiang Chen Xingxing Gong Zhengyu Li Gang Zhou Zhihong Zhu Weilu Zhang Shanshan Liu Xiao Shen
author_facet	Xiang Chen Xingxing Gong Zhengyu Li Gang Zhou Zhihong Zhu Weilu Zhang Shanshan Liu Xiao Shen
author_sort	Xiang Chen
title	Direct transfer of tri- and di-fluoroethanol units enabled by radical activation of organosilicon reagents
title_short	Direct transfer of tri- and di-fluoroethanol units enabled by radical activation of organosilicon reagents
title_full	Direct transfer of tri- and di-fluoroethanol units enabled by radical activation of organosilicon reagents
title_fullStr	Direct transfer of tri- and di-fluoroethanol units enabled by radical activation of organosilicon reagents
title_full_unstemmed	Direct transfer of tri- and di-fluoroethanol units enabled by radical activation of organosilicon reagents
title_sort	direct transfer of tri- and di-fluoroethanol units enabled by radical activation of organosilicon reagents
publisher	Nature Portfolio
publishDate	2020
url	https://doaj.org/article/4052f92859434aa6ba2aefe2fece0ec4
work_keys_str_mv	AT xiangchen directtransferoftrianddifluoroethanolunitsenabledbyradicalactivationoforganosiliconreagents AT xingxinggong directtransferoftrianddifluoroethanolunitsenabledbyradicalactivationoforganosiliconreagents AT zhengyuli directtransferoftrianddifluoroethanolunitsenabledbyradicalactivationoforganosiliconreagents AT gangzhou directtransferoftrianddifluoroethanolunitsenabledbyradicalactivationoforganosiliconreagents AT zhihongzhu directtransferoftrianddifluoroethanolunitsenabledbyradicalactivationoforganosiliconreagents AT weiluzhang directtransferoftrianddifluoroethanolunitsenabledbyradicalactivationoforganosiliconreagents AT shanshanliu directtransferoftrianddifluoroethanolunitsenabledbyradicalactivationoforganosiliconreagents AT xiaoshen directtransferoftrianddifluoroethanolunitsenabledbyradicalactivationoforganosiliconreagents
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Direct transfer of tri- and di-fluoroethanol units enabled by radical activation of organosilicon reagents

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