Atomic-scale perturbation of oxygen octahedra via surface ion exchange in perovskite nickelates boosts water oxidation

While perovskite oxides are well-studied for their oxygen electrocatalysis performances, the impact of oxygen octahedra is less studied. Here, authors show electrochemical exchange of lanthanide nickelate surfaces to distort oxygen octahedra, facilitating charge transfer and improving catalysis.

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Autores principales: Jumi Bak, Hyung Bin Bae, Sung-Yoon Chung
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Lenguaje:EN
Publicado: Nature Portfolio 2019
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Acceso en línea:https://doaj.org/article/4350e2e3d85248eba44fb0f12cdac0dc
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spelling oai:doaj.org-article:4350e2e3d85248eba44fb0f12cdac0dc2021-12-02T14:39:00ZAtomic-scale perturbation of oxygen octahedra via surface ion exchange in perovskite nickelates boosts water oxidation10.1038/s41467-019-10838-12041-1723https://doaj.org/article/4350e2e3d85248eba44fb0f12cdac0dc2019-06-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-10838-1https://doaj.org/toc/2041-1723While perovskite oxides are well-studied for their oxygen electrocatalysis performances, the impact of oxygen octahedra is less studied. Here, authors show electrochemical exchange of lanthanide nickelate surfaces to distort oxygen octahedra, facilitating charge transfer and improving catalysis.Jumi BakHyung Bin BaeSung-Yoon ChungNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-10 (2019)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Jumi Bak
Hyung Bin Bae
Sung-Yoon Chung
Atomic-scale perturbation of oxygen octahedra via surface ion exchange in perovskite nickelates boosts water oxidation
description While perovskite oxides are well-studied for their oxygen electrocatalysis performances, the impact of oxygen octahedra is less studied. Here, authors show electrochemical exchange of lanthanide nickelate surfaces to distort oxygen octahedra, facilitating charge transfer and improving catalysis.
format article
author Jumi Bak
Hyung Bin Bae
Sung-Yoon Chung
author_facet Jumi Bak
Hyung Bin Bae
Sung-Yoon Chung
author_sort Jumi Bak
title Atomic-scale perturbation of oxygen octahedra via surface ion exchange in perovskite nickelates boosts water oxidation
title_short Atomic-scale perturbation of oxygen octahedra via surface ion exchange in perovskite nickelates boosts water oxidation
title_full Atomic-scale perturbation of oxygen octahedra via surface ion exchange in perovskite nickelates boosts water oxidation
title_fullStr Atomic-scale perturbation of oxygen octahedra via surface ion exchange in perovskite nickelates boosts water oxidation
title_full_unstemmed Atomic-scale perturbation of oxygen octahedra via surface ion exchange in perovskite nickelates boosts water oxidation
title_sort atomic-scale perturbation of oxygen octahedra via surface ion exchange in perovskite nickelates boosts water oxidation
publisher Nature Portfolio
publishDate 2019
url https://doaj.org/article/4350e2e3d85248eba44fb0f12cdac0dc
work_keys_str_mv AT jumibak atomicscaleperturbationofoxygenoctahedraviasurfaceionexchangeinperovskitenickelatesboostswateroxidation
AT hyungbinbae atomicscaleperturbationofoxygenoctahedraviasurfaceionexchangeinperovskitenickelatesboostswateroxidation
AT sungyoonchung atomicscaleperturbationofoxygenoctahedraviasurfaceionexchangeinperovskitenickelatesboostswateroxidation
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