Destabilization of Boron-Based Compounds for Hydrogen Storage in the Solid-State: Recent Advances

Boron-based materials have been widely studied for hydrogen storage applications. Examples of these compounds are borohydrides and boranes. However, all of these present some disadvantages that have hindered their potential application as hydrogen storage materials in the solid-state. Thus, differen...

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Autores principales:	Carlos A. Castilla-Martinez, Romain Moury, Salem Ould-Amara, Umit B. Demirci
Formato:	article
Lenguaje:	EN
Publicado:	MDPI AG 2021
Materias:	borohydride borane hydrogen storage destabilization thermolysis hydrogen carrier Technology T
Acceso en línea:	https://doaj.org/article/40842e8595664591a47c709414137972
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spelling	oai:doaj.org-article:40842e8595664591a47c7094141379722021-11-11T15:49:28ZDestabilization of Boron-Based Compounds for Hydrogen Storage in the Solid-State: Recent Advances10.3390/en142170031996-1073https://doaj.org/article/40842e8595664591a47c7094141379722021-10-01T00:00:00Zhttps://www.mdpi.com/1996-1073/14/21/7003https://doaj.org/toc/1996-1073Boron-based materials have been widely studied for hydrogen storage applications. Examples of these compounds are borohydrides and boranes. However, all of these present some disadvantages that have hindered their potential application as hydrogen storage materials in the solid-state. Thus, different strategies have been developed to improve the dehydrogenation properties of these materials. The purpose of this review is to provide an overview of recent advances (for the period 2015–2021) in the destabilization strategies that have been considered for selected boron-based compounds. With this aim, we selected seven of the most investigated boron-based compounds for hydrogen storage applications: lithium borohydride, sodium borohydride, magnesium borohydride, calcium borohydride, ammonia borane, hydrazine borane and hydrazine bisborane. The destabilization strategies include the use of additives, the chemical modification and the nanosizing of these compounds. These approaches were analyzed for each one of the selected boron-based compounds and these are discussed in the present review.Carlos A. Castilla-MartinezRomain MourySalem Ould-AmaraUmit B. DemirciMDPI AGarticleborohydrideboranehydrogen storagedestabilizationthermolysishydrogen carrierTechnologyTENEnergies, Vol 14, Iss 7003, p 7003 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	borohydride borane hydrogen storage destabilization thermolysis hydrogen carrier Technology T
spellingShingle	borohydride borane hydrogen storage destabilization thermolysis hydrogen carrier Technology T Carlos A. Castilla-Martinez Romain Moury Salem Ould-Amara Umit B. Demirci Destabilization of Boron-Based Compounds for Hydrogen Storage in the Solid-State: Recent Advances
description	Boron-based materials have been widely studied for hydrogen storage applications. Examples of these compounds are borohydrides and boranes. However, all of these present some disadvantages that have hindered their potential application as hydrogen storage materials in the solid-state. Thus, different strategies have been developed to improve the dehydrogenation properties of these materials. The purpose of this review is to provide an overview of recent advances (for the period 2015–2021) in the destabilization strategies that have been considered for selected boron-based compounds. With this aim, we selected seven of the most investigated boron-based compounds for hydrogen storage applications: lithium borohydride, sodium borohydride, magnesium borohydride, calcium borohydride, ammonia borane, hydrazine borane and hydrazine bisborane. The destabilization strategies include the use of additives, the chemical modification and the nanosizing of these compounds. These approaches were analyzed for each one of the selected boron-based compounds and these are discussed in the present review.
format	article
author	Carlos A. Castilla-Martinez Romain Moury Salem Ould-Amara Umit B. Demirci
author_facet	Carlos A. Castilla-Martinez Romain Moury Salem Ould-Amara Umit B. Demirci
author_sort	Carlos A. Castilla-Martinez
title	Destabilization of Boron-Based Compounds for Hydrogen Storage in the Solid-State: Recent Advances
title_short	Destabilization of Boron-Based Compounds for Hydrogen Storage in the Solid-State: Recent Advances
title_full	Destabilization of Boron-Based Compounds for Hydrogen Storage in the Solid-State: Recent Advances
title_fullStr	Destabilization of Boron-Based Compounds for Hydrogen Storage in the Solid-State: Recent Advances
title_full_unstemmed	Destabilization of Boron-Based Compounds for Hydrogen Storage in the Solid-State: Recent Advances
title_sort	destabilization of boron-based compounds for hydrogen storage in the solid-state: recent advances
publisher	MDPI AG
publishDate	2021
url	https://doaj.org/article/40842e8595664591a47c709414137972
work_keys_str_mv	AT carlosacastillamartinez destabilizationofboronbasedcompoundsforhydrogenstorageinthesolidstaterecentadvances AT romainmoury destabilizationofboronbasedcompoundsforhydrogenstorageinthesolidstaterecentadvances AT salemouldamara destabilizationofboronbasedcompoundsforhydrogenstorageinthesolidstaterecentadvances AT umitbdemirci destabilizationofboronbasedcompoundsforhydrogenstorageinthesolidstaterecentadvances
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Destabilization of Boron-Based Compounds for Hydrogen Storage in the Solid-State: Recent Advances

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