A bio-inspired coordination polymer as outstanding water oxidation catalyst via second coordination sphere engineering
Proton-coupled electron transfer (PCET) process is very important for water oxidation catalysis. Here, the authors introduced uncoordinated carboxylate in the second-coordination-sphere of Ni-Fe coordination polymer catalyst as an internal base to promote the water oxidation kinetics by such PCET pr...
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Nature Portfolio
2019
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oai:doaj.org-article:417a28bc54ce4f96b2a6b4dcaa2da9482021-12-02T15:35:51ZA bio-inspired coordination polymer as outstanding water oxidation catalyst via second coordination sphere engineering10.1038/s41467-019-13052-12041-1723https://doaj.org/article/417a28bc54ce4f96b2a6b4dcaa2da9482019-11-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-13052-1https://doaj.org/toc/2041-1723Proton-coupled electron transfer (PCET) process is very important for water oxidation catalysis. Here, the authors introduced uncoordinated carboxylate in the second-coordination-sphere of Ni-Fe coordination polymer catalyst as an internal base to promote the water oxidation kinetics by such PCET process.Wenlong LiFusheng LiHao YangXiujuan WuPeili ZhangYu ShanLicheng SunNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-11 (2019) |
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Science Q Wenlong Li Fusheng Li Hao Yang Xiujuan Wu Peili Zhang Yu Shan Licheng Sun A bio-inspired coordination polymer as outstanding water oxidation catalyst via second coordination sphere engineering |
description |
Proton-coupled electron transfer (PCET) process is very important for water oxidation catalysis. Here, the authors introduced uncoordinated carboxylate in the second-coordination-sphere of Ni-Fe coordination polymer catalyst as an internal base to promote the water oxidation kinetics by such PCET process. |
format |
article |
author |
Wenlong Li Fusheng Li Hao Yang Xiujuan Wu Peili Zhang Yu Shan Licheng Sun |
author_facet |
Wenlong Li Fusheng Li Hao Yang Xiujuan Wu Peili Zhang Yu Shan Licheng Sun |
author_sort |
Wenlong Li |
title |
A bio-inspired coordination polymer as outstanding water oxidation catalyst via second coordination sphere engineering |
title_short |
A bio-inspired coordination polymer as outstanding water oxidation catalyst via second coordination sphere engineering |
title_full |
A bio-inspired coordination polymer as outstanding water oxidation catalyst via second coordination sphere engineering |
title_fullStr |
A bio-inspired coordination polymer as outstanding water oxidation catalyst via second coordination sphere engineering |
title_full_unstemmed |
A bio-inspired coordination polymer as outstanding water oxidation catalyst via second coordination sphere engineering |
title_sort |
bio-inspired coordination polymer as outstanding water oxidation catalyst via second coordination sphere engineering |
publisher |
Nature Portfolio |
publishDate |
2019 |
url |
https://doaj.org/article/417a28bc54ce4f96b2a6b4dcaa2da948 |
work_keys_str_mv |
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1718386407392673792 |