Selective E to Z isomerization of 1,3-Dienes Enabled by A Dinuclear Mechanism

Geometric E to Z double C=C bond isomerization is challenging as it requires kinetic trapping of the Z-isomer with injection of chemical energy. Here, the authors report a dinuclear Pd(I)−Pd(I) complex that mediates selective isomerization of E-1,3-dienes to the Z-isomers without photoirradiation.

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Autores principales:	Eiji Kudo, Kota Sasaki, Shiori Kawamata, Koji Yamamoto, Tetsuro Murahashi
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/4371ec1b6c7b412591eee57fec8532bf
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spelling	oai:doaj.org-article:4371ec1b6c7b412591eee57fec8532bf2021-12-02T13:14:48ZSelective E to Z isomerization of 1,3-Dienes Enabled by A Dinuclear Mechanism10.1038/s41467-021-21720-42041-1723https://doaj.org/article/4371ec1b6c7b412591eee57fec8532bf2021-03-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-21720-4https://doaj.org/toc/2041-1723Geometric E to Z double C=C bond isomerization is challenging as it requires kinetic trapping of the Z-isomer with injection of chemical energy. Here, the authors report a dinuclear Pd(I)−Pd(I) complex that mediates selective isomerization of E-1,3-dienes to the Z-isomers without photoirradiation.Eiji KudoKota SasakiShiori KawamataKoji YamamotoTetsuro MurahashiNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-8 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Eiji Kudo Kota Sasaki Shiori Kawamata Koji Yamamoto Tetsuro Murahashi Selective E to Z isomerization of 1,3-Dienes Enabled by A Dinuclear Mechanism
description	Geometric E to Z double C=C bond isomerization is challenging as it requires kinetic trapping of the Z-isomer with injection of chemical energy. Here, the authors report a dinuclear Pd(I)−Pd(I) complex that mediates selective isomerization of E-1,3-dienes to the Z-isomers without photoirradiation.
format	article
author	Eiji Kudo Kota Sasaki Shiori Kawamata Koji Yamamoto Tetsuro Murahashi
author_facet	Eiji Kudo Kota Sasaki Shiori Kawamata Koji Yamamoto Tetsuro Murahashi
author_sort	Eiji Kudo
title	Selective E to Z isomerization of 1,3-Dienes Enabled by A Dinuclear Mechanism
title_short	Selective E to Z isomerization of 1,3-Dienes Enabled by A Dinuclear Mechanism
title_full	Selective E to Z isomerization of 1,3-Dienes Enabled by A Dinuclear Mechanism
title_fullStr	Selective E to Z isomerization of 1,3-Dienes Enabled by A Dinuclear Mechanism
title_full_unstemmed	Selective E to Z isomerization of 1,3-Dienes Enabled by A Dinuclear Mechanism
title_sort	selective e to z isomerization of 1,3-dienes enabled by a dinuclear mechanism
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/4371ec1b6c7b412591eee57fec8532bf
work_keys_str_mv	AT eijikudo selectiveetozisomerizationof13dienesenabledbyadinuclearmechanism AT kotasasaki selectiveetozisomerizationof13dienesenabledbyadinuclearmechanism AT shiorikawamata selectiveetozisomerizationof13dienesenabledbyadinuclearmechanism AT kojiyamamoto selectiveetozisomerizationof13dienesenabledbyadinuclearmechanism AT tetsuromurahashi selectiveetozisomerizationof13dienesenabledbyadinuclearmechanism
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Selective E to Z isomerization of 1,3-Dienes Enabled by A Dinuclear Mechanism

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