Ferrotoroidic ground state in a heterometallic {CrIIIDyIII 6} complex displaying slow magnetic relaxation
Coupling molecular toroids via ferrotoroidic interactions represents an important opportunity to enhance ground state toroidicity, but is challenging to achieve. Here the authors isolate a {CrIIIDyIII 6} complex with a ferrotoroidic ground state and an enhanced toroidal moment, arising solely from i...
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Nature Portfolio
2017
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oai:doaj.org-article:4150ef55a684423d8e3d797a556ddf402021-12-02T14:40:46ZFerrotoroidic ground state in a heterometallic {CrIIIDyIII 6} complex displaying slow magnetic relaxation10.1038/s41467-017-01102-52041-1723https://doaj.org/article/4150ef55a684423d8e3d797a556ddf402017-10-01T00:00:00Zhttps://doi.org/10.1038/s41467-017-01102-5https://doaj.org/toc/2041-1723Coupling molecular toroids via ferrotoroidic interactions represents an important opportunity to enhance ground state toroidicity, but is challenging to achieve. Here the authors isolate a {CrIIIDyIII 6} complex with a ferrotoroidic ground state and an enhanced toroidal moment, arising solely from intramolecular dipolar interactions.Kuduva R. VigneshAlessandro SonciniStuart K. LangleyWolfgang WernsdorferKeith S. MurrayGopalan RajaramanNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-12 (2017) |
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Science Q Kuduva R. Vignesh Alessandro Soncini Stuart K. Langley Wolfgang Wernsdorfer Keith S. Murray Gopalan Rajaraman Ferrotoroidic ground state in a heterometallic {CrIIIDyIII 6} complex displaying slow magnetic relaxation |
description |
Coupling molecular toroids via ferrotoroidic interactions represents an important opportunity to enhance ground state toroidicity, but is challenging to achieve. Here the authors isolate a {CrIIIDyIII 6} complex with a ferrotoroidic ground state and an enhanced toroidal moment, arising solely from intramolecular dipolar interactions. |
format |
article |
author |
Kuduva R. Vignesh Alessandro Soncini Stuart K. Langley Wolfgang Wernsdorfer Keith S. Murray Gopalan Rajaraman |
author_facet |
Kuduva R. Vignesh Alessandro Soncini Stuart K. Langley Wolfgang Wernsdorfer Keith S. Murray Gopalan Rajaraman |
author_sort |
Kuduva R. Vignesh |
title |
Ferrotoroidic ground state in a heterometallic {CrIIIDyIII 6} complex displaying slow magnetic relaxation |
title_short |
Ferrotoroidic ground state in a heterometallic {CrIIIDyIII 6} complex displaying slow magnetic relaxation |
title_full |
Ferrotoroidic ground state in a heterometallic {CrIIIDyIII 6} complex displaying slow magnetic relaxation |
title_fullStr |
Ferrotoroidic ground state in a heterometallic {CrIIIDyIII 6} complex displaying slow magnetic relaxation |
title_full_unstemmed |
Ferrotoroidic ground state in a heterometallic {CrIIIDyIII 6} complex displaying slow magnetic relaxation |
title_sort |
ferrotoroidic ground state in a heterometallic {criiidyiii 6} complex displaying slow magnetic relaxation |
publisher |
Nature Portfolio |
publishDate |
2017 |
url |
https://doaj.org/article/4150ef55a684423d8e3d797a556ddf40 |
work_keys_str_mv |
AT kuduvarvignesh ferrotoroidicgroundstateinaheterometalliccriiidyiii6complexdisplayingslowmagneticrelaxation AT alessandrosoncini ferrotoroidicgroundstateinaheterometalliccriiidyiii6complexdisplayingslowmagneticrelaxation AT stuartklangley ferrotoroidicgroundstateinaheterometalliccriiidyiii6complexdisplayingslowmagneticrelaxation AT wolfgangwernsdorfer ferrotoroidicgroundstateinaheterometalliccriiidyiii6complexdisplayingslowmagneticrelaxation AT keithsmurray ferrotoroidicgroundstateinaheterometalliccriiidyiii6complexdisplayingslowmagneticrelaxation AT gopalanrajaraman ferrotoroidicgroundstateinaheterometalliccriiidyiii6complexdisplayingslowmagneticrelaxation |
_version_ |
1718390169957040128 |