Ferrotoroidic ground state in a heterometallic {CrIIIDyIII 6} complex displaying slow magnetic relaxation
Coupling molecular toroids via ferrotoroidic interactions represents an important opportunity to enhance ground state toroidicity, but is challenging to achieve. Here the authors isolate a {CrIIIDyIII 6} complex with a ferrotoroidic ground state and an enhanced toroidal moment, arising solely from i...
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| Autores principales: | , , , , , |
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| Formato: | article |
| Lenguaje: | EN |
| Publicado: |
Nature Portfolio
2017
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| Materias: | |
| Acceso en línea: | https://doaj.org/article/4150ef55a684423d8e3d797a556ddf40 |
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| Sumario: | Coupling molecular toroids via ferrotoroidic interactions represents an important opportunity to enhance ground state toroidicity, but is challenging to achieve. Here the authors isolate a {CrIIIDyIII 6} complex with a ferrotoroidic ground state and an enhanced toroidal moment, arising solely from intramolecular dipolar interactions. |
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