Study on Adsorption of As(III) by a New Bio-Material from Chitin Pyrolysis
Chitin-char is obtained from fast pyrolysis of chitin. To obtain the maximum surface area, chitin-char is treated by nitric acid. Then, a kind of new arsenic removal bio-material is prepared by loading Ca(OH)<sub>2</sub> on the char (called Ca(OH)<sub>2</sub>-char). IR spectr...
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2021
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oai:doaj.org-article:43e383e6585345d29e03e6d736b913c32021-11-11T19:52:19ZStudy on Adsorption of As(III) by a New Bio-Material from Chitin Pyrolysis10.3390/w132129442073-4441https://doaj.org/article/43e383e6585345d29e03e6d736b913c32021-10-01T00:00:00Zhttps://www.mdpi.com/2073-4441/13/21/2944https://doaj.org/toc/2073-4441Chitin-char is obtained from fast pyrolysis of chitin. To obtain the maximum surface area, chitin-char is treated by nitric acid. Then, a kind of new arsenic removal bio-material is prepared by loading Ca(OH)<sub>2</sub> on the char (called Ca(OH)<sub>2</sub>-char). IR spectroscopy before and after char treatment reveal at least three distinct patterns of peak changes. An adsorption study is performed at different doses, pHs, and coexisting ions in the batch mode. The adsorption kinetics follows two first-order equations. Kinetic studies yield an optimum equilibrium time of 2 h with an adsorbent dose of 0.4 g/L and concentration of 10 mg/L. Using only 0.4 g/L of carbon, the maximum removal capacity is about 99.8%. The result indicates that the Ca(OH)<sub>2</sub>-char has a high adsorption capacity in the process of removing arsenic (III).Zhiguang YangGaojun YanZhiwei SongJunzheng ZhangChenlong WangZhisheng YuZhihui BaiGuoqiang ZhuangFeng LiangMDPI AGarticlebio-materialsarsenicadsorptionwater treatmentHydraulic engineeringTC1-978Water supply for domestic and industrial purposesTD201-500ENWater, Vol 13, Iss 2944, p 2944 (2021) |
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DOAJ |
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bio-materials arsenic adsorption water treatment Hydraulic engineering TC1-978 Water supply for domestic and industrial purposes TD201-500 |
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bio-materials arsenic adsorption water treatment Hydraulic engineering TC1-978 Water supply for domestic and industrial purposes TD201-500 Zhiguang Yang Gaojun Yan Zhiwei Song Junzheng Zhang Chenlong Wang Zhisheng Yu Zhihui Bai Guoqiang Zhuang Feng Liang Study on Adsorption of As(III) by a New Bio-Material from Chitin Pyrolysis |
description |
Chitin-char is obtained from fast pyrolysis of chitin. To obtain the maximum surface area, chitin-char is treated by nitric acid. Then, a kind of new arsenic removal bio-material is prepared by loading Ca(OH)<sub>2</sub> on the char (called Ca(OH)<sub>2</sub>-char). IR spectroscopy before and after char treatment reveal at least three distinct patterns of peak changes. An adsorption study is performed at different doses, pHs, and coexisting ions in the batch mode. The adsorption kinetics follows two first-order equations. Kinetic studies yield an optimum equilibrium time of 2 h with an adsorbent dose of 0.4 g/L and concentration of 10 mg/L. Using only 0.4 g/L of carbon, the maximum removal capacity is about 99.8%. The result indicates that the Ca(OH)<sub>2</sub>-char has a high adsorption capacity in the process of removing arsenic (III). |
format |
article |
author |
Zhiguang Yang Gaojun Yan Zhiwei Song Junzheng Zhang Chenlong Wang Zhisheng Yu Zhihui Bai Guoqiang Zhuang Feng Liang |
author_facet |
Zhiguang Yang Gaojun Yan Zhiwei Song Junzheng Zhang Chenlong Wang Zhisheng Yu Zhihui Bai Guoqiang Zhuang Feng Liang |
author_sort |
Zhiguang Yang |
title |
Study on Adsorption of As(III) by a New Bio-Material from Chitin Pyrolysis |
title_short |
Study on Adsorption of As(III) by a New Bio-Material from Chitin Pyrolysis |
title_full |
Study on Adsorption of As(III) by a New Bio-Material from Chitin Pyrolysis |
title_fullStr |
Study on Adsorption of As(III) by a New Bio-Material from Chitin Pyrolysis |
title_full_unstemmed |
Study on Adsorption of As(III) by a New Bio-Material from Chitin Pyrolysis |
title_sort |
study on adsorption of as(iii) by a new bio-material from chitin pyrolysis |
publisher |
MDPI AG |
publishDate |
2021 |
url |
https://doaj.org/article/43e383e6585345d29e03e6d736b913c3 |
work_keys_str_mv |
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