Ferrotoroidic ground state in a heterometallic {CrIIIDyIII 6} complex displaying slow magnetic relaxation

Coupling molecular toroids via ferrotoroidic interactions represents an important opportunity to enhance ground state toroidicity, but is challenging to achieve. Here the authors isolate a {CrIIIDyIII 6} complex with a ferrotoroidic ground state and an enhanced toroidal moment, arising solely from i...

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Autores principales: Kuduva R. Vignesh, Alessandro Soncini, Stuart K. Langley, Wolfgang Wernsdorfer, Keith S. Murray, Gopalan Rajaraman
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2017
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Acceso en línea:https://doaj.org/article/4150ef55a684423d8e3d797a556ddf40
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spelling oai:doaj.org-article:4150ef55a684423d8e3d797a556ddf402021-12-02T14:40:46ZFerrotoroidic ground state in a heterometallic {CrIIIDyIII 6} complex displaying slow magnetic relaxation10.1038/s41467-017-01102-52041-1723https://doaj.org/article/4150ef55a684423d8e3d797a556ddf402017-10-01T00:00:00Zhttps://doi.org/10.1038/s41467-017-01102-5https://doaj.org/toc/2041-1723Coupling molecular toroids via ferrotoroidic interactions represents an important opportunity to enhance ground state toroidicity, but is challenging to achieve. Here the authors isolate a {CrIIIDyIII 6} complex with a ferrotoroidic ground state and an enhanced toroidal moment, arising solely from intramolecular dipolar interactions.Kuduva R. VigneshAlessandro SonciniStuart K. LangleyWolfgang WernsdorferKeith S. MurrayGopalan RajaramanNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-12 (2017)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Kuduva R. Vignesh
Alessandro Soncini
Stuart K. Langley
Wolfgang Wernsdorfer
Keith S. Murray
Gopalan Rajaraman
Ferrotoroidic ground state in a heterometallic {CrIIIDyIII 6} complex displaying slow magnetic relaxation
description Coupling molecular toroids via ferrotoroidic interactions represents an important opportunity to enhance ground state toroidicity, but is challenging to achieve. Here the authors isolate a {CrIIIDyIII 6} complex with a ferrotoroidic ground state and an enhanced toroidal moment, arising solely from intramolecular dipolar interactions.
format article
author Kuduva R. Vignesh
Alessandro Soncini
Stuart K. Langley
Wolfgang Wernsdorfer
Keith S. Murray
Gopalan Rajaraman
author_facet Kuduva R. Vignesh
Alessandro Soncini
Stuart K. Langley
Wolfgang Wernsdorfer
Keith S. Murray
Gopalan Rajaraman
author_sort Kuduva R. Vignesh
title Ferrotoroidic ground state in a heterometallic {CrIIIDyIII 6} complex displaying slow magnetic relaxation
title_short Ferrotoroidic ground state in a heterometallic {CrIIIDyIII 6} complex displaying slow magnetic relaxation
title_full Ferrotoroidic ground state in a heterometallic {CrIIIDyIII 6} complex displaying slow magnetic relaxation
title_fullStr Ferrotoroidic ground state in a heterometallic {CrIIIDyIII 6} complex displaying slow magnetic relaxation
title_full_unstemmed Ferrotoroidic ground state in a heterometallic {CrIIIDyIII 6} complex displaying slow magnetic relaxation
title_sort ferrotoroidic ground state in a heterometallic {criiidyiii 6} complex displaying slow magnetic relaxation
publisher Nature Portfolio
publishDate 2017
url https://doaj.org/article/4150ef55a684423d8e3d797a556ddf40
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