Crystal structure and Hirshfeld surface analysis of bis[(ethoxymethanethioyl)sulfanido](N,N,N′,N′-tetramethylethane-1,2-diamine)mercury(II)

The title four-coordinate mononuclear complex, [Hg(C3H5OS2)2(C6H16N2)] or [Hg(C3H5OS2)2(tmeda)] (tmeda: N,N,N′,N′-tetramethylethane-1,2-diamine), has a distorted tetrahedral geometry. The HgII ion is coordinated to two N atoms of the N,N,N′,N′-tetramethylethylenediamine ligand and two S atoms from t...

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Autores principales:	Adnan M. Qadir, Sevgi Kansiz, Necmi Dege, Eiad Saif
Formato:	article
Lenguaje:	EN
Publicado:	International Union of Crystallography 2021
Materias:	crystal structure xanthate mercury(ii) hirshfeld surface analysis Chemistry QD1-999
Acceso en línea:	https://doaj.org/article/4347d974eaae44d9a51fba9614e41db4
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spelling	oai:doaj.org-article:4347d974eaae44d9a51fba9614e41db42021-11-12T11:16:09ZCrystal structure and Hirshfeld surface analysis of bis[(ethoxymethanethioyl)sulfanido](N,N,N′,N′-tetramethylethane-1,2-diamine)mercury(II)2056-989010.1107/S2056989021010549https://doaj.org/article/4347d974eaae44d9a51fba9614e41db42021-11-01T00:00:00Zhttp://scripts.iucr.org/cgi-bin/paper?S2056989021010549https://doaj.org/toc/2056-9890The title four-coordinate mononuclear complex, [Hg(C3H5OS2)2(C6H16N2)] or [Hg(C3H5OS2)2(tmeda)] (tmeda: N,N,N′,N′-tetramethylethane-1,2-diamine), has a distorted tetrahedral geometry. The HgII ion is coordinated to two N atoms of the N,N,N′,N′-tetramethylethylenediamine ligand and two S atoms from two ethylxanthate xanthate ligands. In the crystal, molecules are linked by weak C—H...S hydrogen bonds, forming a two-dimensional supramolecular architecture in the ab plane. The most important contributions for the crystal packing are from H...H (59.3%), S...H (27.4%) and O...H (7.5%) interactions.Adnan M. QadirSevgi KansizNecmi DegeEiad SaifInternational Union of Crystallographyarticlecrystal structurexanthatemercury(ii)hirshfeld surface analysisChemistryQD1-999ENActa Crystallographica Section E: Crystallographic Communications, Vol 77, Iss 11, Pp 1126-1129 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	crystal structure xanthate mercury(ii) hirshfeld surface analysis Chemistry QD1-999
spellingShingle	crystal structure xanthate mercury(ii) hirshfeld surface analysis Chemistry QD1-999 Adnan M. Qadir Sevgi Kansiz Necmi Dege Eiad Saif Crystal structure and Hirshfeld surface analysis of bis[(ethoxymethanethioyl)sulfanido](N,N,N′,N′-tetramethylethane-1,2-diamine)mercury(II)
description	The title four-coordinate mononuclear complex, [Hg(C3H5OS2)2(C6H16N2)] or [Hg(C3H5OS2)2(tmeda)] (tmeda: N,N,N′,N′-tetramethylethane-1,2-diamine), has a distorted tetrahedral geometry. The HgII ion is coordinated to two N atoms of the N,N,N′,N′-tetramethylethylenediamine ligand and two S atoms from two ethylxanthate xanthate ligands. In the crystal, molecules are linked by weak C—H...S hydrogen bonds, forming a two-dimensional supramolecular architecture in the ab plane. The most important contributions for the crystal packing are from H...H (59.3%), S...H (27.4%) and O...H (7.5%) interactions.
format	article
author	Adnan M. Qadir Sevgi Kansiz Necmi Dege Eiad Saif
author_facet	Adnan M. Qadir Sevgi Kansiz Necmi Dege Eiad Saif
author_sort	Adnan M. Qadir
title	Crystal structure and Hirshfeld surface analysis of bis[(ethoxymethanethioyl)sulfanido](N,N,N′,N′-tetramethylethane-1,2-diamine)mercury(II)
title_short	Crystal structure and Hirshfeld surface analysis of bis[(ethoxymethanethioyl)sulfanido](N,N,N′,N′-tetramethylethane-1,2-diamine)mercury(II)
title_full	Crystal structure and Hirshfeld surface analysis of bis[(ethoxymethanethioyl)sulfanido](N,N,N′,N′-tetramethylethane-1,2-diamine)mercury(II)
title_fullStr	Crystal structure and Hirshfeld surface analysis of bis[(ethoxymethanethioyl)sulfanido](N,N,N′,N′-tetramethylethane-1,2-diamine)mercury(II)
title_full_unstemmed	Crystal structure and Hirshfeld surface analysis of bis[(ethoxymethanethioyl)sulfanido](N,N,N′,N′-tetramethylethane-1,2-diamine)mercury(II)
title_sort	crystal structure and hirshfeld surface analysis of bis[(ethoxymethanethioyl)sulfanido](n,n,n′,n′-tetramethylethane-1,2-diamine)mercury(ii)
publisher	International Union of Crystallography
publishDate	2021
url	https://doaj.org/article/4347d974eaae44d9a51fba9614e41db4
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Crystal structure and Hirshfeld surface analysis of bis[(ethoxymethanethioyl)sulfanido](N,N,N′,N′-tetramethylethane-1,2-diamine)mercury(II)

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