A diuranium carbide cluster stabilized inside a C80 fullerene cage

While metal–carbon double bonds are common in transition metal chemistry and catalysis, unsupported uranium–carbon double bonds remain highly challenging to prepare. Here, the authors stabilize and characterize a U=C=U cluster containing unusually short, unsupported double bonds inside an I h(7)-C80...

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Autores principales:	Xingxing Zhang, Wanlu Li, Lai Feng, Xin Chen, Andreas Hansen, Stefan Grimme, Skye Fortier, Dumitru-Claudiu Sergentu, Thomas J. Duignan, Jochen Autschbach, Shuao Wang, Yaofeng Wang, Giorgios Velkos, Alexey A. Popov, Nabi Aghdassi, Steffen Duhm, Xiaohong Li, Jun Li, Luis Echegoyen, W. H. Eugen Schwarz, Ning Chen
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2018
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/43cf8bb9730242659a08a6490909e157
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spelling	oai:doaj.org-article:43cf8bb9730242659a08a6490909e1572021-12-02T15:34:27ZA diuranium carbide cluster stabilized inside a C80 fullerene cage10.1038/s41467-018-05210-82041-1723https://doaj.org/article/43cf8bb9730242659a08a6490909e1572018-07-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-05210-8https://doaj.org/toc/2041-1723While metal–carbon double bonds are common in transition metal chemistry and catalysis, unsupported uranium–carbon double bonds remain highly challenging to prepare. Here, the authors stabilize and characterize a U=C=U cluster containing unusually short, unsupported double bonds inside an I h(7)-C80 fullerene cage.Xingxing ZhangWanlu LiLai FengXin ChenAndreas HansenStefan GrimmeSkye FortierDumitru-Claudiu SergentuThomas J. DuignanJochen AutschbachShuao WangYaofeng WangGiorgios VelkosAlexey A. PopovNabi AghdassiSteffen DuhmXiaohong LiJun LiLuis EchegoyenW. H. Eugen SchwarzNing ChenNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-8 (2018)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Xingxing Zhang Wanlu Li Lai Feng Xin Chen Andreas Hansen Stefan Grimme Skye Fortier Dumitru-Claudiu Sergentu Thomas J. Duignan Jochen Autschbach Shuao Wang Yaofeng Wang Giorgios Velkos Alexey A. Popov Nabi Aghdassi Steffen Duhm Xiaohong Li Jun Li Luis Echegoyen W. H. Eugen Schwarz Ning Chen A diuranium carbide cluster stabilized inside a C80 fullerene cage
description	While metal–carbon double bonds are common in transition metal chemistry and catalysis, unsupported uranium–carbon double bonds remain highly challenging to prepare. Here, the authors stabilize and characterize a U=C=U cluster containing unusually short, unsupported double bonds inside an I h(7)-C80 fullerene cage.
format	article
author	Xingxing Zhang Wanlu Li Lai Feng Xin Chen Andreas Hansen Stefan Grimme Skye Fortier Dumitru-Claudiu Sergentu Thomas J. Duignan Jochen Autschbach Shuao Wang Yaofeng Wang Giorgios Velkos Alexey A. Popov Nabi Aghdassi Steffen Duhm Xiaohong Li Jun Li Luis Echegoyen W. H. Eugen Schwarz Ning Chen
author_facet	Xingxing Zhang Wanlu Li Lai Feng Xin Chen Andreas Hansen Stefan Grimme Skye Fortier Dumitru-Claudiu Sergentu Thomas J. Duignan Jochen Autschbach Shuao Wang Yaofeng Wang Giorgios Velkos Alexey A. Popov Nabi Aghdassi Steffen Duhm Xiaohong Li Jun Li Luis Echegoyen W. H. Eugen Schwarz Ning Chen
author_sort	Xingxing Zhang
title	A diuranium carbide cluster stabilized inside a C80 fullerene cage
title_short	A diuranium carbide cluster stabilized inside a C80 fullerene cage
title_full	A diuranium carbide cluster stabilized inside a C80 fullerene cage
title_fullStr	A diuranium carbide cluster stabilized inside a C80 fullerene cage
title_full_unstemmed	A diuranium carbide cluster stabilized inside a C80 fullerene cage
title_sort	diuranium carbide cluster stabilized inside a c80 fullerene cage
publisher	Nature Portfolio
publishDate	2018
url	https://doaj.org/article/43cf8bb9730242659a08a6490909e157
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A diuranium carbide cluster stabilized inside a C80 fullerene cage

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