Ligands with 1,10-phenanthroline scaffold for highly regioselective iron-catalyzed alkene hydrosilylation

Hydrosilylation of alkenes poses substantial challenges in terms of regioselectivity. Here, the authors report iron complexes with 1,10-phenantroline ligand scaffolds which display benzylic selectivity in the hydrosilylation of internal alkenes and Markovnikov selectivity with terminal styrenes and...

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Auteurs principaux:	Meng-Yang Hu, Qiao He, Song-Jie Fan, Zi-Chen Wang, Luo-Yan Liu, Yi-Jiang Mu, Qian Peng, Shou-Fei Zhu
Format:	article
Langue:	EN
Publié:	Nature Portfolio 2018
Sujets:	Science Q
Accès en ligne:	https://doaj.org/article/42378608055b4234b3f7d3430235ee8b
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spelling	oai:doaj.org-article:42378608055b4234b3f7d3430235ee8b2021-12-02T14:41:16ZLigands with 1,10-phenanthroline scaffold for highly regioselective iron-catalyzed alkene hydrosilylation10.1038/s41467-017-02472-62041-1723https://doaj.org/article/42378608055b4234b3f7d3430235ee8b2018-01-01T00:00:00Zhttps://doi.org/10.1038/s41467-017-02472-6https://doaj.org/toc/2041-1723Hydrosilylation of alkenes poses substantial challenges in terms of regioselectivity. Here, the authors report iron complexes with 1,10-phenantroline ligand scaffolds which display benzylic selectivity in the hydrosilylation of internal alkenes and Markovnikov selectivity with terminal styrenes and 1,3-dienes.Meng-Yang HuQiao HeSong-Jie FanZi-Chen WangLuo-Yan LiuYi-Jiang MuQian PengShou-Fei ZhuNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-11 (2018)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Meng-Yang Hu Qiao He Song-Jie Fan Zi-Chen Wang Luo-Yan Liu Yi-Jiang Mu Qian Peng Shou-Fei Zhu Ligands with 1,10-phenanthroline scaffold for highly regioselective iron-catalyzed alkene hydrosilylation
description	Hydrosilylation of alkenes poses substantial challenges in terms of regioselectivity. Here, the authors report iron complexes with 1,10-phenantroline ligand scaffolds which display benzylic selectivity in the hydrosilylation of internal alkenes and Markovnikov selectivity with terminal styrenes and 1,3-dienes.
format	article
author	Meng-Yang Hu Qiao He Song-Jie Fan Zi-Chen Wang Luo-Yan Liu Yi-Jiang Mu Qian Peng Shou-Fei Zhu
author_facet	Meng-Yang Hu Qiao He Song-Jie Fan Zi-Chen Wang Luo-Yan Liu Yi-Jiang Mu Qian Peng Shou-Fei Zhu
author_sort	Meng-Yang Hu
title	Ligands with 1,10-phenanthroline scaffold for highly regioselective iron-catalyzed alkene hydrosilylation
title_short	Ligands with 1,10-phenanthroline scaffold for highly regioselective iron-catalyzed alkene hydrosilylation
title_full	Ligands with 1,10-phenanthroline scaffold for highly regioselective iron-catalyzed alkene hydrosilylation
title_fullStr	Ligands with 1,10-phenanthroline scaffold for highly regioselective iron-catalyzed alkene hydrosilylation
title_full_unstemmed	Ligands with 1,10-phenanthroline scaffold for highly regioselective iron-catalyzed alkene hydrosilylation
title_sort	ligands with 1,10-phenanthroline scaffold for highly regioselective iron-catalyzed alkene hydrosilylation
publisher	Nature Portfolio
publishDate	2018
url	https://doaj.org/article/42378608055b4234b3f7d3430235ee8b
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Ligands with 1,10-phenanthroline scaffold for highly regioselective iron-catalyzed alkene hydrosilylation

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